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Activated Zinc Complexes Supported by a Neutral, Phosphinimine-Containing Ligand: Synthesis and Efficacy for the Polymerization of Lactide

Craig A. Wheaton、B.J. Ireland、Paul G. Hayes2009-02-16Organometallics

A general approach for the synthesis of cationic zinc complexes supported by neutral ancillary ligands has been developed and exploited to prepare [ L H][B(C 6 F 5 ) 4 ] ( L = 4-(2,6- i Pr 2 -C 6 H 3 NPPh 2 )dbf), 1a, and [ L H][SO 3 CF 3 ], 1b ) using [HNMe 2 Ph][B(C 6 F 5 ) 4 ] and triflic acid, respectively. Reacti…

Organometallic Complex Synthesis and Catalysisbiodegradable polymer synthesis and propertiesOrganoboron and organosilicon chemistry

Tension Amplification in Molecular Brushes in Solutions and on Substrates

Sergey Panyukov、Ekaterina B. Zhulina、Sergei S. Sheiko 等 6 位作者2009-02-16The Journal of Physical Chemistry B

Molecular bottle-brushes are highly branched macromolecules with side chains densely grafted to a long polymer backbone. The brush-like architecture allows focusing of the side-chain tension to the backbone and its amplification from the pico-Newton to nano-Newton range. The backbone tension depends on the overall mol…

Polymer Surface Interaction StudiesMolecular Junctions and NanostructuresForce Microscopy Techniques and Applications

High-temperature electrical transport behaviors in textured Ca3Co4O9-based polycrystalline ceramics

Yuan‐Hua Lin、Jinle Lan、Zhijian Shen 等 6 位作者2009-02-16Applied Physics Letters

Highly (00l) oriented Ca3Co4O9-based ceramics were fabricated by spark plasma sintering combined with a dynamic forging process. The grain orientation is effective in lowering the electrical resistivity and enhancing the thermoelectric power factor but with little influence on the Seebeck coefficient. A metallic-to-se…

Physics of Superconductivity and MagnetismAdvanced Thermoelectric Materials and DevicesThermal properties of materials

Influence of Sample Preparation, Temperature, Light, and Pressure on the Two-Step Spin Crossover Mononuclear Compound [Fe(bapbpy)(NCS) 2 ]

Sylvestre Bonnet、Gábor Molnár、José Sánchez Costa 等 9 位作者2009-02-16Chemistry of Materials

The three phases of the mononuclear two-step spin crossover compound [Fe(bapbpy)(NCS) 2 ] ( 1 ) are characterized by powder X-ray diffraction, Mössbauer spectroscopy, Raman spectroscopy, calorimetry, and magnetic susceptibility measurements. Mössbauer and Raman spectroscopies confirm the results obtained from previous…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Catalyzed Oxygenation Mechanisms

Plasmon‐Resonance‐Based Generation of Cathodic Photocurrent at Electrodeposited Gold Nanoparticles Coated with TiO2 Films

Nobuyuki Sakai、Yusuke Fujiwara、Yukina Takahashi 等 4 位作者2009-02-16ChemPhysChem

Reversed photoresponse: Indium tin oxide (ITO)/Au nanoparticle (NP)/TiO(2) electrodes (see picture) exhibit cathodic photocurrents and positive photopotentials under visible light, whereas ITO/TiO(2)/Au NP electrodes show an inverted response. This behavior indicates that electron transfer occurs from the plasmon-exci…

Advanced Photocatalysis TechniquesGold and Silver Nanoparticles Synthesis and ApplicationsCopper-based nanomaterials and applications

Oxygen tracer diffusion in dense Ba0.5Sr0.5Co0.8Fe0.2O3−δ films

L. Wang、Rotraut Merkle、Joachim Maier 等 5 位作者2009-02-16Applied Physics Letters

Ba 0.5 Sr 0.5 Co 0.8 Fe 0.2 O 3 - δ (BSCF) is an interesting material for high temperature oxygen permeation membranes and solid oxide fuel cell cathodes, applications for which oxygen transport properties are crucial. Here oxygen isotope exchange is performed on dense BSCF films prepared by pulsed laser deposition on…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Spin-Hall effect and spin-Coulomb drag in doped semiconductors

E. M. Hankiewicz、G. Vignale2009-02-16arXiv

In this review, we describe in detail two important spin-transport phenomena: the extrinsic spin-Hall effect (coming from spin-orbit interactions between electrons and impurities) and the spin-Coulomb drag. The interplay of these two phenomena is analyzed. In particular, we discuss the influence of scattering between…

Mesoscale and Nanoscale PhysicsMaterials Science

Characteristics of the ZnO thin film transistor by atomic layer deposition at various temperatures

Semyung Kwon、Seokhwan Bang、Seungjun Lee 等 10 位作者2009-02-16Semiconductor Science and Technology

Characteristics of the ZnO thin film transistor by atomic layer deposition at various temperatures, Kwon, Semyung, Bang, Seokhwan, Lee, Seungjun, Jeon, Sunyeol, Jeong, Wooho, Kim, Hyungchul, Gong, Su Cheol, Chang, Ho Jung, Park, Hyung-ho, Jeon, Hyeongtag

ZnO doping and propertiesThin-Film Transistor TechnologiesGa2O3 and related materials

New Polymeric Composites Based on Poly(ϵ-caprolactone) and Layered Double Hydroxides Containing Antimicrobial Species

Umberto Costantino、Valeria Bugatti、Giuliana Gorrasi 等 7 位作者2009-02-16ACS Applied Materials & Interfaces

Benzoate (Bz), 2,4-dichlorobenzoate (BzDC), and p- and o-hydroxybenzoate (p- and o-BzOH) anions with antimicrobial activity have been intercalated into [Zn(0.65)Al(0.35)(OH)(2)](NO(3))(0.35).0.6H(2)O, layered double hydroxide (LDH), via anion-exchange reactions. The composition of the obtained intercalation compounds,…

Polyoxometalates: Synthesis and ApplicationsLayered Double Hydroxides Synthesis and ApplicationsMagnesium Oxide Properties and Applications

Kinetic roughening in a realistic model of non-conserved interface growth

Matteo Nicoli、Mario Castro、Rodolfo Cuerno2009-02-16Journal of Statistical Mechanics Theory and Experiment

We provide a quantitative picture of non-conserved interface growth from a diffusive field, placing special emphasis on two main issues, the range of validity of the effective small slopes (interfacial) theories and the interplay between the emergence of morphological instabilities in the aggregate dynamics, and its k…

Theoretical and Computational PhysicsSolidification and crystal growth phenomenananoparticles nucleation surface interactions

Inverse square-root field dependence of conductivity in organic field-effect transistors

J. H. Wei、Yongli Gao、X. R. Wang2009-02-16Applied Physics Letters

Variable-range hopping is usually the main electron transport mechanism of an organic semiconductor at low temperature. For an organic field-effect transistor at low temperature and under both high source-drain bias and high gate voltage, it is argued that multistep tunneling (MUST) can dominate charge transport. The…

Organic Electronics and PhotovoltaicsMolecular Junctions and NanostructuresOrganic and Molecular Conductors Research

Multiferroicity with high-TC in ceramics of the YBaCuFeO5 ordered perovskite

B. Kundys、A. Maignan、Ch. Simon2009-02-16Applied Physics Letters

A dielectric anomaly has been found near the incommensurate to commensurate antiferromagnetic phase transition (TN2≈230 K) in YBaCuFeO5 ceramics, a compound which crystallizes in an ordered perovskite structure. The existence of electric polarization below TN2 suggests the magnetism induced charge polarization effect…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsDielectric properties of ceramics

The mechanism of ion induced amorphization in Si

H. P. Lenka、U. M. Bhatta、P. K. Kuiri 等 7 位作者2009-02-16arXiv

Some results on damage build up in, and amorphization of, Si, induced by 25-30 keV Al$_5^-$, Si$_5^-$ and Cs$^-$ ions, at room temperature, are reported. We show that at low energy, amorphization is a nucleation and growth process, based on the direct impact mechanism. With an Avrami exponent $\sim 1.6$, the growth to…

Materials Science

Magnetic-Field-Dependent Raman Scattering in Multiferroic Bilayer Films: Evidence for Stress-Mediated Magnetoelectric Coupling

Zheng Li、Yao Wang、Yuanhua Lin 等 4 位作者2009-02-16arXiv

We report the first magnetic-field-dependent Raman scattering studies on Pb(Zr,Ti)O3-CoFe2O4 bilayer multiferroic system. The phonon frequencies of the nano-bilayers obviously change with magnetic field, which is absent in the single Pb(Zr,Ti)O3 films. The magnetostriction of the CoFe2O4 layer generates stress mechani…

Materials Science

Inkjet printing of light emitting quantum dots

Hanna M. Haverinen、Risto Myllylä、Ghassan E. Jabbour2009-02-16Applied Physics Letters

We demonstrate the fabrication of diodes having inkjet printed light emitting quantum dots layer. Close packing of printed layer is shown to be influenced by surface morphology of the underlying polymer layer and size variance of quantum dots used. We extend our approach to printing quantum dots onto a quarter video g…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesNanomaterials and Printing Technologies

Logic gates with a single graphene transistor

Roman Sordan、Floriano Traversi、Valeria Russo2009-02-16Applied Physics Letters

The operation of four basic two-input logic gates fabricated with a single graphene transistor is demonstrated. Single-transistor operation is obtained in a circuit designed to exploit the charge neutrality point of graphene to perform Boolean logic. The type of logic function is selected by offset of the input digita…

Graphene research and applicationsLow-power high-performance VLSI designQuantum and electron transport phenomena

Photoelectrochemical Study of the Band Structure of Zn2SnO4 Prepared by the Hydrothermal Method

Mario A. Alpuche-Avilés、Yiying Wu2009-02-16Journal of the American Chemical Society

It is fundamentally interesting to study the photoelectrochemical properties of complex oxides for applications in photovoltaics and photocatalysis. In this paper, we study the band gap (E(g)) and energetics of the conduction band (CB) and valence band (VB) for films of zinc stannate (Zn(2)SnO(4)) nanoparticles (ca. 2…

ZnO doping and propertiesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Mechanically robust and electrically conductive carbon nanotube foams

Marcus A. Worsley、S. O. Kucheyev、Joe H. Satcher 等 5 位作者2009-02-16Applied Physics Letters

We describe the fabrication of ultralow-density carbon nanotube (CNT) foams that simultaneously exhibit high electrical conductivities and robust mechanical properties. Our approach utilizes carbon nanoparticles as a binder to crosslink randomly oriented bundles of single-walled CNTs. The resulting CNT foams are the s…

Carbon Nanotubes in CompositesGraphene research and applicationsSupercapacitor Materials and Fabrication

Protein Adsorption of Ultrafine Metal Oxide and Its Influence on Cytotoxicity toward Cultured Cells

Masanori Horie、Keiko Nishio、Katsuhide Fujita 等 13 位作者2009-02-16Chemical Research in Toxicology

Many investigations about the cellular response by metal oxide nanoparticles in vitro have been reported. However, the influence of the adsorption ability of metal oxide nanoparticles toward cells is unknown. The aim of this study is to understand the influence of adsorption by metal oxide nanoparticles on the cell vi…

Nanoparticle-Based Drug DeliveryNanoparticles: synthesis and applicationsGraphene and Nanomaterials Applications