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Formkontrolle von Halbleiter‐ und Metalloxid‐Nanokristallen durch nichthydrolytische Kolloidverfahren

Young‐wook Jun、Jin‐sil Choi、Jinwoo Cheon2006-04-27Angewandte Chemie

Abstract Anorganische Nanokristalle mit gezielt präparierten Formen und Abmessungen haben einzigartige, formabhängige Eigenschaften und sind als Bausteine zur Herstellung von Nanofunktionseinheiten von großem Interesse. In diesem Aufsatz fassen wir die jüngsten Entwicklungen bei der Formkontrolle von kolloidalen Nanok…

Advanced Photocatalysis TechniquesQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications

Universal magnetic-field-driven metal-insulator-metal transformations in graphite and bismuth

Y. Kopelevich、J. C. Medina Pantoja、R.R. da Silva 等 4 位作者2006-04-27Physical Review B

Applied magnetic field induces metal-insulator and reentrant insulator-metal transitions in both graphite and rhombohedral bismuth. The corresponding transition boundaries plotted on the magnetic field---temperature $(B\text{\ensuremath{-}}T)$ plane nearly coincide for these semimetals and can be best described by pow…

Graphene research and applicationsQuantum and electron transport phenomenaSurface and Thin Film Phenomena

Optically and thermally stimulated luminescence characteristics of MgO:Tb3+

A.J.J. Bos、M. Prokić、J.C. Brouwer2006-04-27Radiation Protection Dosimetry

In this paper main optically stimulated luminescence (OSL) and thermoluminescence (TL) characteristics are presented of a newly synthesised material MgO doped with terbium (Tb) developed at the Institute of Nuclear Science, Vinca. A thermally stimulated emission spectrum showed the characteristic lines of Tb3+ in a wi…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesNuclear materials and radiation effects

Plasma wall interactions in ITER

G. Federici2006-04-27Physica Scripta

Designing the interface between a thermonuclear plasma and the solid material environment is arguably one of the highest technical challenges of ITER and of the successful development of future fusion power reactors. Carbon-based materials are recognized to have superior thermomechanical properties and do not melt, bu…

Magnetic confinement fusion researchDiamond and Carbon-based Materials ResearchFusion materials and technologies

Polyhydroxyalkanoate copolymers from forest biomass

Thomas M. Keenan、J. P. Nakas、Stuart W. Tanenbaum2006-04-27Journal of Industrial Microbiology & Biotechnology

The potential for the use of woody biomass in poly-beta-hydroxyalkanoate (PHA) biosynthesis is reviewed. Based on previously cited work indicating incorporation of xylose or levulinic acid (LA) into PHAs by several bacterial strains, we have initiated a study for exploring bioconversion of forest resources to technica…

biodegradable polymer synthesis and propertiesCatalysis for Biomass ConversionCarbon dioxide utilization in catalysis

Structural signatures of the unjamming transition at zero temperature

Leonardo E. Silbert、Andrea J. Liu、Sidney R. Nagel2006-04-27Physical Review E

We study the pair correlation function g(r) for zero-temperature, disordered, soft-sphere packings just above the onset of jamming. We find distinct signatures of the transition in both the first and split second peaks of this function. As the transition is approached from the jammed side (at higher packing fraction)…

Material Dynamics and PropertiesAdvanced Thermodynamics and Statistical MechanicsQuantum Electrodynamics and Casimir Effect

Emergence of inhomogeneous moments from spin liquid in the triangular-lattice Mott insulatorκ−(ET)2Cu2(CN)3

Yasuhiro Shimizu、Kazuya Miyagawa、Kazushi Kanoda 等 5 位作者2006-04-27Physical Review B

The static and dynamic local spin susceptibility of the organic Mott insulator $\ensuremath{\kappa}\text{\ensuremath{-}}(\mathrm{ET}{)}_{2}{\mathrm{Cu}}_{2}(\mathrm{CN}{)}_{3}$, a model material of the spin-1/2 triangular lattice, is studied by $^{13}\mathrm{C}$ NMR spectroscopy from room temperature down to $20\phant…

Physics of Superconductivity and MagnetismMagnetism in coordination complexesOrganic and Molecular Conductors Research

Buckling of single-walled carbon nanotubes upon bending: Molecular dynamics simulations and finite element method

Guoxin Cao、Xi Chen2006-04-27Physical Review B

The bending buckling behaviors of single-walled carbon nanotubes (SWCNTs) are systematically investigated by using both molecular dynamics (MD) simulation and finite element method (FEM), to analyze the relationships between critical bending buckling curvature, critical buckling strain and nanotube geometry parameters…

Carbon Nanotubes in CompositesGraphene research and applicationsBoron and Carbon Nanomaterials Research

Free transverse vibrations of nano-to-micron scale beams

Mingtian Xu2006-04-27Proceedings of the Royal Society A Mathematical Physical and Engineering Sciences

In the present work, the integral equation approach and the non-local elasticity theory are employed to investigate the free transverse vibrations of nano-to-micron scale beams. The frequency equation is analytically formulated into an eigenvalue problem of a matrix with an infinite order. The numerical calculation is…

Mechanical and Optical ResonatorsThermoelastic and Magnetoelastic PhenomenaNonlocal and gradient elasticity in micro/nano structures

Controlled Self‐Assembly Behavior of an Amphiphilic Bisporphyrin–Bipyridinium–Palladium Complex: From Multibilayer Vesicles to Hollow Capsules

Yongjun Li、Xiaofang Li、Yuliang Li 等 10 位作者2006-04-27Angewandte Chemie International Edition

Gas-filled: Porphyrin-based amphiphiles can self-assemble into multibilayer vesicles. These vesicles can be converted into hollow capsules and wormlike structures (see picture) by controlling the release rate of methanol encapsulated through changing the heating temperature and pattern.

Supramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine ChemistrySupramolecular Self-Assembly in Materials

Proteolytic Actuation of Nanoparticle Self‐Assembly

Todd J. Harris、Geoffrey von Maltzahn、Austin M. Derfus 等 5 位作者2006-04-27Angewandte Chemie International Edition

Sleeping giant: Inorganic nanoparticles are synthesized to exist in a latent form until proteolytic activation drives them to self-assemble into nanostructures with amplified magnetic properties. Binding of complimentary Fe3O4 nanoparticles is blocked by the attachment of inhibitory polymers that may be removed by pro…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Exotic radiation from a photonic crystal excited by an ultra-relativistic electron beam

N. Horiuchi、T. Ochiai、J. Inoue 等 12 位作者2006-04-27arXiv

We report the observation of an exotic radiation (unconventional Smith-Purcell radiation) from a one-dimensional photonic crystal. The physical origin of the exotic radiation is direct excitation of the photonic bands by an ultra-relativistic electron beam. The spectrum of the exotic radiation follows photonic bands o…

Materials Science

Weakly Coupled Motion of Individual Layers in Ferromagnetic Resonance

D. A. Arena、E. Vescovo、C. -C. Kao 等 5 位作者2006-04-27arXiv

We demonstrate a layer- and time-resolved measurement of ferromagnetic resonance (FMR) in a Ni81Fe19 / Cu / Co93Zr7 trilayer structure. Time-resolved x-ray magnetic circular dichroism has been developed in transmission, with resonant field excitation at a FMR frequency of 2.3 GHz. Small-angle (to 0.2 degree), time-dom…

Materials Science

A stress relaxation approach to glass transition

Kostya Trachenko2006-04-27Journal of Physics Condensed Matter

We propose that the onset of a glass transition can be defined as the point at which a supercooled liquid acquires the stress relaxation mechanism of a solid glass. We translate this condition into the rate equation for local relaxation events. This equation simultaneously gives two main signatures of a glass transiti…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesGlass properties and applications

Surface roughness and hydrodynamic boundary conditions

Olga I. Vinogradova、Gleb E. Yakubov2006-04-27Physical Review E

We report results of investigations of a high-speed drainage of thin aqueous films squeezed between randomly nanorough surfaces. A significant decrease in the hydrodynamic resistance force as compared with that predicted by Taylor's equation is observed. However, this reduction in force does not represent the slippage…

Surface Modification and SuperhydrophobicityAdhesion, Friction, and Surface InteractionsParticle Dynamics in Fluid Flows

Nanofibril Self-Assembly of an Arylene Ethynylene Macrocycle

Kaushik Balakrishnan、Aniket Datar、Wei Zhang 等 10 位作者2006-04-27Journal of the American Chemical Society

Nanofibril structures have been fabricated from an arylene ethynylene macrocycle (AEM), which consists of a square frame corner-joined by four carbazole moieties. The fabrication was performed through a gelating process by cooling a warm, homogeneous solution in cyclohexane at high temperature (e.g., 100 degrees C) to…

Lipid Membrane Structure and BehaviorSupramolecular Chemistry and ComplexesSupramolecular Self-Assembly in Materials

Synthesis, Photochemistry, and Electrochemistry of Single-Wall Carbon Nanotubes with Pendent Pyridyl Groups and of Their Metal Complexes with Zinc Porphyrin. Comparison with Pyridyl-Bearing Fullerenes

Mercedes Álvaro、Pedro Atienzar、Pilar de la Cruz 等 9 位作者2006-04-27Journal of the American Chemical Society

A soluble, functionalized Py-SWNT has been synthesized and characterized by solution (1)H and (13)C NMR, FT-Raman, and electron microscopy. Experimental data indicate that Py-SWNT has short tubes with pentyl esters at the tips and pyridyl isoxazolino units along the walls. The synthesis of Py-SWNT is based on a 1,3-di…

Carbon Nanotubes in CompositesMolecular Junctions and NanostructuresFullerene Chemistry and Applications

Effect of heavy ion irradiation on microstructure and electron density distribution of zirconium alloy characterised by X-ray diffraction technique

A. Sarkar、P. Mukherjee、P. Barat2006-04-27arXiv

Different techniques of the X-ray Diffraction Line Profile Analysis (XRDLPA) have been used to assess the microstructure of the irradiated Zr-1.0%Nb-1.0%Sn-0.1%Fe alloy. The domain size, microstrain, density of dislocation and the stacking fault probabilities of the irradiated alloy have been estimated as a function o…

Materials Science

Optical switching in graded plasmonic waveguides

J. J. XIAO、K. Yakubo、K. W. Yu2006-04-27arXiv

A new mechanism of longitudinal confinement of optical energy via coupled plasmon modes is proposed in chains of noble metal nanoparticles embedded in a graded dielectric medium, which is analogous to the confinement of electrons in semiconductor quantum wells. In these systems, one can control the transmission of opt…

Materials ScienceSoft Condensed Matterphysics.comp-phphysics.optics

Pressure-Induced Metal-Insulator Transition inLaMnO3Is Not of Mott-Hubbard Type

A. Yamasaki、M. Feldbacher、Yi‐feng Yang 等 5 位作者2006-04-27Physical Review Letters

Calculations employing the local density approximation combined with static and dynamical mean field theories (LDA+U and LDA+DMFT) indicate that the metal-insulator transition observed at 32 GPa in paramagnetic LaMnO3 at room temperature is not a Mott-Hubbard transition, but is caused by orbital splitting of the major…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsAdvanced Condensed Matter Physics