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Catalytic Performance of P(4VP-co-St)/SiO_2-Supported Co Tetraphenylporphyrins for the Aerobic Oxidation of Phenylethane

Rui Wang2009-01-01Acta Physico-Chimica Sinica

The X-substituted cobalt tetraporphyrins (CoTXPP) (X=H, Cl, NO2) were easily bound to the side chains of the grafting particles poly(4-vinyl-pyridine-co-styrene)/SiO2 (P(4VP-co-St)/SiO2) via an axial coordination reaction to prepare supported catalysts CoTXPP-P(4VP-co-St)/SiO2. Structures of the CoTXPP-P(4VP-co-St)/Si…

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsOxidative Organic Chemistry Reactions

Realization and investigation of negative refractive materials

Zhenqing Li2009-01-01Optical Instruments

As new materials with special characteristics,the negative refractive materials have been a focus.This paper introduces the unique characteristics of negative refraction,and expounded deeply the three ways to realize negative refraction,which are left-handed medium, chiral medium and photonic crystals,among them,the b…

Photonic Crystals and ApplicationsAdvanced Antenna and Metasurface TechnologiesOptical Coatings and Gratings

Preparation of Polyaniline/SiO_2 Composite Particles and Its Anti-corrosion Properties

SI Shi-hui2009-01-01Fain kemikaru

The synthesis of hydrochloric acid doped polyaniline was preformed by using manganese dioxide instead of the ammonium persulfate oxidant,and the polyaniline coated silicon dioxide particle composites were obtained by adding a proper proportion of silicon dioxide particles to the oxidation-polymerization reaction syste…

Conducting polymers and applications

The Analysis of Q345B Hot Strip Production Process in ASP Production Line

Yan Kun2009-01-01Gansu Metallurgy

the process and product performance of using low-cost production of high-strength low-alloy steel Q345B on ASP1700 in Jinan Iron and Steel production line.Developed by the chemical constituents of low-alloy steel Q345B adopt low-phosphorus low-silicon high manganese sulfur,do not use Nb,V,such as micro-alloying,throug…

Metallurgical Processes and ThermodynamicsMetallurgy and Material FormingMetal Alloys Wear and Properties

Synthesis of ETBE Catalyzed by Different Molecular Sieves

Yang Li-na2009-01-01Chemical Industry and Engineering

Ethyl tertiary butyl ether(ETBE)was synthesized from ethanol and tert-butyl alcohol catalyzed by the Hβ zeolite,HY,HUSY,HZSM-5 and D-06 resin in a fixed-bed reactor.The comparison experiments were performed and the results showed the catalytic activity order of zeolite was:Hβ zeoliteHYHUSYHZSM-5,the catalytic activity…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisCatalysis and Oxidation Reactions

Graphite Calorimeter for Measurement of Absorbed Dose of Electron Beam

Wen Xia2009-01-01Nuclear Instruments and Methods in Physics Research Section B Beam Interactions with Materials and Atoms

A multi-layer graphite calorimeter for the measurement of depth-map of the absorbed dose and the energy of the electron beams,and a device of the semi-adiabatic graphite calorimeter for the measurement of the absorbed dose and the calibration of film dosimeter were developed for the requirement to the standard method…

Radiation Detection and Scintillator TechnologiesRadiation Effects and DosimetryGraphite, nuclear technology, radiation studies

Novel Synthesis of Salicylic Acid-Crosslinked Polystyrene Chelating Resin

Zhanbin Wang2009-01-01Journal of Functional Polymers

The chloromethylation of crosslinked polystyrene(CPS) microspheres was performed using 1,4-bis(chloromethoxy)butane(BCMB) as the chloromethylation reagent.Then the nucleophilic substitution reaction between 5-amino salicylic acid and benzyl chloride groups on the CMCPS microspheres was conducted,and amino salicylic ac…

Synthesis and properties of polymers

Influence of Local Distorted Structure on Polarization Properties of Ferroelectric Thin Films

Gang Tie-chen2009-01-01Journal of Shenyang University of Chemical Technology

By introducing distribution function to characterize the polarization in films,GLD(Ginzburg-Landau-Devonshire) thermodynamic theory is used to investigate the influence of non-ferroelectric local distorted structure on polarization properties of ferroelectric thin films.The results show that non-ferroelectric local di…

Ferroelectric and Piezoelectric MaterialsLiquid Crystal Research AdvancementsAcoustic Wave Resonator Technologies

Effect of surface treatment on soakage of epoxy resin to carbon fibers

Lang Liu2009-01-01Huagong jinzhan

Carbon fibers (CFs) were surface oxidized and aminated,respectively. The influence on the element contents and functional groups of the fiber surface was investigated with X-ray photoelectron spectroscopy (XPS). The oxygen content increased significantly and the (O+N)/C ratio was comparably higher after oxidation trea…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsFiber-reinforced polymer composites

Synthesis and characterization of fluorinated indium phosphate

Xing Li2009-01-01OpenAlex

A fluorinated indiumphosphate,InF_2[PO_3(OH)]_2(NH_4)_3,has been prepared under ionothermal condition using deep-eutectic solvents of choline chloride and urea as solvent and template-delivery agents.The same material can not be observed with the presence of the same deep-eutectic mixture under normal hydrothermal pro…

Synthesis and properties of polymersSilicone and Siloxane ChemistryInorganic Fluorides and Related Compounds

Some feeling in use of JZD series double-side top comb

Zhu Jian-qing2009-01-01OpenAlex

In this article is described the development of top carding mechanism of comber,discussed its carding function of double-side top comb in comber with the focuss on the structure of JZD double-side top comb and compared the impact of different top comb on the formed yarn quality.

Textile materials and evaluations

Effect of Overaging Temperature in Continuous Annealing on Microstructure and Properties of Heat-Treated DP Steel

Wang Guo-dong2009-01-01Ironmaking & Steelmaking Processes Products and Applications

With bright continuous annealing simulator,the microstructure and properties of 0.08C-1.7Mn-0.03Si steel treated with different overaging temperature and the phase transformation during continuous annealing process were studied.The results show that second phase was mostly of granular bainite and martensite in the spe…

Microstructure and Mechanical Properties of SteelsMetallurgy and Material FormingMetal Alloys Wear and Properties

Analysis on Microstructure of AlSi7Cu5 Alloy Obtained by Slope-liquidus Method

Xiuyan Guo2009-01-01Rejiagong gongyi

The casting microstructure and its change during remelting of AlSi7Cu5 alloy cast by slope-liquidus method were researched.The results show that it has a significant impact on microstructure by cooling methods,casting molds and pouring methods.The microstructure of AlSi7Cu5 alloy obtained by slope liquidus method is u…

Aluminum Alloy Microstructure PropertiesAluminum Alloys Composites PropertiesMetallurgy and Material Science

Stretching and Elastic Recovery of PTT/PET Self-crimping Filament

Fumei Wang2009-01-01Synthetic Fiber in China

Stretching and elastic recovery properties based on elongation of three kinds of PTT (Polytrimethylene terephthalate)/PET (Polyethylene terephthalate) self-crimping filaments with same linear density were tested. The testing results showed that there were typical two steps and two yield points in the force-elongation…

Advanced Sensor and Energy Harvesting MaterialsPolymer crystallization and propertiesFiber-reinforced polymer composites

Mechanism of Ionic Conduction of ZrO2 Base Solid Electrolyte

Linxiu Zhang2009-01-01The Heat Treatment

Cubic ZrO2 provides an excellent ionic conduction and is extensively used as electrolyte of solid oxide fuel cell(SOFC) in recent years.The ion electrical conductivity in solid is dependent on both carrier concentration(density) and mobility,while the conduction and diffusion of solid state ions are dependent on the s…

Advancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

Effect of Compounding of PVC Paste Resins on Viscosity and Stability of Corresponding PVC Plastisols

JI Yu-bi、Guomin Xu、Minmin Zhang 等 5 位作者2009-01-01China Plastics

Viscosity and stability over time of PVC plastisols were studied based on compounds of a high-and a low-degree polymerization PVC paste resins,PSH-10 and CPM-31.When PSH-10/CPM-31=20/80,the plastisol provided the lowest viscosity.When PSH-10/CPM-31=50/50,the worst stability was observed.The viscosity and stability of…

Polymer Science and PVC

MAGNETIC PHASE TRANSITION OF THE DOUBLE-LAYERED PEROVSKITE Nd_(2-2x)Ca_(1+2x)Mn_2O_7(x=0.4,0.5)

Sheng Xu2009-01-01Diwen wuli xuebao

Polycrystals of double-layered perovskite Nd2-2xCa1+2xMn2O7 (x=0.0~0.9) were prepared by solid-state reactions. With the Rietveld-Method,the samples' XRD pattern was fitted by the program FULLPROF. The compounds show the space group I4/mmm at the room temperature. The temperature dependence of the resistivity (80KT300…

Magnetic and transport properties of perovskites and related materials

Effects of Valence Electron Structure and Alloying Elements on NiAl Mechanical Properties

Dan Liŭ2009-01-01Journal of Qingdao University of Science and Technology

Based on the empirical electron theory of solid and molecule(EET),the valence electron structure(VES) of(NiM)Al is calculated.Several parameters of mechanical properties involved in nA and ρLA are used to characterize and assess the effect of alloying elements on the ductility and hardness of NiAl intermetallic compou…

Intermetallics and Advanced Alloy Propertiesnanoparticles nucleation surface interactionsMetallurgical and Alloy Processes