Materials Literature
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Axial absorption and circular dichroism (CD) spectra are reported for single crystals of Na3[Sm(oxydiacetate)3]·2NaClO4·6H2O over the spectral region 17 600–30 500 cm-1. Within this region, 213 individual (4f → 4f) crystal-field transitions may occur from the ground crystal-field level of Sm3+. Each of these transitio…
A p-n junction diode of cubic boron nitride was made by growing an n-type crystal epitaxially on a p-type seed crystal at a pressure of 55 kilobars and a temperature of about 1700 degrees C. A temperature-difference solvent method was used for the crystal growth, and beryllium and silicon were doped as acceptors and d…
Abstract Optical absorption and fluorescence, magnetic susceptibility and electron magnetic resonance experiments have been made of Tb3+, 4f8, ions in lanthanide nicotinate dihydrate single crystals. Optical absorption spectroscopy in undiluted terbium nicotinate dihydrate (TbND) indicates that the ground state of Tb3…
Abstract The stability of superspheres containing a few tens of particles, formed by the aggregation of weakly charged spherical colloidal crystalites, can be explained by the existence of two opposing forces of different range within the superspheres: long-range electrostatic repulsion and shortrange attractive dispe…
Abstract A set of transformed composition variables is introduced for the representation of reactive-phase diagrams. These variables are superior to mole fractions because in the new representation, the non-reactive limits are well defined, the equilibrium surfaces are tangent at azeotropic states, and the number of l…
Article Neutron diffraction study of zoisite at 15 Κ and X-ray study at room temperature was published on October 1, 1987 in the journal Zeitschrift für Kristallographie - Crystalline Materials (volume 179, issue 1-4).
Article Ruthenium(III)triphosphide RuP3: Preparation, crystal structure and properties was published on October 1, 1987 in the journal Zeitschrift für Kristallographie - Crystalline Materials (volume 179, issue 1-4).
Space charge may lower the breakdown strength of solid insulation by making local electric fields bigger than the applied field. One extensive study[1] of this phenomenon led to a proposal to blend crosslinked polyethylene (XLPE) insulation with an ionomer to reduce space charge build-up. The authors used contact elec…
A detailed description of our revised method of preparing PE and XLPE samples to be used for the investigation of the fundamental parameters of these two materials will be presented. The latest findings regarding the long term conductivity of the specimens under high and constant electrical field, when temperature was…
Synopsis The effect of hydration time, water/solids ratio and addition of melamine sulphonate or naphthalene sulphonate resins on the I (001) /I (101) XRD peak intensity ratio of portlandite formed in the hydration of pure tricalcium silicate or Portland cement was studied. It was found that this ratio does not remain…
Fort St. Vrain (FSV) is the only graphite-moderated, helium-cooled nuclear power plant in the United States. It was preceded by the 40-MW(electric) Peach Bottom high-temperature gas-cooled reactor (HTGR), which was permanently shut down in 1975. The Public Service Company of Colorado owns and operates FSV, and the cor…
This paper reports progress in measuring electric fields due to space charge in continuous dielectric media by-means of the thermal pulse method[1–3]. This work is pertinent to the study of charge injection and transport processes as well as to the study of the effects of space charge on the dielectric breakdown of el…
Thermal properties of fluorinated and unfluorinated glasses based on the systems AlF 3 ‐NaPO 3 and AlF 3 ‐CaF 2 ‐NaPO 3 were investigated. Crystallization is more distinct in glasses with a higher fluorine content. The increase in fluorine content in aluminofluorophosphate glasses increases the thermal dilatometry coe…
The FRAS3 code, developed to model transient fission‐gas behavior in oxide fuel, has been modified for application to metallic fuel. The code has been applied to analyze a series of experiments on irradiated uranium fuel, in which fission‐gas bubble distributions were measured following isothermal anneals under variou…
<div class="htmlview paragraph">Federal Aviation Administration (FAA) Advisory Circular AC 20-107A, Composite Aircraft Structure, issued in 1984 provides updated guidance material for use in demonstrating compliance with the provisions of the applicable Federal Aviation Regulations, (FAR) regarding airworthiness…
Aluminum‐tin alloys were electrodeposited onto steel from alkyl benzene, electrolytes. Bright, adherent, and coherent aluminum‐tin coatings were obtained at cathode efficiencies approaching 100%. The composition of the cathode deposit can be readily controlled by using Al‐Sn anodes of specified tin content. If the cur…
Abstract Several polymer‐metal complexes were prepared by reacting poly(vinyl carbazole) (PNVC) with copper(II) chloride, CuCl 2 .2H 2 O, in refluxing tetrahydrofurane (THF) for mole ratios of CuCl 2 .2H 2 O to monomeric unit (Cu:PNVC ratio) ranging between 0.086 and 4.98. Complexes were characterized by infrared (IR)…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSolution-crosslinked networks. 2. Viscoelastic behavior of guest polyisoprene in natural rubber networksBeng Teik Poh, Keiichiro Adachi, and Tadao KotakaCite this: Macromolecules 1987, 20, 10, 2569–2574Publication Date (Print):October 1, 1987Publication History Published onl…
Abstract The hole transport of trans ‐1,2‐biscarbazolylcyclobutane (CB) doped poly(bisphenol A carbonate) (PC) film has been investigated in the CB concentration range of 3.8 × 10 −4 mol cm −3 (12 wt%) to 1.6 × 10 −3 mol cm −3 (51 wt%). The hole mobility increased drastically with increasing CB concentration. The hole…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSolution-crosslinked networks. 3. Dielectric normal mode process of guest polyisoprene in natural rubber networksBeng Teik Poh, Keiichiro Adachi, and Tadao KotakaCite this: Macromolecules 1987, 20, 10, 2574–2579Publication Date (Print):October 1, 1987Publication History Publ…