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Cross‐Linking via Electron Beam Treatment of a Tailored Polysilazane (ABSE) for Processing of Ceramic SiCN‐Fibers

Sylvia Kokott、Günter Motz2007-05-01Soft Materials

Cost‐efficient ceramic SiCN fibers were produced by the precursor route consisting of four processing steps: synthesis of the polymer, melt‐spinning, curing via electron beam (e‐beam) and subsequent pyrolysis at 1100°C in a nitrogen atmosphere. A special solid and meltable fiber polymer, the so‐called polycarbosilazan…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsAdvanced materials and composites

Effect of Sulfate-reducing Bacteria on Corrosion Behavior of Mild Steel in Sea Mud

Xiaodong Zhao、Jizhou Duan、Baorong Hou 等 4 位作者2007-05-01Journal of Material Science and Technology

Microbiologically influenced corrosion (MIC) is very severe corrosion for constructions buried under sea mud environment. Therefore it is of great importance to carry out the investigation of the corrosion behavior of marine steel in sea mud. In this paper, the effect of sulfate-reducing bacteria (SRB) on corrosion be…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Computational Fluid Dynamics Model of a Planar Solid-Oxide Electrolysis Cell for Hydrogen Production from Nuclear Energy

Grant L. Hawkes、James E. O’Brien、C. M. Stoots 等 5 位作者2007-05-01Nuclear Technology

A three-dimensional computational fluid dynamics (CFD) model has been created to model high-temperature steam electrolysis in a planar solid-oxide electrolysis cell (SOEC). The model represents a single cell as it would exist in an electrolysis stack. Details of the model geometry are specific to a stack tested at the…

Advancements in Solid Oxide Fuel CellsChemical Looping and Thermochemical ProcessesMolten salt chemistry and electrochemical processes

Copolymerizations of Glycolide andL‐Lactide Initiated with Bismuth(III)n‐Hexanoate or Bismuth Subsalicylate

H. R. Kricheldorf、Gesa Behnken2007-05-01Journal of Macromolecular Science Part A

Equimolar copolymerizations of glycolide and L‐lactide were conducted in bulk in the temperature range from 100 to 160°C. The catalytic efficiency of tin(II)2‐ethylhexanoate (SnOct2) and bismuth(III)n‐hexanoate (BiHex3) were compared under identical conditions. Furthermore, four copolymerizations were conducted with b…

biodegradable polymer synthesis and propertiesPolyoxometalates: Synthesis and ApplicationsCarbon dioxide utilization in catalysis

Nanorods of Silver-Coated Magnetic CrO2 Particles from a Polymer Template in Hot Water

Somnath Biswas、Vivek K. Srivastava、S. Ram 等 4 位作者2007-05-01The Journal of Physical Chemistry C

A surface coating of silver of CrO 2 nanoparticles at an early stage of growth leads the latter to grow in an anisotropic shape of nanorods. When heating in polymer molecules of polyvinyl alcohol (PVA) in water at ∼90 °C fibrils as long as 10−50 μm (∼300 nm diameter) have developed embedding in the polymer. Small PVA…

Advanced Photocatalysis TechniquesZnO doping and propertiesHeusler alloys: electronic and magnetic properties

Polymer clay self‐assembly complexes on paper

Runqing Ou、Jianguo Zhang、Yulin Deng 等 4 位作者2007-05-01Journal of Applied Polymer Science

Abstract Layer‐by‐layer (LBL) self‐assembly was used to form polymer/clay complexes on paper to enhance its wet strength properties. Initially, alternating layers of poly(allylamine hydrochloride) (PAH) and Kaolin clay were sequentially deposited on quartz substrate and characterized by UV/Vis/NIR spectroscopy as a mo…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesRecycling and Waste Management Techniques

Lanthanum Strontium Manganite Powders Synthesized by Gel‐Casting for Solid Oxide Fuel Cell Cathode Materials

Lan Zhang、Yujun Zhang、Y. D. Zhen 等 4 位作者2007-05-01Journal of the American Ceramic Society

Lanthanum strontium manganite ((La 0.8 Sr 0.2 ) 0.9 MnO 3 ; LSM) powder was successfully synthesized by an aqueous gel‐casting technique, using carbonaceous precursors. Both thermal and X‐ray diffraction analysis confirmed that the gel‐casting LSM powder formed a single perovskite phase at 850°C, which is 100°–150°C l…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Room-temperature fabricated ZnCoO diluted magnetic semiconductors

Hsin-Hung Huang、C.-Y. Yang、Po-Hsiang Huang 等 8 位作者2007-05-01Journal of Applied Physics

(0002) textured and epitaxial ZnCo0.07O films were fabricated at room temperature by ion beam deposition on Si substrates. Hall measurement revealed that ZnCo0.07O films were n-type semiconductors with carrier concentrations higher than 1019∕cm3. The carrier concentration of ZnCo0.07O can be manipulated by controlling…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

Phase Analysis of Hydraulic Cements by X-Ray Powder Diffraction: Precision, Bias, and Qualification

Paul E. Stutzman、Stefan D. Leigh2007-05-01Journal of ASTM International

Abstract Estimates of cement phase composition have traditionally been made using bulk chemical analysis and the Bogue calculations, developed over 75 years ago. X-ray powder diffraction analysis provides an alternative with direct phase determination, qualitatively and quantitatively. The Rietveld method to refine mu…

Concrete and Cement Materials ResearchAdvanced materials and compositesX-ray Diffraction in Crystallography

Bridging the Gap Between FEA Field Solution and the Magnetic Component Model

R. Prieto、R. Asensi、C. Fernández 等 5 位作者2007-05-01IEEE Transactions on Power Electronics

The use of finite element analysis (FEA) solvers in order to explore the field distribution is a common practice for designing custom made magnetic components. However, the use of the field distribution information for the generation of a model valid to be simulated in a circuit simulator is not evident. There are sev…

Electric Motor Design and AnalysisMagnetic Properties and ApplicationsNon-Destructive Testing Techniques

High spin polarization in a two phase quaternary Heusler alloy Co2MnAl1−XSnX

A. Rajanikanth、Dhishan Kande、Y. K. Takahashi 等 4 位作者2007-05-01Journal of Applied Physics

We have investigated the structure and the spin polarization of Co2MnAl, Co2MnSn, and Co2MnAl0.5Sn0.5 alloys. The structures of the Co2MnAl and Co2MnSn alloys that were annealed for four days at 450°C were B2 and L21, respectively. Co2MnAl0.5Sn0.5 had a dendrite microstructure that was formed by the phase separation i…

Intermetallics and Advanced Alloy PropertiesMXene and MAX Phase MaterialsHeusler alloys: electronic and magnetic properties

Gram-Charlier development of the atomic displacement factors into mineral structures: The case of samsonite, Ag4MnSb2S6

L. Bindi、M. Evain2007-05-01American Mineralogist

During structure solution of Ag-, Cu-bearing minerals it is quite common to observe disorder. Ag + and Cu + , indeed, can occur in different, but overlapping sites. The typical way to deal with these kind of minerals in structure determination is to use a split-atom model. This approach, however, has several disadvant…

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyX-ray Diffraction in Crystallography

Glass Formation and Properties of Chalcogenides in a GeSe 2 –As 2 Se 3 –PbSe System

Guang Yang、Xianghua Zhang、Jing Ren 等 7 位作者2007-05-01Journal of the American Ceramic Society

The glass‐forming region in a GeSe 2 –As 2 Se 3 –PbSe system was determined, and the dependence of properties on the composition as a formula of 20 GeSe 2 –(80− x )As 2 Se 3 − x PbSe ( x =0–30) was investigated. Measurements include density, differential scanning calorimetry, X‐ray diffraction, Vis‐NIR, and IR transmi…

Glass properties and applicationsCrystal Structures and PropertiesPhase-change materials and chalcogenides

Preparation of (001) oriented Pb(Zr,Ti)O3 thin films and their piezoelectric applications

Eiji Fujii、Ryoichi Takayama、Koji Nomura 等 9 位作者2007-05-01OpenAlex

Preparation of (001) oriented Pb(Zr,Ti)O3(PZT) thin films and their applications to a sensor and actuators were investigated. The (001) oriented PZT thin films were epitaxicially grown on (100)Pt/(100)MgO single crystal substrates by rf-magnetron sputtering. The PZT thin films on (100)Pt/(100)MgO buffer layer/glass su…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAcoustic Wave Resonator Technologies

Sensing with porous silicon double layers: A general approach for background suppression

Claudia Pacholski、Michael J. Sailor2007-05-01Physica status solidi. C, Conferences and critical reviews/Physica status solidi. C, Current topics in solid state physics

Abstract One‐dimensional porous silicon photonic crystals can be considered as optical double layers. The reflectivity spectrum of the structure displays a strong peak corresponding to the stop band of the photonic crystal (rugate filter) and Etalon fringes due to Fabry‐Pérot interference in the porous silicon film. T…

Photonic and Optical DevicesPhotonic Crystals and ApplicationsSilicon Nanostructures and Photoluminescence

Influence of Mn substitution on microstructure and magnetic properties of Cu1−xMnxO nanoparticles

G. Narsinga Rao、Y. D. Yao、J.W. Chen2007-05-01Journal of Applied Physics

Mn-doped CuO nanoparticles were synthesized using a coprecipitation method. Powder x-ray analysis reveals that all the samples crystallize into a monoclinic-type structure. Significant changes occur in both the microstructure and particle size with calcination temperature TA. The average particle size d increases from…

ZnO doping and propertiesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Effect of laser quenching and subsequent heat treatment on the structure and wear resistance of a cemented steel 20KhN3A

А. В. Макаров、Л. Г. Коршунов、I. Yu. Malygina 等 4 位作者2007-05-01The Physics of Metals and Metallography

The martensite-austenite structures that are formed under the action of continuous laser irradiation in the 20KhN3A steel subjected to various regimes of cementation have been studied by metallography, electron microscopy, and X-ray diffraction. It has been established that a decrease in the amount of retained austeni…

High Entropy Alloys StudiesMetal Alloys Wear and PropertiesEngineering and Environmental Studies

Recrystallization behavior of ZnS during hot isostatic pressing

E.V. Karaksina、В. Б. Иконников、Е. М. Гаврищук2007-05-01Inorganic Materials

The effect of hot isostatic pressing conditions on the microstructure of CVD ZnS has been studied. The results have been used to analyze the mechanisms of zinc sulfide recrystallization at high temperatures and pressures.

Microstructure and mechanical propertiesSolidification and crystal growth phenomena

Raman Spectroscopic Study of the Molybdate MineralSzenicsiteand Comparison with Other Paragenetically Related Molybdate Minerals

Ray L. Frost、J. Bouzaid、Ian S. Butler2007-05-01Spectroscopy Letters

The molybdate‐bearing mineral szenicsite, Cu3(MoO4)(OH)4, has been studied by Raman and infrared spectroscopy. A comparison of the Raman spectra is made with those of the closely related molybdate‐bearing minerals, wulfenite, powellite, lindgrenite, and iriginite, which show common paragenesis. The Raman spectrum of s…

Crystal Structures and PropertiesRadioactive element chemistry and processingMineralogy and Gemology Studies

Effect of process parameter on mechanical properties of friction stir welded tailored blanks from aluminium alloy 6181-T4

Shahram Sheikhi、Jorge F. dos Santos2007-05-01Science and Technology of Welding & Joining

Tailor welded blanks (TWBs) are produced by joining at least two sheets of dissimilar gauge and/or properties to achieve a lighter blank of desired stiffness and strength. In this way, the properties of the blank may be tailored to meet the design requirements of a panel. As in steel structures, cost and weight can be…

Electromagnetic Effects on MaterialsMaterial Properties and Failure MechanismsMetallurgical and Alloy Processes