Materials Literature
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Rod-shaped polyaniline (PANI)-barium ferrite nanocomposite was synthesized by in situ polymerization of aniline in the presence of BaFe(12)O(19) nanoparticles with diameters of 60-80 nm. The structure, morphology and properties of the nanocomposite were measured using powder x-ray diffraction, Fourier transform infrar…
The cyclophosphazene hydrazide gem-N3P3Ph2[N(Me)NH2]4 was reacted with o-hydroxybenzaldehyde to afford the multisite coordination ligand gem-N3P3Ph2[N(Me)N=CHC6H4-2-OH]4 (LH4). The latter reacted with copper(II) salts to afford a novel tetranuclear copper assembly {N3P3Ph2[N(Me)N=CHC6H4-2-O]4Cu2}2, which contains, rem…
The anionic {Fe(NO)2}(9) DNIC[(NO)2Fe(C3H3N2)2](-) (2) (C3H3N2 = deprotonated imidazole) containing the deprotonated imidazole-coordinated ligands and DNICs [(NO)2Fe(C3H3N2)(SR)](-) (R = (t)Bu(3), Et(4), Ph(5)) containing the mixed deprotonated imidazole-thiolate coordinated ligands, respectively, were synthesized by…
Cerium oxide films equivalent to 2 ML of CeO 2 were grown at 520 K in an oxygen atmosphere on a clean Cu(111) substrate in order to prepare a model catalytic system. This “inverse model catalyst” was characterized by low-energy electron diffraction (LEED), X-ray photoelectron spectroscopy (XPS) of core levels, and res…
We report the quadratic nonlinearity of one- and two-electron oxidation products of the first series of transition metal complexes of meso-tetraphenylporphyrin (TPP). Among many MTPP complexes, only CuTPP and ZnTPP show reversible oxidation/reduction cycles as seen from cyclic voltammetry experiments. While centrosymm…
High Resolution Image Download MS PowerPoint Slide We demonstrate that commonly face-centered cubic (fcc) metallic nanowires can be stabilized in hexagonal structures even when their surface energy contribution is relatively small. With a modified electrochemical growth process, we have grown purely single-crystalline…
Abstract A highly pH sensitive water‐soluble polyfluorene derivative (PFP‐aa) has been designed and synthesized by Suzuki coupling reaction. The PFP‐aa contains two amino and four carboxylic acid groups in each repeat unit (RU). The protonation and deprotonation of both the carboxylate and amine are controlled by medi…
Abstract We report the remote growth of carbon nanowalls in a plasma beam sustained by an expanding argon radiofrequency discharge and injected with a small amount of acetylene in the presence of hydrogen as active gas. The growth process was investigated by varying the mass flow rates, ratio and nature of gases (argo…
The ability to predict ferroresonance significantly relies on the accuracy of the transformer model and the power system's parameters. The accomplishment of a suitable simulation model allows the sensitivity studies to be performed to determine the degree of influence of various components and parameters of the f…
Glassy dynamics was investigated for thin films of atactic polystyrene by complex electric capacitance measurements using dielectric relaxation spectroscopy. During the isothermal aging process the real part of the electric capacitance increased with time, whereas the imaginary part decreased with time. It follows tha…
Density functional theory (DFT) has been applied to the analysis of the structural and electronic properties of the alkyl-cobalt(III) phthalocyanine complexes, [CoIIIPc]-R (Pc = phthalocyanine, R = Me or Et), and their pyridine adducts. The BP86/6-31G(d) level of theory shows good reliability for the optimized axial b…
An effective and facile method for the fabrication of a surface-enhanced Raman scattering (SERS)-active film with closely packed gold nanoparticle (AuNP) arrays is proposed by self-assembly of different sizes (16, 25, 40 and 70 nm) of AuNPs at a toluene/water interface with ethanol as the inducer. The as-prepared AuNP…
The characterization of a new five-coordinate derivative of (2-methylimidazole)(tetraphenylporphinato)iron(II) provides new and unique information about the effects of forming a hydrogen bond to the coordinated imidazole on the geometric and electronic structure of iron in these species. The complex studied has two cr…
The glass transition and thermodynamics of spherical liquid TiO(2) nanoparticles, with different sizes ranging from 2 to 5 nm, have been studied in a model under non-periodic boundary conditions. We use the pairwise interatomic potentials proposed by Matsui and Akaogi. Models have been obtained by cooling from the mel…
The solubility of stearic acid was measured in ethanol, 2-propanol, heptane, hexane, acetone, and trichloroethylene and in the azeotropic mixtures of the solvents (ethanol−heptane; hexane−ethanol; ethanol−trichloroethylene; acetone−heptane; heptane−2-propanol; acetone−hexane; hexane−2-propanol; 2-propanol−trichloroeth…
The dielectric permittivity (100 Hz–1 MHz) and IR reflectivity of SrTiO 3 :Mn(0.1 at.%) crystals and SrTiO 3 :Mn(0.1–3 at.%) ceramics prepared maintaining the ratio (Sr+Mn)/ Ti = 1 or (Ti+Mn)/Sr = 1 (A- and B-type ceramics, respectively) were studied. Surprisingly, the magnitude and ε ′ ( T ) dependence for the crysta…
AIM: To boost short-chain-length-long-chain-length polyhydroxyalkanoate (SCL-LCL-PHA) co-polymer yield in Pseudomonas aeruginosa MTCC 7925 by manipulating culture conditions. METHODS AND RESULTS: Stationary phase culture of P. aeruginosa MTCC 7925 was subjected to various doses of different carbons and, N and P defici…
A novel family of transcription factors responsible for regulation of various aspects of NAD synthesis in a broad range of bacteria was identified by comparative genomics approach. Regulators of this family (here termed NrtR for Nudix-related transcriptional regulators), currently annotated as ADP-ribose pyrophosphata…
The temperature dependence of magnetization, magnetic anisotropy, and coercive field of gallium-substituted cobalt ferrite was investigated for a series of compositions of CoGaxFe2−xO4 (0⩽x⩽0.8). Hysteresis loops were measured for each sample over the range of −5T⩽μ0H⩽5T for selected temperatures between 10 and 400K.…
The extremely stable conductivity against molecular physisorptions was revealed in thin films of high-purity metallic single wall carbon nanotubes (SWCNTs). The stability of the metallic SWCNTs results from their constant electronic density of state near the Fermi level. In the case of a mixture of metallic and semico…