Materials Literature
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Single-molecule (SM) spectroscopy has been conducted to study exciton-like intramolecular charge transfer (ICT) coupling dynamics in two model dendritic systems containing branched ICT interactions. The strong coupling and stepwise photobleaching of the ICT branches in the dendrimers, which depend on the torsional dis…
The crystal structures of 6H-type BaMn 0.15 Ti 0.85 O 3, BaMn 1/4 Ti 3/4 O 2.95, and BaMn 1/2 Ti 1/2 O 2.84 and 12R-type BaMn 2/3 Ti 1/3 O 3 have been established by a combination of X-ray, neutron, and electron diffraction, and high-resolution electron microscopy. The 6H-type structure (space group P 6 3 / mmc ) can…
Tin-doped cadmium oxide films were deposited by electron beam evaporation technique. The structural, optical and electrical properties of the films were characterized. The X-ray diffraction (XRD) study reveals that the films are polycrystalline in nature. As composition and structure change due to the dopant ratio and…
An accumulative and integrative mechanoluminescence recording system consisting of a mechanoluminescent (ML) material and a photosensitive material was successfully demonstrated. The ML material developed in our laboratory is the world's first light-emitting material for practical use with the application of stress in…
Abstract The potential for decreasing the texture intensity generated during the bulk deformation of Mg alloys was investigated using a combination of contraction twinning, double (secondary) twinning and static recrystallization. A large number of twins was induced by tensile deformation at room temperature. Their vo…
BACKGROUND: Nephrogenic fibrosing dermopathy (NFD) has emerged as a clinicopathologic entity since 1997 and recently renamed as nephrogenic systemic fibrosis (NSF). The etiology and pathogenesis remain uncertain. Characteristic clinical presentation is described as diffuse thickening and hardening of the skin occurrin…
Thin films of LaMnXO (X=P, As, and Sb), which are isostructural compounds of the newly discovered superconductor, LaFeAsO, were grown epitaxially on MgO (001) substrates at ∼680 °C by pulsed laser deposition. Postdeposition thermal annealing at 1000 °C in evacuated silica glass ampoules improved the crystallinity and…
Abstract Intercalation of a wide variety of alkylammonium cations into the interlayer spaces of swelling clay minerals leads to many different applications, ranging from surface-charge measurements to rendering the clay compatible for the preparation of clay nanocomposites, but knowledge of the exact conformation of t…
The diffusive dynamics of hydration water in lysozyme is studied by high-resolution incoherent quasielastic neutron scattering spectroscopy and molecular dynamics (MD) simulations in a temperature range of 290 K<T<380 K. The hydration level of the protein powder sample is kept at h=0.35 gram of water per gram of dry p…
Conjugation of monoclonal antibodies to super paramagnetic nanoparticles is an effective method for cancer diagnosis and treatment. In this study the humanized anti her2/neu monoclonal antibody- Herceptin- was conjugated to super paramagnetic iron oxide (SPIO) nanoparticles using EDC method. The concentration of the c…
The organic charge-transfer (CT) complexes nanostructures of CuTCNQF 4 and AgTCNQF 4 (copper/silver tetrafluorotetracyanoquinodimethane) were successfully fabricated by organic solid-phase reaction. The morphologies of CuTCNQF 4 and AgTCNQF 4 nanostructures can be easily tuned by controlling the reaction temperature.…
Magnesium molybdate is considered as a promising material for cryogenic scintillation bolometers. The luminescence properties of MgMoO 4 have been investigated on single crystals grown from melts of stoichiometric and nonstoichiometric compositions and on crystals doped with Yb 3+ ions. Their optical properties are in…
Part of the metalloporphyrin fraction was separated from asphaltenes by a combination of reactive modification and affinity chromatography. The targeted vanadyl porphyrin complexes were modified by reaction with oxalyl chloride followed by a long chain alkylamine or perfluoroalkylaniline to produce an imido vanadium(I…
We study heat transport in semiconductor nanostructures by solving the Boltzmann transport equation by means of the discrete ordinate method. Relaxation time and phase and group velocity spectral dependencies are taken into account. The Holland model of phonon relaxation time is revisited and recalculated from dispers…
The evaluation of the temperature produced during adiabatic dissipative processes for a large class of engineering materials (metals and some polymers) remains a major subject of interest, notably in the fields of high-speed machining and impact dynamics.The hypothesis consisting in considering the proportion of plast…
Nickel-rich Ni–Mn–Ga Heusler alloys were prepared by arc melting and subsequent homogenization by annealing. A large magnetic entropy change was observed around 291 K in the alloy where martensite-austenite structural and ferro-para magnetic transitions almost coincide with each other. The effect of hydrostatic pressu…
Irradiation of methyl 3-methoxyl-2-naphthoate (2,3-NA) in methanol solution with light lambda > 280 nm produces anti-head-to-head cubane-like photocyclodimer 1 and [4+4] intermediate 2, which is, to the best of our knowledge, the first incidence of directly obtaining the intermediate in photocyclodimerization of napht…
This chapter contains sections titled: Abstract Introduction Theoretical Premises of the Research Results Conclusions References
A list of diatom taxa from inland waters of the northwestern United States is presented as a product of the author's bioassessment work over the last 40 years. The list is limited to taxa that have been identified from slides that are deposited in the Montana Diatom Collection. The list includes 1,348 species and infr…
Automatized microelectrochemical investigations are achieved using a scanning droplet cell. The area reproducibility for a 100 mum oxide spot is found to be better than 1%, a value typically difficult to reach even in macroscopic samples. A systematic change in color appearance is seen for oxide films with a thickness…