Materials Literature
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The potential application range of coarse-grained commercial purity titanium is limited by its low mechanical properties. A reduction of the grain size of titanium leads to a significant increase in its strength and hardness. This paper is concerned with application of hydrostatic extrusion (HE) for fabrication nano-g…
Abstract Amino‐terminated and carboxyl‐containing polyurethane (PU) is prepared by an isocyanate‐terminated PU prepolymer process. Carboxyl‐containing epoxy resin is obtained from a half‐esterification of epoxy resin with maleic anhydride. These two aqueous resins are obtained after neutralization with triethylamine a…
Experiments were conducted on an Al-0.2wt.%Sc alloy to evaluate the effect of equalchannel angular pressing (ECAP) on its creep behaviour. ECAP was conducted at room temperature with a die that had an internal angle of 90° between the two parts of the channel. The subsequent extrusion passes were performed by route BC…
Abstract The effect of prepolymer molecular weight on the solid‐state polymerization (SSP) of poly(bisphenol A carbonate) was investigated using nitrogen (N 2 ) as a sweep fluid. Prepolymers with different number–average molecular weights, 3800 and 2400 g/mol, were synthesized using melt transesterification. SSP of th…
Two series of novel thermotropic main chain liquid crystalline polymers containing photocrosslinkable chalcone and photoisomerizable azobenzene moieties were synthesized from bis[4-( m-hydroxyalkoxy)benzylidene]cycloalkanones [ m = 6,8,10] with 4,4'-azobenzene dicarbonylchloride. The chemical structure of the monomers…
The effect of equal-channel angular extrusion (ECAE) on mechanical properties of an AA2017 produced by powder metallurgy is investigated. Special attention is given to the influence of heat treatment, processing temperature and backpressure on the workability for achieving high strength and moderate ductility. This is…
Nanocarrier mediated therapy of gliomas has shown promise. The success of systemic nanocarrier-based chemotherapy is critically dependent on the so-called leaky vasculature to permit drug extravasation across the blood-brain barrier. Yet, the extent of vascular permeability in individual tumors varies widely, resultin…
Abstract A convenient and cost‐effective strategy for synthesis of hyperbranched poly(ester‐amide)s from commercially available dicarboxylic acids (A 2 ) and multihydroxyl secondary amine (CB 2 ) has been developed. By optimizing the conditions of model reactions, the AB 2 ‐type intermediates were formed dominantly du…
Abstract Effect of molar mass distribution (MMD) and composition distribution (CD) on crystallization behavior of linear low‐density polyethylene materials at moderate and high supercooling was studied using differential scanning calorimetry, hot‐stage polarized light microscopy, small‐angle light scattering, and chip…
Electron-hole symmetry upon p- and n-doping of conducting organic polymers is rationalized with Hückel theory by the presence of symmetrically located intragap states. Since density functional theory (DFT) predicts very different geometries and energy level diagrams for conjugated pi-systems than semiempirical methods…
The radiotracer technique was applied for measuring grain boundary diffusion of Ni in ultrafine grained (UFG) copper materials with different nominal purities and in a Cu—1wt.%Pb alloy. The UFG specimens were prepared by equal channel angular pressing at room temperature. The stability of the microstructure was studie…
The scattering unit of X-ray crystal structure analysis is changed from atoms to the subshell electrons by X-ray atomic orbital analysis (XAO). All the atoms in the unit cell are divided into groups of subshell electrons in the XAO analysis. Each subshell is treated as an independent pseudo-atom, which enables the ato…
The microstructures of B bearing cast steel (B steel) containing 0·8–1·2 wt-%B, 0·8–1·2 wt-%Cr, 1·0–1·5 wt-%Mn, 0·6–1·0 wt-%Si and 0·10–0·25 wt-%C have been characterised by means of optical microscopy, scanning electron microscopy, electron probe microanalyser and X-ray diffraction. The solidification structure of B…
Distinctive structure features of rods produced by hot and cold radial forging of a Zr- 2.5%Nb alloy were revealed. Most experimental data were obtained by X-ray methods. Among considered aspects, connected with the undulatory mechanism of energy transfer, there are the uniformity of bulk deformation, structure perfec…
This paper describes the influence of initial crystallographic orientation on the formation of dense shear bands in pure copper single crystals subjected to equal-channel angular pressing (ECAP) for one pass at room temperature. Local orientation change during simple shear by ECAP traced by electron backscatter diffra…
Aluminum alloys have found many applications in different branches of industry. In spite of the valuable properties, there is a significant drawback because of the strong corrosion susceptibility, especially in chloride-containing medium. The present work is focused on study of the 2024 aluminum alloy corrosion mechan…
Aging behavior and mechanical properties of ultra fine grained Cu-Cr-Zr alloy sheet produced by accumulative roll bonding (ARB) process were investigated. A Cu-0.85Cr-0.07Zr (in mass%) alloy was solution treated and then cold-rolled at ambient temperature in the sheet of 1 mm thick. The sheets were heavily deformed by…
Signals attributable to amide protons and used in previous studies to measure intracellular pH were observed in the low-field region of the (1)H-MR spectra of four tumour cell lines: T98G, MCF-7, A172 and HeLa. The signals were more intense in the spectra of the two cell lines (T98G and MCF-7) characterised by higher…
This paper reports on the microstructures and fatigue properties of ultrafine-grained (UFG) AM60 magnesium alloy processed by equal channel angular pressing (ECAP) at various temperatures. After ECAP processing, samples exhibited an increase in fatigue endurance limit, which correlates well with a decrease in grain si…
Abstract Isotactic polypropylene has been reactively blended with an ethylene‐octene copolymer so as to improve mechanical and rheological properties. Free radical polymerization of styrene and a multifunctional acrylate during melt extrusion has resulted in the formation of unique features in both amorphous and cryst…