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Thermodynamic Properties of Lanthanides and Actinides for Reductive Extraction of Minor Actinides

Taro TODA、Takehiro Maruyama、Kimikazu Moritani 等 5 位作者2009-01-01Journal of Nuclear Science and Technology

The excess thermodynamic quantities of lanthanides and actinides in molten salts and liquid metals were studied for reductive extraction of minor actinides. The excess enthalpies and entropies of those elements in the molten chloride phase were found to be correlated with the ionic radii of metal ions possibly due to…

Radioactive element chemistry and processingNuclear Materials and PropertiesMolten salt chemistry and electrochemical processes

Unique two-fold interpenetration of 3D microporous 3d–4f heterometal–organic frameworks (HMOF) based on a rigid ligand

Ming Fang、Bin Zhao、Ya Zuo 等 7 位作者2009-01-01Dalton Transactions

Six heterometal-organic frameworks, {[LnCu1.5(BPDC)3(H2O)2].mH2O}n (Ln = Gd (1, m = 4.75), Tb (2, m = 3.75), Eu (3, m = 5), Ho (4, m = 2), Yb (5, m = 2.25), BPDC = 4,4-dicarboxylate-2,2-dipyridine anion), and {[LuCu1.5(BPDC)3(H2O)1.5].2.5H2O}n (6), have been synthesized under hydrothermal conditions. The structure ana…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Magnetic orientation and magnetic anisotropy in paramagnetic layered oxides containing rare-earth ions

Shigeru Horii、Atsushi Ishihara、T. Fukushima 等 9 位作者2009-01-01Science and Technology of Advanced Materials

The magnetic anisotropies and easy axes of magnetization at room temperature were determined, and the effects of rare-earth (RE) ions were clarified for RE-based cuprates, RE-doped bismuth-based cuprates and RE-doped Bi-based cobaltite regarding the grain orientation by magnetic field. The easy axis, determined from t…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsMagnetic Properties of Alloys

One-pot controlled synthesis of biodegradable and biocompatible co-polymer micelles

Aram Saeed、Sabrina Dey、Steven M. Howdle 等 5 位作者2009-01-01Journal of Materials Chemistry

A facile route to biocompatible poly(lactic acid-co-glycolic acid)-co-poly(ethyleneglycolmethacrylate) (PLGA–PEGMA) block co-polymers is described utilising a combination of ring-opening polymerisation (ROP) and reversible addition fragmentation transfer (RAFT) methods. A series of PLGA–PEGMA polymers varying in co-mo…

Nanoparticle-Based Drug DeliveryAdvanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and properties

First structurally characterized mono- and dinuclear ruthenium complexes derived from zwitterionic quinonoid ligands

Hari Sankar Das、Atanu Kumar Das、R. Pattacini 等 6 位作者2009-01-01Chemical Communications

Electron transfer and delocalization of the pi systems were investigated in mono- and dinuclear Ru complexes with the zwitterionic ligand L = N,N'-diisopropyl-2-amino-5-alcoholate-1,4-benzoquinonemonoiminium.

Metal complexes synthesis and propertiesMagnetism in coordination complexesPorphyrin and Phthalocyanine Chemistry

Estimation of Planar Anisotropy of the r-Value in Ferritic Stainless Steel Sheets

Jun-ichi Hamada、Kazuyuki Agata、Hirofumi Inoue2009-01-01MATERIALS TRANSACTIONS

Planar anisotropies of r-values are calculated from crystallite orientation distribution functions (ODFs) by using the Taylor theory. These values are compared with experimentally obtained values for two kinds of ferritic stainless steel sheets with different planar anisotropies of the r-values and different texture g…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsMetallurgy and Material Forming

Interfacial Microstructure of Aluminum/Metallic Glass Lap Joints Fabricated by Magnetic Pulse Welding

Mitsuhiro Watanabe、Shinji Kumai、Go Hagimoto 等 5 位作者2009-01-01MATERIALS TRANSACTIONS

Magnetic pulse welding was applied to the lap joining of crystalline pure aluminum and metallic glass (Zr48Cu36Al8Ag8 and Cu50Zr42.5Al7.5) and interfacial microstructure was examined. The metallic glass fractured in brittle manner in conventional plate layout. However, Al/metallic glass joints were successfully obtain…

Glass properties and applicationsMetallic Glasses and Amorphous AlloysLaser Material Processing Techniques

Sacrificial layer electrophoretic deposition of free-standing multilayered nanoparticle films

Saad A. Hasan、Dustin W. Kavich、James H. Dickerson2009-01-01Chemical Communications

Sacrificial layer electrophoretic deposition (SLED) is a technique to assemble nanoparticles that yields free-standing, multilayered nanoparticle films with macroscopic lateral dimensions after the sacrificial layer is dissolved.

Quantum Dots Synthesis And PropertiesMolecular Junctions and NanostructuresElectrophoretic Deposition in Materials Science

Like-charge interactions between colloidal particles are asymmetric with respect to sign

Esther W. Gomez、Nathan Clack、Hung‐Jen Wu 等 4 位作者2009-01-01Soft Matter

Two-dimensional dispersions of colloidal particles with a range of surface chemistries and electrostatic potentials are characterized under a series of solution ionic strengths. A combination of optical imaging techniques are employed to monitor both the colloid structure and the electrostatic surface potential of ind…

Material Dynamics and PropertiesPickering emulsions and particle stabilizationElectrostatics and Colloid Interactions

Effective Temperature for Analysis of Permanent Deformation and Fatigue Distress on Asphalt Mixtures

Mohamed El-Basyouny、Myung Goo Jeong2009-01-01Transportation Research Record Journal of the Transportation Research Board

The determination of a single test temperature for asphalt mixtures to simulate major distresses on flexible pavement is quite significant in characterizing asphalt mixtures. It is apparent that the practical use of a single temperature would reduce testing needs as well as relevant analysis efforts. Effective tempera…

Asphalt Pavement Performance EvaluationInfrastructure Maintenance and MonitoringMaterial Properties and Failure Mechanisms

Solid Solution Phases in the Olivine-Type LiMnPO[sub 4]/MnPO[sub 4] System

Guoying Chen、Thomas J. Richardson2009-01-01Journal of The Electrochemical Society

Nonstoichiometry is reported in the system. As lithium is removed from crystalline by chemical or electrochemical methods, the resulting two-phase mixture consists of stoichiometric and a delithiated phase, , whose lattice parameters depend on the global extent of delithiation and on the crystalline domain size of the…

Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesTransition Metal Oxide Nanomaterials

Minimum quantity lubrication (MQL) grinding using vitrified cbn wheels

Bin Shen、Albert J. Shih2009-01-01OpenAlex

This research investigated the vitrified bond CBN wheel for MQL grinding of cast iron. Grinding under the dry, MQL, and flood cooling conditions were evaluated and compared in terms of forces, surface roughness, workpiece temperature and energy partition. Compared to flood cooling, CBN MQL grinding can achieve the sam…

Advanced machining processes and optimizationAdvanced Surface Polishing TechniquesMetal Alloys Wear and Properties

Preparation, Characterization and Catalytic Activity of Transition Metal Oxide Nanocrystals

Gurdip Singh、Inder Pal Singh Kapoor、Shalini Dubey 等 4 位作者2009-01-01Journal of Scientific Conference Proceedings

Nanocrystals of four transition metal oxides (TMOs) were prepared by a novel quick precipitation method and characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). From the XRD patterns, average particle sizes for CuO, NiO, Co 2 O 3 , MnO 2 are calculated to be 15 nm, 4 nm, 13 nm, 40 nm, r…

Energetic Materials and CombustionThermal and Kinetic AnalysisChemical and Physical Properties of Materials

Preparation of Insulin-Containing Microcapsules by a Layer-by-Layer Deposition of Concanavalin A and Glycogen

Katsuhiko Sato、Daisuke Kodama、Yoshihiro Endo 等 4 位作者2009-01-01Journal of Nanoscience and Nanotechnology

The sugar sensitive microcapsules were prepared by a layer-by-layer deposition of concanavalin A (Con A) and glycogen on a calcium carbonate particle containing fluorescein-labeled insulin (F-insulin). The Con A/glycogen multilayer capsules were formed through sugar-lectin interactions by using inner and outer poly(et…

Microfluidic and Capillary Electrophoresis ApplicationsPolymer Surface Interaction StudiesInnovative Microfluidic and Catalytic Techniques Innovation

Mineral Precipitation Kinetics

Bertrand Fritz、Claudine Noguera2009-01-01Reviews in Mineralogy and Geochemistry

Research Article| January 01, 2009 Mineral Precipitation Kinetics Bertrand Fritz; Bertrand Fritz Laboratoire d'Hydrologie et de Géochimie de Strasbourg, Université de Strasbourg/EOST, CNRS, 1 rue Blessig, F-67084 Strasbourg Cedex, France, bertrand.fritz@illite.u-strasbg.fr Search for other works by this author on: GSW…

Spectroscopy and Quantum Chemical StudiesIron oxide chemistry and applicationsCrystallization and Solubility Studies

Exploring the use of APTS as a fluorescent reporter dye for continuous glucose sensing

Zachary Sharrett、Soya Gamsey、Lacie C. Hirayama 等 7 位作者2009-01-01Organic & Biomolecular Chemistry

The anionic fluorescent dye, aminopyrene trisulfonic acid (APTS), was synthesized and used in a solution-based two-component glucose-sensing system comprising the dye and a boronic acid-appended viologen. The fluorescence of the dye was quenched in the presence of the viologen and the fluorescence restored upon glucos…

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsAnalytical Chemistry and Sensors

Solubility test in some phosphate rocks and their potential for direct application in soil.

Abdollatif Gholizadeh、Mohammadreza Ardalan、M. M. Tehrani 等 5 位作者2009-01-01OpenAlex

Abstract: There are various methods to evaluating phosphate rock for direct application. The first approach is solubility test of Phosphate Rocks (PR) using chemical extractant. In this study to compare the effectiveness of direct application of PRs, two samples of a sedimentary unbeneficiated PR from Lar mine of Yaso…

Geochemistry and Elemental AnalysisClay minerals and soil interactionsPhosphorus and nutrient management

On the relation of microstructure and impact toughness characteristics of DSAW steel of grade API X70

S.H. Hashemi、Dariush Mohammadyani、M. Pouranvari 等 4 位作者2009-01-01Fatigue & Fracture of Engineering Materials & Structures

ABSTRACT In this research, mechanical characteristics of double submerged arc‐welded line pipe steel of grade API X70 (70 ksi yield strength) were investigated. Different experimental examinations including chemical analysis, microstructural investigation, microhardness, tensile and Charpy tests and standard fractogra…

Microstructure and Mechanical Properties of SteelsHydrogen embrittlement and corrosion behaviors in metalsWelding Techniques and Residual Stresses

Colorimetric recognition of the coralyne–poly(dA) interaction using unmodified gold nanoparticle probes, and further detection of coralyne based upon this recognition system

Zhaozi Lv、Hui Wei、Bingling Li 等 4 位作者2009-01-01The Analyst

Among the functional nucleic acids studied, adenine-rich nucleic acids have attracted attention due to their critical roles in many biological processes and self-assembly-based nanomaterials, especially deoxyribonucleic acids (abbreviated as poly(dA)). Therefore the ligands binding to poly(dA) might serve as potential…

Advanced biosensing and bioanalysis techniquesMolecular Sensors and Ion DetectionLuminescence and Fluorescent Materials

Co2P nanostructures constructed by nanorods: hydrothermal synthesis and applications in the removal of heavy metal ions

Yonghong Ni、Jun Li、Lina Jin 等 6 位作者2009-01-01New Journal of Chemistry

In this paper, we report the successful synthesis of cobalt phosphide (Co2P) nanostructures built up of nanorodsvia a simple hydrothermal route using white phosphorus (WP), sodium hypophosphite and cobalt dichloride as starting reactants in the presence of polyvinylpyrrolidone (PVP, 30 K). The as-obtained product was…

Electrocatalysts for Energy ConversionMolecular Junctions and NanostructuresCopper-based nanomaterials and applications