Materials Literature
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This thesis is based on the experimental study of the damage of the Ultra High Performance Fiber Reinforced Concrete (UHPFRC) under physic, chemic or mechanic solicitations. All our concrete specimens used in this thesis have the same cement matrix and they are reinforced with a 1% volume fraction of fiber, these conc…
This work was aimed at understanding whether the bond strength of laminates will affect the puncture resistance of the laminate. Even though a strongly bonded adhesive layer in between two webs will considerably improve the mechanical properties of the laminate compared to that of the individual materials, there is a…
In food industry, hot air jet impingement ovens are used to bake pizza shells, crackers, cookies, and to toast ready-to-eat cereals. Despite its significant applications and advantages (faster processing and better quality products) in food processing industry, there is a very limited understanding of detailed transpo…
Physisorption of CO and N2O on surfaces of ceria (CeO2) was investigated by means of high-level quantum-mechanical embedded cluster calculations. Both systems have high relevance in the field of environmental chemistry and heterogeneous catalysis. The CO/CeO2 system, has been investigated in a couple of both experimen…
The adsorption structure of Pt(111) surface was studied by thermal desorption spectroscopy (TDS), infra-red absorption spectroscopy (IRAS), scanning tunneling microscopy (STM) and low-energy electron diffraction (LEED). LEED dynamical analysis, with the aid of other techniques, concluded that NO occupies the fcc hollo…
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Tese de mestrado integrado. Engenharia Mecânica. Faculdade de Engenharia. Universidade do Porto, Faculty of Mechanical Engineering. University of Galati. 2009
Optically compensated bend liquid crystal display (OCB-LCD) has many application fields owing to its fast response time and wide viewing angle. However, in order to operate the OCB-LCD in bend state, this device needs quick transitions from the initial splay state to bend state. Unlike conventional approach using tran…
The relationship between the enthalpies of point defects formation, ΔH def , and cohesive enthalpy, ΔH Ma/b O, in metal oxides exhibiting high departure from the stoichiometric composition has been discussed. It was found that the enthalpy of point defects formation during the change of the oxygen activity is strongly…
In the paper, we introduce a generalized class of k-starlike functions associated with Wright generalized hypergeometric functions and obtain the sequential subordination results and integral means in- equalities. Some interesting consequences of our results are also pointed out
Damage to concrete due to freeze-thaw (F-T) action is a serious concern for agencies in cold regions of the United States. The most effective method to protect concrete from F-T damage is through the addition of an air entraining agent as an admixture that creates a well distributed, closely spaced, small sized air vo…
The precursor polyimide of the photoreactive polyimides(PI-SP6 and PI-SP12) was prepared from a derivative of 2, 2, 2-trifluoroethane dianhydride and 3,3'-dihydroxy-4,4'-diaminobiphenyl. PI-SP6 and PI-SP12 were then prepared by the polymer reactions of the precursor polyimide with photoreactive 2-styrylpyridine alkyle…
$ZrTiO_4$ dielectric thin films were coated by metal-organic decomposition, and annealed by rapid thermal processing up to $900^{\circ}C$ for their crytallization. Crystallized single-phase $ZrTiO_4$ thin films were fabricated above the annealing temperature of $800^{\circ}C$ , but their grains were randomly oriented…
In this study, LPG-blended DME fuel was experimentally investigated in CI(compression ignition) engine. In particular, performance, emissions characteristics (including hydrocarbon, CO, and NOx emissions), and combustion stability of engine fueled with LPG-blended DME fuel were examined. The extent of LPG fuel in the…
Porous silicon film is fabricated by electrochemical etching in a chemical mixture of HF and ethanol. Effects of Si type, Si resistivity, ultrasonic frequency, current density and etching time on surface morphology of PS film were studied. Electrochemical etching in ultrasonic bath promotes the uniformity of porous la…
PtSn/C electrocatalysts were prepared with Pt:Sn atomic ratios of 3:1, 1:1 and 1:3 in water/2-propanol using electron beam irradiation. The obtained materials were characterized by EDX, XRD and cyclic voltammetry. The ethanol electro-oxidation was studied by chronoamperometry. The XRD diffractograms of the PtSn/C elec…
This thesis focuses on developing an appropriate cathode material throughnanotechnology as a key component for a promising alternative of renewable energygenerating systems, Intermediate Temperature Solid Oxide Fuel Cells (IT-SOFC).Aiming at a working cathode material for IT-SOFC, a recently reported capable oxidepero…
In the asymmetric unit of the title nicotinonitrile derivative, C23H21BrN2O4, there are two non-planar independent molecules. The central pyridine ring makes dihedral angles of 9.05 (7) and 77.06 (7)°, respectively, with the 4-bromophenyl and 2,4,6-trimethoxylphenyl rings in one molecule, whereas the corresponding val…
The reactions which give the products ethylene oxide, vinyl alcohol, vinyl aldehyde and vinyl radical for ethylene oxidation and the reactions which give propylene oxide, propanal, acetone and pi-allyl radical for propylene oxidation were investigated by using Density Functional Theory (DFT) method with B3LYP/LanL2DZ…
Embryonic and larval stages are thought to be more sensitive to environmental fluctuations than later life history stages. Therefore, examining how marine larval gastropods might be affected by climate change stressors, in this case, high temperatures and ocean acidification (OA), becomes important for predicting long…