Materials Literature
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A sign of the times: A 1:1 tweezer complex consisting of an achiral bis(zinc porphyrin) and (R,R)-1,2-diaminocyclohexane has been characterized by X-ray crystallographic analysis (see picture, Zn red, N blue). This has enabled a full and unambiguous rationalization of the highly efficient transfer of chirality informa…
Abstract We discuss dispersion forces, beginning with toy models that illustrate the limitations of various standard approaches. For metallic cohesion of very thin layers, we show that because the local density approximation (LDA) misses distant dispersion interactions, it also makes significant errors in the maximum…
We demonstrate a universal correlation between the spectral linewidth and position of the excitonic transition in the spectral jitter observed from single elongated colloidal quantum dots. Breaking the symmetry of electron and hole confinement as well as of the spatial directions for surface charge diffusion enables u…
Abstract The synthesis and characterization of novel first‐ and second‐generation true dendritic reversible addition–fragmentation chain transfer (RAFT) agents carrying 6 or 12 pendant 3‐benzylsulfanylthiocarbonylsulfanylpropionic acid RAFT end groups with Z‐group architecture based on 1,1,1‐hydroxyphenyl ethane and t…
Porous alumina templates have been used to prepare dendrimer nanotubes with uniform size and orientation as well as high aspect ratios by a layer-by-layer deposition technique (see SEM image). The tubes may be released from or located in the template pores. Diffusion limitations arising from the pore geometry lead to…
We report on a thin polyelectrolyte film (mixed polyelectrolyte brush) with a gradual change of the composition (ratio between two different oppositely charged surface-grafted weak polyelectrolytes) across the sample. The gradient of surface composition creates a gradient in surface charge density and, consequently, a…
In the field of the immobilisation of high-activity-level and long-life radwaste (HAVL) for a deep underground repository, several phosphate matrices were already proposed as good candidates to delay the release of actinides in the near-field of such disposal. Among them, thorium phosphate–diphosphate (TPD), monazites…
A single-crystalline film of ${\mathrm{S}\mathrm{r}}_{2}{\mathrm{C}\mathrm{o}\mathrm{O}}_{4}$ with square-lattice ${\mathrm{C}\mathrm{o}\mathrm{O}}_{2}$ sheets (${\mathrm{K}}_{2}{\mathrm{N}\mathrm{i}\mathrm{F}}_{4}$-type structure) was synthesized, and its electronic properties were characterized. The compound exhibit…
For the first time,we report the effect of pentavalent subtitution at the Mn site of La(0.67)Ca(0.33)MnO(3). The ferromagnetic -metallic ground state modifies to a cluster-glass insulator beyond x=0.03. The observed suppression in the transition temperatures (39K/at.%) is the largest reported for the Mn site subtitute…
The spin-dependent density of states and the density of spin polarization of an InAs-based two-dimensional electron gas with the Rashba spin-orbit coupling under an intense terahertz laser field are investigated by utilizing the Floquet states to solve the time-dependent Schrödinger equation. It is found that both den…
Accurate ab-initio pseudopotential calculations within density functional theory in the LDA approximation have been performed for structural properties and stability of ZnSe/GaAs(001) defected heterostructures. There is a strong experimental evidence that ZnSe/GaAs heterostructures with minimum stacking fault density…
Using a Bayesian approach a general method is developed to assess error bars on predictions made by models fitted to data. The error bars are estimated from fluctuations in ensembles of models sampling the model-parameter space with a probability density set by the minimum cost. The method is applied to the developmen…
Mononuclear gold complexes in zeolite NaY were synthesized from initially physisorbed Au(CH 3 ) 2 (C 5 H 7 O 2 ) and characterized in reactive atmospheres by X-ray absorption and infrared spectroscopies. Under conditions of CO oxidation catalysis at 298 K and 760 Torr in a flow reactor, the gold remained as mononuclea…
Electrophoretically deposited single-wall carbon nanotube (SWCNT) films on optically transparent electrodes are photoelctrochemically active and generate photocurrent upon visible excitation. A low photon-to-current conversion efficiency of 0.15% suggests that most of the photogenerated charge carriers are lost in the…
Microorganisms point the way: The silica cell walls of various diatoms were covalently functionalized with DNA by using straightforward chemical procedures and then used as templates for the sequence-specific assembly and 3D hierarchical arrangement of prefabricated DNA-modified gold nanoparticles. The DNA was used to…
We report on a multiband microscopic theory of many-exciton complexes in self-assembled quantum dots. The single particle states are obtained by three methods: single-band effective-mass approximation, the multiband $k\cdot p$ method, and the tight-binding method. The electronic structure calculations are coupled with…
Magnetic instability in both ultra-pure and carbon-doped MgB2 films is investigated by magneto-optical imaging, transport and bulk magnetization measurements. In the carbon-doped MgB2 thin film, familiar dendritic flux-jump patterns were observed at low temperature as reported in previous experiments. In the ultra-pur…
A new far-field optical microscopy technique capable of reaching nanometer-scale resolution has been developed recently using the in-plane image magnification by surface plasmon polaritons. This microscopy is based on the optical properties of a metal-dielectric interface that may, in principle, provide extremely larg…
We propose a model which could explain some of the unusual magnetic properties observed for the one-dimensional helical spin system $\mathrm{Co}{(hfac)}_{2}\mathrm{N}\mathrm{I}\mathrm{T}\mathrm{Ph}\mathrm{O}\mathrm{Me}$. One of these properties is that the magnetization shows some plateaus if a magnetic field is appli…
Light illumination of thin crystals of CDW conductor TaS$_3$ is found to result in dramatic changes of both linear ($G$) and nonlinear conduction. The increase of $G$ is accompanied by suppression of the collective conduction, growth of the threshold field $E_T$, and appearance of the switching and hysteretic behavior…