Materials Literature
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The strongly anisotropic thioarsenates A(3)Ta(2)AsS(11) are stabilized in a polysulfide flux. All compounds contain the same parallel (1)/(infinity)[Ta(2)AsS(11)(3-)] polymeric anionic chains, but the size of the alkali-metals has a profound effect on the packing of the chains. The K(+) or Rb(+) favor noncentrosymmetr…
ZnO nanocrystals with different oxygen defects (type and concentration) are successfully prepared via the templating method in Nafion membranes. Photoluminescence and infrared characterizations reveal that the concentration of oxygen defects (oxygen vacancy and interstitial oxygen) is quite different for the samples p…
The recent discovery of superconductivity in (Ba,K)Fe2As2, which crystallizes in the ThCr2Si2 (122) structure as compared with the LnFeAsO (Ln is lanthanide) systems that possess the ZrCuSiAs (1111) structure, demonstrates the exciting potential of the FeAs-based materials for high-T{C} superconductivity. Here we repo…
In the title compound, (C(6)H(16)N)(2)[Fe(2)(C(4)H(2)N(2)S(2))(4)]·2CH(4)O, the [Fe(III)(pdt)(2)](-) anion (pdt is pyrazine-2,3-dithiol-ate) forms a centrosymmetric dimer supported by two Fe(III)-S bonds [Fe-S = 2.4787 (4) Å]. In the crystal structure, dimers form a one-dimensional stack along the b axis via π-π stack…
The advanced characteristics of synchrotron light has led in recent years to the development of a series of new experimental techniques to investigate chemical and physical properties on a microscopic scale. Although originally developed for materials science and biomedical research, such techniques find increasing ap…
We report the formation of molecular solid solutions from the 1:1 binary mixtures of 1-naphthylmethylammonium n -alkanoates with different alkyl chain lengths. Systematic investigation of all the combinations from acetate to nonadecanoate concluded that a 1-naphthylmethylammonium n -alkanoate formed the molecular soli…
This research work aimed to synthesize boron carbonitride powder from cheap precursors using a combustion synthesis, followed by a carbothermic reaction process. A mixture of boric acid, lactose, and urea was subjected to thermolysis under a mild temperature of 250°C, followed by heat treatment at 1200°C for 2 h in an…
Prediction criterions for the formabilities of perovskite-type oxides are obtained by using the empirical structure map methods constructed by two parameters octahedral factor (r B /r O ) and tolerance factor, on this structure map, simple point representing systems of forming and non forming are distributed in distin…
In the scientific studies the influence of burning regime or composition of formation mix on the final properties of the ceramic bricks is analysed most often. However, drying regime is also of paramount importance in the process of the high quality ceramic production. The formed ceramic samples were dried according t…
The stoichiometric self‐propagating high‐temperature synthesis (SHS) thermite reaction involving magnesium (Mg), titanium dioxide (TiO 2 ), and boron oxide (B 2 O 3 ) forms MgO and titanium diboride (TiB 2 ) as final products. Selective acid leaching is used to remove the MgO leaving TiB 2 powder. This study investiga…
A field theoretical method for fluctuating hydrodynamics with preserved fluctuation-dissipation relations is reformulated. By assuming that the correlations including momentum are irrelevant in the long time region, we demonstrate that the equation obtained from the first-order perturbation is reduced to that for stan…
Abstract The effect of different surface sizing formulations on the chemical features of surfaces of the papers produced from Eucalyptus kraft pulp was studied. The surface analysis techniques, electron spectroscopy for chemical analysis and time-of-flight secondary ion mass spectrometry were applied. An uncoated base…
Collapse of an ice clathrate of type II structure containing tetrahydrofuran as guest molecules has been studied at different pressures by dielectric spectroscopy. The sample was pressurized to 1.3 GPa at 130 K and the resulting collapsed state was pressure cycled. The dielectric relaxation time increases at a progres…
The self-assembly and selective distribution of metal or metal oxide nanoparticles in block copolymer matrices was designed to produce photonic bandgap materials through a bottom-up method rather than the more common top-down approach. The synthesis of such materials consists of the in situ thermolysis of metal carbon…
The preparation and the characterization of three new dyads composed of a ruthenium trisbipyridine complex linked to a naphthalene bisimide electron acceptor via a phenyleneethynylene spacer of different length (one or two units) are reported. The dyads also differ by the anchoring position of the spacer on the bipyri…
Self-assembly, optical, and mechanical properties of surfactant-directed biphenyl-bridged periodic mesoporous organosilica thin films (PMOF-Bp's) with molecular-scale periodicity in the pore walls were successfully demonstrated for the first time. The biphenyl-bridged organosilica precursor, 4,4-bis(triethoxysilyl)bip…
Dy:YAG phosphor coatings were deposited using the solution precursor plasma spray process. The phase composition, microstructure, and photoluminescent properties of the as‐deposited coatings were investigated. X‐ray diffraction analysis confirmed that the coating is mainly composed of the YAG phase with a small amount…
Thermal stabilities of the zwitterionic glycine (zg) combined with water molecules are investigated by both ab initio/RRKM calculations and the thermostatic molecular dynamics (MD) simulations. The microhydrated zg clusters, zg-nw (n = 2, 3; w = water), can transfer to the canonical clusters cg-nw through the rapid in…
We present a technological approach to the realization of channeled optical waveguides, starting from reactively sputtered tellurite glass thin films, grown on silica-coated 4" Si wafers. In particular, optical lithographic process and etching recipes have been developed to overcome the solubility of TeO(2) films in a…
Carbon foam templates were prepared from a mixture of mesophase pitch (MP) and Si particles, followed by foaming and carbonization. Subsequent molten Si infiltrated into the carbon foam at 1500°C for 4 h in an inert atmosphere resulted in the formation of porous SiC ceramics. Micrographs were investigated by a scannin…