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Capacitance Limits of Activated Carbon Fiber Electrodes in Aqueous Electrolyte

Chun-Ling Liu、Wen‐Sheng Dong、Gaoping Cao 等 6 位作者2007-11-26Journal of The Electrochemical Society

Phenolic resin-based activated carbon fibers (ACFs) were prepared by , , steam, , and ferrocene activation. The porosity, surface chemistry, and electric conductivity of ACFs were studied as electric double-layer capacitors in electrolyte. The specific capacitance for ACFs is generally in the range 130– and roughly ha…

Supercapacitor Materials and FabricationAdvanced Battery Materials and TechnologiesConducting polymers and applications

Inkjet printing effects of pigment inks on silk fabrics surface‐modified with O2 plasma

Kuanjun Fang、Shaohua Wang、Chaoxia Wang 等 4 位作者2007-11-26Journal of Applied Polymer Science

Abstract Without any preprocessing, silk fabric has lower ability to hold on water due to the smooth morphology of silk fibers. Therefore, patterns directly printed with pigment inks have poor color yields and easily bleed. Plasma surface‐treatment of silk fabric was carried out in an oxygen atmosphere under different…

Surface Modification and SuperhydrophobicityElectrospun Nanofibers in Biomedical ApplicationsSilk-based biomaterials and applications

Reaction Mechanism of Solid Carbon Fuel in Rechargeable Direct Carbon SOFCs with Methane for Charging

Shinichi Hasegawa、Manabu Ihara2007-11-26Journal of The Electrochemical Society

Rechargeable direct carbon fuel cells (RDCFC) can be expected as portable power sources. The performance of power generation from RDCFCs was investigated here for various Ar flow rates into the anode. The fuel of solid carbon was charged by thermal decomposition of pure dry methane on the anode. The power generation t…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

A Study on the Effects of the Degree of Deacetylation of Chitosan Films on Physical and Antibacterial Properties

Hsien‐Tang Chiu、Ray-Lun Chen、Peiyi Wu 等 5 位作者2007-11-26Polymer-Plastics Technology and Engineering

The principal aim of this research study is to discuss the influences and effects of the acetylation degree of chitosan on antibacterial properties, mechanism, and thermal properties. Various chitosan with different degrees of deacetylation (DD%) were dissolved in acetic acid solution to produce films. The basic struc…

Hydrogels: synthesis, properties, applicationsNanocomposite Films for Food Packagingbiodegradable polymer synthesis and properties

Ageing studies of ethylene propylene diene monomer rubber/styrene butadiene rubber blends: Effects of heat, ozone, gamma radiation, and water

T. Muraleedharan Nair、M. G. Kumaran、G. Unnikrishnan 等 4 位作者2007-11-26Journal of Applied Polymer Science

Abstract The ageing behavior due to the effects of heat, ozone, γ‐ radiation, and water on ethylene propylene diene monomer rubber/styrene butadiene rubber (EPDM/SBR) blends was studied. The tensile strength, crack initiation, ozone ageing, gamma radiation, and water resistance of the blends were measured and used to…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and Irradiation

Effect of polymorphism of isotactic polybutene‐1 on peel behavior of polyethylene/polybutene‐1 peel systems

Michael Nase、René Androsch、Beate Langer 等 5 位作者2007-11-26Journal of Applied Polymer Science

Abstract The effect of polymorphism of isotactic polybutene‐1 (iPB‐1) on the peel behavior of the specific peel system low‐density polyethylene/polybutene‐1 (LDPE/iPB‐1) was investigated using wide‐angle X‐ray scattering, calorimetry, and the T‐peel test. Melt‐crystallization of iPB‐1, initially, yields tetragonal for…

Polymer crystallization and propertiesNatural Fiber Reinforced Compositesbiodegradable polymer synthesis and properties

Synthesis of Nitridosilicate CaSr[sub 1−x]Eu[sub x]Si[sub 5]N[sub 8] (x=0–1) Phosphor by Calcium Cyanamide Reduction for White Light-Emitting Diode Applications

Xianqing Piao、Ken‐ichi Machida、Takashi Horikawa 等 4 位作者2007-11-26Journal of The Electrochemical Society

Synthesis of Nitridosilicate CaSr1 − x Eu x Si5N8 ( x = 0 – 1 ) Phosphor by Calcium Cyanamide Reduction for White Light-Emitting Diode Applications, Piao, Xianqing, Machida, Ken-ichi, Horikawa, Takashi, Hanzawa, Hiromasa

Luminescence Properties of Advanced MaterialsAmmonia Synthesis and Nitrogen ReductionInorganic Chemistry and Materials

A liquid crystalline polymer microlens array with tunable focal intensity by the polarization control of a liquid crystal layer

Yoonseuk Choi、Hak‐Rin Kim、Kwang Ho Lee 等 5 位作者2007-11-26Applied Physics Letters

We propose a focal intensity tunable microlens array by using a birefringent liquid crystalline polymer for lensing action. Due to the difference of effective refractive indices, it acts as a positive or negative microlens with respect to the polarization state. As we control the incident polarization by adding a liqu…

Liquid Crystal Research AdvancementsAdvanced Optical Imaging TechnologiesPhotochromic and Fluorescence Chemistry

Highly shifted LIPOCEST agents based on the encapsulation of neutral polynuclear paramagnetic shift reagents

Enzo Terreno、Alessandro Barge、Lorena Beltrami 等 8 位作者2007-11-26Chemical Communications

Improved LIPOCEST MRI contrast agents with highly shifted intraliposomal water protons were prepared by entrapping neutral polynuclear Tm(III)-based paramagnetic shift reagents in phospholipidic vesicles.

Advanced MRI Techniques and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Thermal degradation of a phenolic resin, vegetable fibers, and derived composites

Claudia Noemí Zárate、Mirta I. Aranguren、M. M. Reboredo2007-11-26Journal of Applied Polymer Science

Abstract The thermal degradation behavior of resol, several vegetable fibers (two types of cotton fibers, sisal and sugar cane bagasse) and derived polymer composites have been investigated using thermogravimetric analysis (TGA). The initial thermal degradation temperature T ONSET , the temperature at the maximum degr…

Polymer crystallization and propertiesNatural Fiber Reinforced CompositesFlame retardant materials and properties

A dinuclear iron( ii ) complex, [(TPyA)Fe II (THBQ 2– )Fe II (TPyA)](BF 4 ) 2 [TPyA = tris(2-pyridylmethyl)amine; THBQ 2– = 2,3,5,6-tetrahydroxy-1,4-benzoquinonate] exhibiting both spin crossover with hysteresis and ferromagnetic exchange

Kil Sik Min、K. Świerczek、Antonio G. DiPasquale 等 7 位作者2007-11-26Chemical Communications

Dinuclear [(TPyA)FeII(THBQ(2-))FeII(TPyA)](BF4)2 (1) possesses hydrogen bonding interactions that form a 1-D chain, and pi-pi interactions between the 1-D chains that give rise to a 2-D supramolecular-layered structure, inducing hysteresis in the spin crossover behavior; 1 has shown spin crossover behavior around 250…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Supramolecular motifs and solvatomorphism within the compounds [M(bpy) 3 ] 2 [NbO(C 2 O 4 ) 3 ]Cl·nH 2 O (M = Fe 2+ , Co 2+ , Ni 2+ , Cu 2+ and Zn 2+ ; n = 11, 12). Syntheses, structures and magnetic properties

Marijana Jurić、Berislav Perić、Nevenka Brničević 等 8 位作者2007-11-26Dalton Transactions

Solvatomorphism has been found between two series of complexes of the composition [M(bpy)3]2[NbO(C2O4)3]Cl.nH2O [M = Fe2+ (1, 2), Co2+ (3, 4), Ni2+ (5, 6), Cu2+ (7) and Zn2+ (8, 9); bpy = 2,2'-bipyridine)], crystallizing in the monoclinic space group P2 1/c [3, 5, 8 (n = 11)] or in the orthorhombic space group P21 21…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Luminescent heteropolynuclear or multicomponent complexes with polypyridyl-functionalized alkynyl ligands

Zhong‐Ning Chen、Yang Fan、Jun Ni2007-11-26Dalton Transactions

Polypyridyl-functionalized alkynes are a class of bifunctional ligands and very useful for the design of heteropolynuclear or multicomponent arrays as optoelectronic materials at the molecular level. This article focuses on reviewing the recent progress in design of luminescent heteropolynuclear or multicomponent comp…

Organometallic Complex Synthesis and CatalysisLanthanide and Transition Metal ComplexesPolyoxometalates: Synthesis and Applications

Advantages of SiSb phase-change material and its applications in phase-change memory

Ting Zhang、Zhitang Song、Feng Wang 等 6 位作者2007-11-26Applied Physics Letters

Te-free environmental friendly SiSb phase-change material is investigated for the applications of phase-change memory. The binary material, which is compatible with the complementary metal-oxide semiconductor manufacturing process, is outstanding in various properties comparing with the most widely adopted ternary Ge2…

Liquid Crystal Research AdvancementsChalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenides

Size control and midinfrared emission of epitaxial PbTe∕CdTe quantum dot precipitates grown by molecular beam epitaxy

Heiko Groiß、E. Kaufmann、G. Springholz 等 12 位作者2007-11-26Applied Physics Letters

Epitaxial quantum dots with symmetric and highly facetted shapes are fabricated by thermal annealing of two-dimensional (2D) PbTe epilayers embedded in a CdTe matrix. By varying the thickness of the initial 2D layers, the dot size can be effectively controlled between 5 and 25nm, and areal densities as high as 3×1011c…

Semiconductor Quantum Structures and DevicesQuantum Dots Synthesis And PropertiesAdvanced Semiconductor Detectors and Materials

Resistive switching properties of high crystallinity and low-resistance Pr0.7Ca0.3MnO3 thin film with point-contacted Ag electrodes

Masayuki Fujimoto、Hiroshi Koyama、Yuji Nishi 等 4 位作者2007-11-26Applied Physics Letters

A high-crystallinity, low-resistance Pr0.7Ca0.3MnO3(PCMO) thin film deposited by sputtering at 600°C showed no resistive switching with a Pt∕Pr0.7Ca0.3MnO3∕Pt structure but a remarkable bipolar resistive switching with a Ag paste/Pr0.7Ca0.3MnO3∕Pt structure. Observed retention fatigue of the low-resistance state was a…

Advanced Memory and Neural ComputingMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Grain size dependence of relaxor behavior in CaCu3Ti4O12 ceramics

Hongtao Yu、Hanxing Liu、Hua Hao 等 7 位作者2007-11-26Applied Physics Letters

The dielectric properties show a typical ferroelectric relaxor behavior in CaCu3Ti4O12 ceramics with different grain sizes in the temperature range of 400–600K. The relaxation strength and the frequency dispersion increase with grain size decreasing, which can be due to the different stresses in grains with different…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsDielectric properties of ceramics

Surface-enhanced Raman spectroscopy and correlated scanning electron microscopy of individual carbon nanotubes

Rajay Kumar、Hao Zhou、Stephen B. Cronin2007-11-26Applied Physics Letters

Raman spectra of individual carbon nanotubes are measured by scanning a focused laser spot (0.5μm diameter) over a large area (100μm2) before and after depositing silver nanoparticles. Local regions exhibiting surface enhanced Raman spectroscopy (SERS) were located with respect to a lithographically patterned grid, al…

Carbon Nanotubes in CompositesGold and Silver Nanoparticles Synthesis and ApplicationsNanopore and Nanochannel Transport Studies

Reversible switching on superhydrophobic TiO 2 nano-strawberry films fabricated at low temperature

Wentao Sun、Shuyun Zhou、Ping Chen 等 4 位作者2007-11-26Chemical Communications

Superhydrophobic TiO2 nano-strawberry rutile films, on which superhydrophobicity and superhydrophilicity can be reversibly switched by alternation of ultraviolet (UV) irradiation and dark storage, were fabricated on a large scale from aqueous solution via a seeded growth method at low temperature without any pressure…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsNanomaterials and Printing Technologies

Towards understanding of magnetic interactions within a series of tetrathiafulvalene–π conjugated-verdazyl diradical cation system: a density functional theory study

Víctor Polo、Antonio Alberola、Juán Andrés 等 5 位作者2007-11-26Physical Chemistry Chemical Physics

The intramolecular magnetic exchange coupling constants (J) for a series of tetrathiafulvalene (TTF) and verdazyl diradical cations connected by a range of pi conjugated linkers have been investigated by means of methodology based on unrestricted density functional theory. The magnetic interaction between radicals is…

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchElectron Spin Resonance Studies