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An Alanine-Zipper Structure Determined by Long Range Intermolecular Interactions

Jie Liu、Min Lu2002-12-01Journal of Biological Chemistry

A major challenge in protein folding is to identify and quantify specific structural determinants that allow native proteins to acquire their unique folded structures. Here we report the engineering of a 52-residue protein (Ala-14) that contains exclusively alanine residues at the hydrophobic a and d positions of a na…

Protein Structure and DynamicsEnzyme Structure and FunctionBiochemical and Structural Characterization

Characterization of monopolymer blend of virgin and recycled polyamide 6

Roberto Scaffaro、Francesco Paolo La Mantia2002-12-01Polymer Engineering and Science

Abstract It is a common industrial practice to blend virgin polymer with the same recycled polymer coming from plastic scraps that, in general, has not undergone relevant degradation. In this work, the characteristics of blends of virgin and recycled polyamide have been considered by changing the amount of recycled po…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesMicroplastics and Plastic Pollution

Preparation, Structure, and Properties of Thermally and Mechanically Improved Aluminum Titanate Ceramics Doped with Alkali Feldspar

Masahide Takahashi、Masahiro Fukuda、Masaaki Fukuda 等 5 位作者2002-12-01Journal of the American Ceramic Society

Aluminum titanate (AT) ceramic materials doped with alkali feldspar ((Na 0.6 K 0.4 )AlSi 3 O 8 ) have been prepared. These ceramics exhibited high sinterability, large resistance to thermal decomposition, and large flexure strength. The existence of liquid‐phase feldspar at sintering temperatures promoted the formatio…

Ferroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesisMicrowave Dielectric Ceramics Synthesis

Simultaneous Synthesis and Densification of Titanium Nitride/ Titanium Diboride Composites by High Nitrogen Pressure Combustion

Masachika Shibuya、Manshi Ohyanagi、Zuhair A. Munir2002-12-01Journal of the American Ceramic Society

Composites of TiN/TiB 2 were synthesized by a combustion process of BN, Ti in a nitrogen atmosphere. The effect of the BN/Ti ratio and the nitrogen gas pressure on the synthesis of these composites was investigated. Dense TiN/TiB 2 composites with relatively high hardness and toughness were fabricated by combustion sy…

Metal and Thin Film MechanicsIntermetallics and Advanced Alloy PropertiesMXene and MAX Phase Materials

PHENYLENIC AND NAPHTHYLENIC TORI

Mircea V. Diudea2002-12-01Fullerenes Nanotubes and Carbon Nanostructures

Toroidal polyhex lattices have been proposed in the literature as models for the “circle crops” observed in soot condensed from arc-vaporized graphite. Other covering patterns, including azulenic C5C7, “bathroom floor” C4C8, and mixed patterns have been suggested. In this paper, novel phenylenic (PH) and naphthylenic…

Carbon Nanotubes in CompositesGraphene research and applicationsGraph theory and applications

Weathering of Chlorite: II. Reactions and Products in Microsystems Controlled by Solution Avenues

Mehrooz Aspandiar、Richard A. Eggleton2002-12-01Clays and Clay Minerals

Abstract Weathering of chlorite adjacent to macro- and micro-passages (fissures) in regolith units has been studied to determine the alteration mechanisms and products and compare them to those that prevail at a distance from the open passages. The micro-fissures in the saprolith units evolve as a function of weatheri…

Geological and Geochemical AnalysisClay minerals and soil interactionsIron oxide chemistry and applications

New Quaternary Bismuth Sulfides: Syntheses, Structures, and Band Structures of AMBiS4 (A = Rb, Cs; M = Si, Ge)

Jiyong Yao、Bin Deng、D. E. Ellis 等 4 位作者2002-12-01Inorganic Chemistry

Four new compounds, RbSiBiS(4), RbGeBiS(4), CsSiBiS(4), and CsGeBiS(4), have been synthesized by means of the reactive flux method. The isostructural compounds RbSiBiS(4), RbGeBiS(4), and CsGeBiS(4) crystallize in space group P2(1)/c of the monoclinic system with four formula units in cells of dimensions at 153 K of a…

Crystal Structures and PropertiesIron-based superconductors researchInorganic Chemistry and Materials

A Novel Impact Modifier for Nylon 6

Jing Peng、Jinliang Qiao、Shijun Zhang 等 4 位作者2002-12-01Macromolecular Materials and Engineering

Abstract A new carboxylated styrene‐butadiene rubber (CSBR) in ultrafine powder form was used to modify the properties of nylon 6. The nylon 6/CSBR blends possessed higher toughness than nylon 6/maleic anhydride‐grafted polyethylene‐octene elastomer (POE‐ g ‐MAH) system. TEM micrographs revealed the fine dispersion of…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesEpoxy Resin Curing Processes

Scratch behavior of nanoparticle Al2O3‐filled gelatin films

Tao Li、Quan Chen、Linda S. Schadler 等 6 位作者2002-12-01Polymer Composites

Abstract Nanoscale alumina/protein gel composite films with 10–50 wt% filler were subjected to scratch testing and compared to micron‐scale alumina/protein gel composites. Atomic force microscopy (AFM) was employed to examine the width, depth, and morphology of the as‐produced scratches. The results show that the scra…

Electrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction StudiesPolymer Nanocomposite Synthesis and Irradiation

Calcined calcium magnesium acetate as a superior SO2 sorbent: I. Thermal decomposition

Dong Han、Hong Yong Sohn2002-12-01AIChE Journal

Abstract The reactivity of the calcination product of calcium magnesium acetate (CMA) as a possible dry desulfurization agent was evaluated. The first step in the dry desulfurization reaction—the thermal decomposition of CMA—was investigated by determining the decomposition reaction in three steps: 1. the evaporation…

Layered Double Hydroxides Synthesis and ApplicationsThermal and Kinetic AnalysisMagnesium Oxide Properties and Applications

Crystalline Structure of Polyethylene Containing 1,2- or 1,3-Disubstituted Cyclopentane Units in the Main Chain

Naofumi Naga、Michiyo Tsubooka、Masato Sone 等 5 位作者2002-12-01Macromolecules

Polyethylene having 1,2- or 1,3-disubstituted cyclopentane structures was prepared by copolymerization of ethylene and cyclopentene (CPE) or 1,5-hexadiene (HD), and the crystalline structure was studied. Treatment with fuming nitric acid preferentially degraded the amorphous phase of the copolymers, and the structure…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

PVC/wood‐flour composites compatibilized with chlorinated polyethylene

Virginia O. Guffey、Amiel B. Sabbagh2002-12-01Journal of Vinyl and Additive Technology

Abstract Chlorinated polyethylene has been demonstrated to be an effective compatibilizer for dissimilar materials in various mixed‐polymer or recycled‐polymer systems. In this paper the use of chlorinated polyethylene to compatibilize polymer/natural‐fiber composites is discussed. Examples of applications in PVC/wood…

Natural Fiber Reinforced CompositesInnovations in Concrete and Construction MaterialsPolymer Science and PVC

Luminescence and compositional analysis of Y3Al5O12:Ce films fabricated by pulsed-laser deposition

Jae Young Choe2002-12-01Materials Research Innovations

Y3-xAl5O12: Cex3+ (YAG: Ce3+) thin-films were deposited by a pulsed-laser deposition method on quartz substrates using a solid YAG: Ce target. The films were analyzed by X-ray diffraction, scanning electron microscopy, photoluminescence (PL), and energy dispersive X-ray analysis (EDX). The as-deposited films were amor…

Luminescence Properties of Advanced MaterialsQuantum Dots Synthesis And PropertiesGlass properties and applications

Dielectric and Ferroelectric Properties of Nanocrystalline Bi 2 Ti 2 O 7 Prepared by a Metallorganic Decomposition Method

Yun Hou、Min Wang、Xiaohong Xu 等 6 位作者2002-12-01Journal of the American Ceramic Society

Nanopowders of Bi 2 Ti 2 O 7 were synthesized by a metallorganic decomposition (MOD) technique. Pure Bi 2 Ti 2 O 7 nanocrystals formed after annealing at 550°C for 5 min. X‐ray patterns show that Bi 20 TiO 32 is a metastable phase during Bi 2 Ti 2 O 7 formation. It was found that there were two peaks in the curves of…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Gaseous electrical discharge characteristics in air and nitrogen at cryogenic temperature

Hiroyuki Toyota、S Zama、Yotaro Akamine 等 5 位作者2002-12-01IEEE Transactions on Dielectrics and Electrical Insulation

In designing superconducting electrical power apparatus, the knowledge of cryogenic gas and liquid insulation characteristics is essential. The authors have studied the discharge characteristics of relatively long-gap configurations in air and nitrogen at a cryogenic temperature. A sphere-to-sphere electrode with a ga…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationAerosol Filtration and Electrostatic Precipitation

Effects of conductive fibers and processing conditions on the electromagnetic shielding effectiveness of injection molded composites

Sen Yang、Cheng–Ying Chen、S. H. Parng2002-12-01Polymer Composites

Abstract This paper investigates the electromagnetic interference shielding effectiveness (EMI SE) of injection molded ABS disks filled with stainless steel fibers (SSF) and nickel‐coated graphite fibers (NGF). The effects of fiber type, fiber length and weight percentage on SE were studied. Optical microscope (OM) an…

Electromagnetic wave absorption materialsElectromagnetic Compatibility and Noise SuppressionElectrical Contact Performance and Analysis

Preparation of zinc sodium polyphosphates glasses from coacervates precursors. Characterisation of the obtained glasses, and their applications

G. WILLOT、François Gomez、P. Vast 等 7 位作者2002-12-01Comptes Rendus Chimie

A soft chemistry route is described to obtain glasses in the P 2 O 5 –Na 2 O–ZnO–H 2 O. It is based on the addition of zinc salts to coacervates prepared from sodium polyphosphate. The processing of these coacervates leads to polyphosphate glasses with the same properties as those of glasses prepared in the classical…

Material Dynamics and PropertiesGlass properties and applicationsPigment Synthesis and Properties

Fractal fragmentation theory for shape effects of quasi-brittle materials in compression

Alberto Carpinteri、Nicola M. Pugno2002-12-01Magazine of Concrete Research

The influence of the slenderness (shape effects) of a specimen in compression and of the friction between it and the loading platens on the dissipated energy density and on the compressive strength (strain-softening response) is theoretically and experimentally analysed. The energy dissipated during the process is ass…

Rock Mechanics and ModelingGranular flow and fluidized bedsHigh-Velocity Impact and Material Behavior

Deformation behaviour of duplex stainless steel during industrial hot rolling

Lode Duprez、Bruno C. De Cooman、Nuri Akdut2002-12-01Steel Research

Industrially processed duplex stainless steel sheet was investigated after the reheating, the roughing mill and the finishing rolling. Light optical microscopy revealed that the cast structure that existed before rolling was removed and changed into a banded microstructure. During the process, the ferrite-austenite vo…

Corrosion Behavior and InhibitionMicrostructure and Mechanical Properties of SteelsHydrogen embrittlement and corrosion behaviors in metals

Area-Based Strategy for Determining Web Uniformity

Behnam Pourdeyhimi、Ludovic Kohel2002-12-01Textile Research Journal

This paper reports on work that should lead to real-time characterization of nonwovens as they are being produced. Statistical techniques and image processing techniques are employed. The initial results indicate the possibility of better process understanding and control. The goal of this work is to develop affordabl…

Textile materials and evaluationsColor Science and ApplicationsIndustrial Vision Systems and Defect Detection