Materials Literature
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The electronic structure of two series of small titanium oxide clusters, TiOy (y = 1−3) and (TiO2)n (n = 1−4), is studied using anion photoelectron spectroscopy. Vibrationally resolved spectra are obtained for TiO− and TiO2−. Six low-lying electronic states for TiO are observed with five of these excited states result…
Toluene diisocyanate-based polyurethane iniferters containing tetraphenyl-ethane groups in between polyurethane blocks were prepared by the reaction of isocyanate-terminated prepolymers and 1,1,2,2-tetraphenyl-1,2-ethanediol. When these iniferters were decomposed in the presence of styrene, polyurethane-polystyrene mu…
The effects of styrene-co-acrylonitrile resin (AS) on the mechanical properties, morphology, and plasticizing and rheological behaviors of poly(vinyl chloride)/chlorinated polyethylene(PVC/CPE) blends are studied. The results show that the impact strength and the tensile strength are all increased and the plasticizing…
A series of novel poly(phthalazinone ether sulfone ketone)s was synthesized from bis(4-fluorophenyl) ketone, bis(4-chlorophenyl)sulfone, and 4-(4-hydroxybenzyl)-2,3-phthalazin-1-one through nucleophilic substitution polycondensation. The synthesized polymers exhibited surprisingly high glass transition temperatures an…
Wood fiber of aspen was used as a reinforced filler in linear low-density polyethylene (LLDPE). To improve the compatibility between the wood fiber and the LLDPE matrix, the wood fiber was treated with titanate coupling agents (i.e., TC-PBT and TC-POT) or grafted by acrylonitrile. Both treatments resulted in an improv…
This article reviews the most important achievements in the studies of the compositional (chemical) and magnetic ordering effects in the surface region of single-crystal binary alloys with different bulk structures. These alloys include the non-magnetic and magnetic concentrated substitutional binary systems which hav…
Polymer films of poly(ethylene terephthalate), polypropylene, and cellophane were surface treated with tetrafluoromethane plasma under different time, power, and pressure conditions. Contact angles for water and methylene iodide and surface energy were analyzed with a dynamic contact angle analyzer. The stability of t…
A dislocation moving through a quasicrystal is leaving in its wake a fault denoted phason wall. For a two-dimensional model quasicrystal the disregistry energy of this phason wall is studied to determine possible Burgers vectors of the quasicrystalline structure. Contrary to periodic crystals, the disregistry energy i…
Poly(lactic acid) (PLA) and poly(ethylene glycol) (PEG) were melt-blended and extruded into films in the PLA/PEG ratios of 100/0, 90/10, 70/30, 50/50, and 30/70. It was concluded from the differential scanning calorimetry and dynamic mechanical analysis results that PLA/PEG blends range from miscible to partially misc…
Citrate esters were used as plasticizers with poly(lactic acid) (PLA). Films were extruded using a single-screw extruder with plasticizer contents of 10, 20, and 30% by weight. All of the citrate esters investigated were found to be effective in reducing the glass transition temperature and improving the elongation at…
The crystal structure and magnetic properties of the α- Al 2 O 3 and γ- Al 2 O 3 samples were investigated. The α- Al 2 O 3 and γ- Al 2 O 3 powders have the trigonal and cubic symmetries, respectively. Moreover, the α- Al 2 O 3 powders have better crystallinity than γ- Al 2 O 3 material. A peculiar magnetic behavior i…
Abstract Since the arrival of the transistor in 1947, research in hot electrons, like any field in semiconductor research, has grown at a stunning rate. From a physicist's point of view the understanding of hot electrons and their interactions with the lattice has always been a challenging problem of condensed matter…
We emphasize the importance of choosing an appropriate correlation function to reduce numerical errors in calculating the linear-response function as a Fourier transformation of a time-dependent correlation function. As an example we take dielectric functions of silicon crystal calculated with a time-dependent method…
The mean-field theory for lossy nonlinear composites, described by complex and field-dependent dielectric functions, is presented. By using the spectral representation of linear composites with identical microstructure, we develop self-consistent equations for the effective response. We examine two types of microstruc…
We review recent results on the linear and non-linear optical response of realistic quantum-wire structures. Our theoretical approach is based on a set of generalized semiconductor Bloch equations, and allows a full three-dimensional multisubband description of Coulomb correlation for any shape of the confinement prof…
A model for high temperature superconductors based on the idea of Cooper pairs comprised of electrons from different bands is studied. We propose that the two bands relevant for the cuprates are comprised of Cu dx2-y2, dz2, planar O psigma, and apical O pz orbitals. Along the diagonal, kx=ky in the Brillouin zone, the…
A review of coherent phenomena in photoexcited semiconductors is presented. In particular, two classes of phenomena are considered: On the one hand the role played by optically-induced phase coherence in the ultrafast spectroscopy of semiconductors; On the other hand the Coulomb-induced effects on the coherent optical…
In this note we re-examine the classic Janssen theory for stresses in bins, including a randomness in the friction coefficient. The Janssen analysis relies on assumptions not met in practice; for this reason, we numerically solve the PDEs expressing balance of momentum in a bin, again including randomness in friction.
We present the results of a new Hubbard model for optimally doped LaSrCuO. This model uses parameters derived from BLYP calculations on the cluster CuO6. It explicitly includes the Cu dx2-y2 and dz2 orbitals, the O psigma orbitals, and the apical O pz orbitals. When correlation is properly included in the Hubbard mode…
The theoretical analysis of the ultrafast energy relaxation and transport phenomena in semiconductor superlattices is reviewed. In particular, we discuss the two equivalent quantum-mechanical pictures of Bloch oscillations and Wannier-Stark localization. A review of simulated experiments and their comparison with avai…