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Study on combustion property and synergistic effect of intumescent flame retardant styrene butadiene rubber with metallic oxides

Qingqing Liu、Lei Song、Hongdian Lu 等 6 位作者2009-01-09Polymers for Advanced Technologies

Abstract Effect of metallic oxides on flame retardancy and the thermal stability of styrene butadiene rubber (SBR) composites based on ammonium polyphosphate (APP) and pentaerythritol (PER) was studied by the limiting oxygen index (LOI), UL 94, the cone calorimeter tests, and thermogravimetry analysis (TGA), respectiv…

Polymer Nanocomposites and PropertiesFlame retardant materials and propertiesSynthesis and properties of polymers

Fluorescence Dynamics of Directly Meso−Meso Linked Porphyrin Rings Probed by Single Molecule Spectroscopy

Hyejin Yoo、Jaesung Yang、Yasuyuki Nakamura 等 6 位作者2009-01-09Journal of the American Chemical Society

Porphyrin rings CZ4, CZ6, and CZ8 that respectively comprise four, six, and eight porphyrins, immobilized in a thin PMMA film, have been investigated using single molecule fluorescence spectroscopy with a focus on the influences of the overall structural rigidity as the ring size of porphyrin array increases. Neighbor…

Porphyrin and Phthalocyanine ChemistryMolecular Junctions and NanostructuresLuminescence and Fluorescent Materials

Thermal Comfort Properties of Wearing Caps from Various Textiles

Youngmin Jun、Chung Hee Park、Huen-Sup Shim 等 4 位作者2009-01-09Textile Research Journal

The purpose of this research was to explore the effects of textile properties on the microclimate inside caps and on subjective wearing sensations. Physical tests on heat and moisture transfer properties of cap fabrics were conducted, as well as tests on the sensations from subjects wearing the caps. The temperature a…

Textile materials and evaluationsIndustrial Vision Systems and Defect DetectionColor perception and design

Carboxymethyl Cellulose Treatment As a Method to Inhibit Vessel Picking Tendency in Printing of Eucalyptus Pulp Sheets

Minna Rakkolainen、Eero Kontturi、Akira Isogai 等 6 位作者2009-01-09Industrial & Engineering Chemistry Research

This article presents an industrially feasible method to effectively reduce vessel picking tendency by a simple chemical modification of pulp. ECF-bleached eucalyptus kraft pulp was treated with carboxymethyl cellulose (CMC) under specified conditions. The aim was to study the effects on vessel element structure and v…

Advanced Cellulose Research StudiesLignin and Wood ChemistryMaterial Properties and Processing

Highly sensitive carbon nanotube-embedding gas sensors operating at atmospheric pressure

Ju‐Hyung Yun、Joondong Kim、Yun Chang Park 等 6 位作者2009-01-09Nanotechnology

Highly sensitive palladium (Pd) decorated carbon nanotube (CNT) embedding gas sensors working at atmospheric pressure were fabricated. Two types of gas sensors of bare CNTs and Pd nanoparticle decorated CNTs were synthesized by dielectrophoresis. The CNT-containing solution was dropped onto the patterned-platinum elec…

Carbon Nanotubes in CompositesGas Sensing Nanomaterials and SensorsMechanical and Optical Resonators

Kinetics of Epoxidation of Hydroxyl-Terminated Polybutadiene with Hydrogen Peroxide under Phase Transfer Catalysis

Qingfa Wang、Xiangwen Zhang、Li Wang 等 4 位作者2009-01-09Industrial & Engineering Chemistry Research

The epoxidation of hydroxyl-terminated polybutadiene (HTPB) via phase transfer catalysis (PTC) using H 2 O 2 as the oxidant and ammonium tungstate hydrate and phosphoric acid as the cocatalysts was successfully carried out in an acidic solution/organic solvent two-phase medium. The microstructures of original and epox…

biodegradable polymer synthesis and propertiesFlame retardant materials and propertiesSynthesis and properties of polymers

A Simple Method To Improve the Clarity and Rheological Properties of Polymer/Clay Nanocomposites by Using Fractionated Clay Particles

Bani H. Cipriano、Takashi Kashiwagi、Xin Zhang 等 4 位作者2009-01-09ACS Applied Materials & Interfaces

We present a simple method to improve the transparency and rheological properties of polystyrene/organoclay nanocomposites. Such composites are typically prepared using organophilic derivatives of commercial montmorillonite (MMT) clays that contain a wide range of particle sizes. Our approach is to fractionate the nat…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesTribology and Wear Analysis

Photodynamics of Charge Separation and Recombination in Solid Alternating Films of Phthalocyanine or Phthalocyanine−Fullerene Dyad and Perylene Dicarboximide

Heli Lehtivuori、Tatu Kumpulainen、Matti Hietala 等 8 位作者2009-01-09The Journal of Physical Chemistry C

Alternate bilayer structures of N, N ′-bis(2,5-di- tert -butylphenyl)-3,4,9,10-perylene dicarboximide (PDI), free-base phthalocyanines (Pc), and double-linked free-base phthalocyanine−fullerene dyad (Pc−C 60 ) were prepared by the Langmuir−Schäfer method and studied using a range of optical spectroscopy methods includ…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesSpectroscopy and Quantum Chemical Studies

Some Studies on Water Permeability of Nonwoven Fabrics

Asis Patanaik、Rajesh D. Anandjiwala2009-01-09Textile Research Journal

In this paper we report on the water permeability behavior of nonwoven fabrics produced from flax fibers. Three different types of needle punched nonwoven fabrics are produced by varying the depths of needle penetration during the needle punching process. The pore size and its distribution in the nonwoven fabrics are…

Advanced Sensor and Energy Harvesting MaterialsTextile materials and evaluationsAerosol Filtration and Electrostatic Precipitation

Analysis of Polymeric Braided Tubular Structures Intended for Medical Applications

Mehmet Yüksekkaya、Sabit Adanur2009-01-09Textile Research Journal

In this study, monofilament tubular braided structures were fabricated and their performances were analyzed. The braided tubes are in three-dimensional form, made of polyester monofilaments intended for use in medical applications. This type of structure, called a stent, is used to open clogged arteries and veins by e…

Textile materials and evaluationsMechanical stress and fatigue analysisEngineering and Materials Science Studies

The synthesis and fabrication of horizontally aligned single-walled carbon nanotubes suspended across wide trenches for infrared detecting application

Fubo Rao、Xiang Liu、Tie Li 等 5 位作者2009-01-09Nanotechnology

Horizontally aligned single-walled carbon nanotubes (SWNTs) were directly grown across trenches produced on SiO(2)/Si substrate, forming suspended aligned SWNTs over the trenches, and were fabricated with simple methods for infrared (IR) detection application. The horizontally aligned SWNTs can grow across trenches as…

Carbon Nanotubes in CompositesNanowire Synthesis and ApplicationsMechanical and Optical Resonators

Physical properties of biopolymers containing natamycin and rosemary extract

Hasan Türe、Erdal Eroğlu、Banu Özen 等 4 位作者2009-01-09International Journal of Food Science & Technology

Summary Antifungal biopolymers were prepared by incorporating natamycin (NA) and NA + rosemary extract (RE) into wheat gluten (WG) and methyl cellulose (MC) films. Interaction between antimicrobial agents and biopolymers was determined with mid‐infrared spectroscopy and scanning electron microscopy (SEM). Water vapour…

Postharvest Quality and Shelf Life ManagementNanocomposite Films for Food PackagingComposting and Vermicomposting Techniques

Optimization and Characterization of Pulp Extracted from the Agave Americana L. Fibers

Mounir Jaouadi、Slah Msahli、Faouzi Sakli2009-01-09Textile Research Journal

The influence of temperature, pulping time and soda concentration on the yield, kappa index, brightness and fiber density of Agave Americana L. pulp has been studied. Using a factorial design to identify the optimum operating conditions, equations relating the dependent variables to the operational variables of the pu…

Advanced Cellulose Research StudiesLignin and Wood ChemistryBotanical Research and Applications

Electronic conduction in nematic phase of small molecules

Keiji Tokunaga、Yukiko Takayashiki、Hiroaki Iino 等 4 位作者2009-01-09Physical Review B

We investigated charge-carrier transport in the nematic phase of small molecules such as 2-phenylbenzothiazoles by time-of-flight experiments, in which the conduction mechanism has been considered to be ionic. As a result, we established the hole and electron transports in the nematic phase of highly purified samples:…

Liquid Crystal Research AdvancementsIonic liquids properties and applicationsPhotochemistry and Electron Transfer Studies

A Nontwisted, Ferromagnetically Coupled MnIII3O Triangular Complex from the Use of 2,6-Bis(hydroxymethyl)-p-cresol

Christos Lampropoulos、Khalil A. Abboud、Theocharis C. Stamatatos 等 4 位作者2009-01-09Inorganic Chemistry

The reaction between Mn(O(2)CMe)(2) x 4 H(2)O and hmcH(3) [hmcH(3) = 2,6-bis(hydroxymethyl)-p-cresol] in CH(2)Cl(2) in the presence of NEt(3) affords the Mn(III)(3) complex [NEt(3)(CH(2)Cl)](2)[Mn(3)O(hmcH)(3)(hmcH(2))(3)] (1). The anion of 1 contains a [Mn(III)(3)(mu(3)-O)](7+) triangular core, with the central O(2-)…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Catalyzed Oxygenation Mechanisms

High‐resolution structures of collagen‐like peptides [(Pro‐Pro‐Gly)4‐Xaa‐Yaa‐Gly‐(Pro‐Pro‐Gly)4]: Implications for triple‐helix hydration and Hyp(X) puckering

Kenji Okuyama、Chizuru Hongo、Guanghan Wu 等 9 位作者2009-01-09Biopolymers

Abstract Structures of (Pro‐Pro‐Gly)4‐Xaa‐Yaa‐Gly‐(Pro‐Pro‐Gly)4 (ppg9‐XYG) where (Xaa, Yaa) = (Pro, Hyp), (Hyp, Pro) or (Hyp, Hyp) were analyzed at high resolution using synchrotron radiation. Molecular and crystal structures of these peptides are very similar to those of the (Pro‐Pro‐Gly)9 peptide. The results obtai…

Chemical Synthesis and AnalysisProtein Hydrolysis and Bioactive PeptidesCollagen: Extraction and Characterization

Fatigue Behavior of Filament Warp Yarns under Cyclic Loads during Weaving Process

Hooshang Nosraty、Ali Asghar Asgharian Jeddi、Mostafa Jamshidi Avanaki2009-01-09Textile Research Journal

Warp yarns in their different applications during weaving processes are often required to support loads, either in a static manner (simple tensile) or in a dynamic one (fatigue). For this reason, the investigation into the variations of the mechanical behavior of warp yarns during weaving condition is important. The p…

Mechanical Behavior of CompositesTextile materials and evaluationsStructural Analysis and Optimization

Ranking the Lacunary (Bu4N)9{H[α2-P2W17O61]} Polyoxometalate’s Stabilizing Ability for Ir(0)n Nanocluster Formation and Stabilization Using the Five-Criteria Method Plus Necessary Control Experiments

Christopher R. Graham、Lisa S. Ott、Richard G. Finke2009-01-09Langmuir

The primary goal of the present studies is to rank the monoprotonated, lacunary Wells-Dawson-type polyoxometalate [H[alpha2-P2W17O61]](9-) as a stabilizing anion for the formation and subsequent stabilization of Ir(0)(n) nanoclusters in acetone using the five-criteria method developed previously ( Ozkar , S. ; Finke ,…

Polyoxometalates: Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Thermal Stable Cetyltrimethylammonium−Magadiites: Influence of the Surfactant Solution Type

Fethi Kooli、Yan Liu2009-01-09The Journal of Physical Chemistry C

The reaction of protonated magadiite with the cationic surfactant cetyltrimethylammonium (C16TMA) was studied using different C16TMA solutions. The intercalation was achieved from C16TMAOH solution. However, only adsorption of C16TMA cations occurred on the external silicate surfaces from C16TMABr and C16TMACl solutio…

Mesoporous Materials and CatalysisClay minerals and soil interactionsLayered Double Hydroxides Synthesis and Applications

Crystallographic Observation of Dynamic Gas Adsorption Sites and Thermal Expansion in a Breathable Fluorous Metal–Organic Framework

Yang Chi、Xiaoping Wang、Mohammad A. Omary2009-01-09Angewandte Chemie

Abstract Akkordeonspiel: Beim Abkühlen eines Einkristalls eines mikroporösen fluorigen metall‐organischen Gerüsts unter Umgebungsbedingungen tritt bei Gasadsorption ein starkes Atmen auf, und mehrere N2‐Moleküle werden in Kanäle und Käfige gefüllt (siehe Bild). Im Vakuum zeigt das Gerüst eine deutliche positive thermi…

Metal-Organic Frameworks: Synthesis and ApplicationsAdvanced Battery Materials and TechnologiesThermal Expansion and Ionic Conductivity