Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
The heat capacity and entropy of liquids in the GeSe2–Se system are reported. The thermodynamics of the system is evaluated and discussed in light of earlier reported viscosities and recent structural studies of liquid GeSe2. The thermodynamics of liquid GeSe2 suggest that extensive structural disordering takes place…
High-resolution powder diffraction was used to study the thermal transformation of silver carbonate. A sample of Ag(2)CO(3) was heated in a capillary under 4.5 atm CO(2) pressure. The decomposition temperature of silver carbonate to silver oxide is thereby increased, allowing high-resolution synchrotron X-ray powder d…
HeteroPolyAcids (HPA's) are a class of solid acids that have broad applications in many fields of science and technology, including catalysis and chemical engineering. The proton locations within the thermally stable and commonly known Keggin unit, which is the primary structure building unit/block, has remained undet…
Polymers based on meta substituted phenylene ethylene are prepared with patterned polar and nonpolar groups to favor an extended conformation. These polymers were characterized at the air-water interface by Langmuir techniques and found to form stable monolayers with an extended conformation based on molecular models.…
The conductance through a local nuclear spin precessing in a magnetic field is studied by using the equations-of-motion approach. The characteristics of the conductance is determined by the tunneling matrix and the position of equilibrium chemical potential. We find that the spin flip coupling between the electrons on…
We present experimental results on the displacement of a domain wall by injection of a dc current through the wall. The samples are 1 micron wide long stripes of a CoO/Co/Cu/NiFe classical spin valve structure. The stripes have been patterned by electron beam lithography. A neck has been defined at 1/3 of the total le…
The rheology of granular particles in an inclined plane geometry is studied using molecular dynamics simulations. The flow--no-flow boundary is determined for piles of varying heights over a range of inclination angles $θ$. Three angles determine the phase diagram: $θ_{r}$, the angle of repose, is the angle at which a…
The effect of uniaxial pressure (P_u) on the magnetic susceptibility (X), magnetization (M), and magnetoresistance (MR) of the heavy-fermion metamagnet CeRu2Si2 has been investigated. For the magnetic field along the tetragonal c axis, it is found that characteristic physical quantities, i.e., the temperature of the s…
We present a temperature dependent single crystal x-ray diffraction study of twinned orthorhombic perovskites La1-xCaxMnO3, for x=0.16 and x=0.25. These data show the evolution of the crystal structure from the ferromagnetic insulating state to the ferromagnetic metallic state. The data are modelled in space group Pnm…
The formation of coherent three-dimensional islands in highly mismatched epitaxy is discussed in terms of the traditional concept of wetting. It is shown that the wetting layer and the 3D islands represent different phases which cannot be in equilibrium with each other, and the transfer of matter from the stable wetti…
The Gd(3+), Tb(3+), and Eu(3+) complexes of a bis-bipyridine-phenylphosphine oxide ligand PhP(O)(bipy)(2) 1 (bipy for 6-methylene-6'-methyl-2,2'-bipyridine) have been synthesized. In acetonitrile solutions at room temperature, the Tb(3+) and Eu(3+) complexes show a metal-centered luminescence, indicative of an efficie…
Reviewing work done in collaboration with Jennifer Hodgdon, we derive the most general crack growth law allowed by symmetry for mixed-mode three-dimensional fracture. We do so using the system developed in condensed matter physics to derive new laws that emerge on long length and time scales. In our derivation, we pro…
We have investigated Na2SiO5 melts with inelastic neutron scattering at temperatures up to 1600K. The Si-O network relaxes on a time scale of ns, whereas the Na ion relaxation dynamics are found on a time scale of 10ps. The elastic structure factor exhibits at ~0.9A-1 an emerging prepeak which becomes more pronounced…
Arabinoxylans (AX) are natural fibers extracted from maize bran, an industrial byproduct. To promote this polymer as a food ingredient, development of edible coatings and films had been proposed. Indeed, composite arabinoxylan-based films were prepared by emulsifying a fat: palmitic acid, oleic acid, triolein, or a hy…
We propose a comprehensive mechanism for the formation and growth of <100> interstitial loops in alpha-Fe. This mechanism reconciles long-standing experimental observations of these defects in irradiated ferritic materials with recent atomistic simulations of collision cascades and defect cluster properties in Fe, in…
The synthesis, structure, and characterization of a new noncentrosymmetric tellurite, Na 2 TeW 2 O 9, is reported. The oxide exhibits a three-dimensional structure comprising distorted W 6+ O 6 octahedra linked to asymmetric Te 4+ O 3 groups. Both cations are in local acentric environments attributable to second-order…
The complete energy expression of a deformed single-walled carbon nanotube (SWNT) is derived in the continuum limit from the local density approximation model proposed by Lenosky et al. [Nature (London) 355, 333 (1992)] and is shown to be consistent with the classic shell theory by which Young's modulus, the Poisson r…
We have observed size effects in the structural phase transition of submicron vanadium dioxide precipitates in silica. The ${\mathrm{VO}}_{2}$ nanoprecipitates are produced by the stoichiometric coimplantation of vanadium and oxygen and subsequent thermal processing. The observed size dependence in the transition temp…
Hydrogen uptake capacities of 1.8 and 2.6 wt % were obtained on BN multiwalled nanotubes and bamboo-like nanotubes, respectively, under approximately 10 MPa at room temperature. The preliminary results show that chemical interactions mainly take place between hydrogen and BN. Taking into consideration the uniform semi…
An analytical solution is presented for the borehole problem of an elasto-plastic plane strain body containing a traction-free circular hole and subjected to uniform far field stress. A strain gradient plasticity theory is used to describe the constitutive behavior of the material undergoing plastic deformations, wher…