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Seed-mediated synthesis of metal sulfide patchy nanoparticles

Toshiharu Teranishi、Masaki Saruyama、Masayuki Kanehara2009-01-01Nanoscale

Anisotropically phase-segregated nanoparticles, so-called patchy nanoparticles, are promising materials, because the close coupling of different components on the nanoscale may significantly improve application performance, or even create new properties. We review the seed-mediated synthesis of various kinds of metal…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanomaterials and Printing TechnologiesPickering emulsions and particle stabilization

Multi-responsive carbon nanotube gel prepared via ultrasound-induced assembly

Ye‐Zi You、Junjie Yan、Zhiqiang Yu 等 6 位作者2009-01-01Journal of Materials Chemistry

Hyperbranched poly(amido amine) is grown from the surface of carbon nanotubesvia a multi-step Michael addition reaction, hence the amido and amine units are linked onto the surface of carbon nanotubes. These amido and amine units can facilitate the assembly of carbon nanotubes with other functional polymersviahydrogen…

Carbon Nanotubes in CompositesAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Development of Underwater Laser Cladding and Underwater Laser Seal Welding Techniques for Reactor Components

Takehisa Hino、M. Tamura、Yoshimi Tanaka 等 7 位作者2009-01-01Journal of Power and Energy Systems

Stress corrosion cracking (SCC) has been reported at the aged components in many nuclear power plants. Toshiba has been developing the underwater laser welding. This welding technique can be conducted without draining the water in the reactor vessel. It is beneficial for workers not to exposure the radiation. The weld…

Hydrogen embrittlement and corrosion behaviors in metalsWelding Techniques and Residual StressesNuclear Materials and Properties

Double-gated graphene-based devices

Russo, S.、Craciun, M. F.、Yamamoto, M. 等 5 位作者2009-01-01Archive ouverte UNIGE (University of Geneva)

We discuss transport through double-gated single- and few-layer graphene devices. This kind of device configuration has been used to investigate the modulation of the energy band structure through the application of an external perpendicular electric field, a unique property of few-layer graphene systems. Here we disc…

Graphene research and applicationsQuantum and electron transport phenomenaSemiconductor materials and devices

Yawning Detection Based on Gabor Wavelets and LDA

Yanfeng Sun2009-01-01Journal of Beijing University of Technology

To improve driving safety,the authors propose an approach to locate a driver's mouth by a web camera and extract texture features from mouth comers for monitoring drivers' yawning.Firstly,it detects drivers' left and right mouth corners by gray projection based on the result of driver face detection,and then it extrac…

Textile materials and evaluations

A molecular cage of nickel(ii) and copper(i): a [{Ni(L)2}2(CuI)6] cluster resembling the active site of nickel-containing enzymes

Raja Angamuthu、Lodewijk Gelauff、Maxime A. Siegler 等 5 位作者2009-01-01Chemical Communications

A new mononuclear low-spin nickel(II) dithiolato complex, [NiL(2)] (1), reacts with copper iodide to form the hetero-octanuclear cluster [{Ni(L)(2)}(2)(CuI)(6)] (2) with four trigonal-planar CuI(2)S and two tetrahedral CuI(2)S(2) sites; anagostic interactions between the nickel(II) ions and aromatic protons have been…

Magnetism in coordination complexesMetalloenzymes and iron-sulfur proteinsMetal-Catalyzed Oxygenation Mechanisms

Mineralization for micropatterned growth of carbonate nanofibers

Jianhua Zhu、Jiming Song、Shu‐Hong Yu 等 5 位作者2009-01-01CrystEngComm

Large area arrays of patterned carbonate nanofibers have been constructed viapolymer controlled mineralization. Micropatterned octadecyltrichlorosilane (OTS)-coated domains on the smooth substrate were found to preferentially deposit mineral films, which could act as a secondary template for growth of nanofibers after…

Bone Tissue Engineering MaterialsCalcium Carbonate Crystallization and InhibitionCatalysis and Hydrodesulfurization Studies

Study of the thermoluminescence emission of a natural α-cristobalite

V. Correcher、J. Garcı́a-Guinea、M. A. Bustillo 等 4 位作者2009-01-01Radiation effects and defects in solids

The thermoluminescence (TL) properties of a well-characterised natural α-cristobalite from Lanzarote (Canary Islands, Spain) have been studied. The natural blue emission (at 400 nm) of this silica polymorph of quartz reveals the appearance of three groups of components peaked at 150, 230–240 and 370 °C, which could be…

Luminescence Properties of Advanced MaterialsMesoporous Materials and CatalysisClay minerals and soil interactions

How to mimic the shapes of plant tendrils on the nano and microscale: spirals and helices of electrospun liquid crystalline cellulose derivatives

M. H. Godinho、João P. Canejo、Luís F.V. Pinto 等 5 位作者2009-01-01Soft Matter

We show that suspended nano and microfibres electrospun from liquid crystalline cellulosic solutions will curl into spirals if they are supported at just one end, or, if they are supported at both ends, will twist into a helix of one handedness over half of its length and of the opposite handedness over the other half…

Electrospun Nanofibers in Biomedical ApplicationsAdvanced Materials and MechanicsSilk-based biomaterials and applications

Synthesis of spherical ordered mesoporous carbons from direct carbonization of silica/triblock-copolymer composites

Xin Yan、Huaihe Song、Xiaohong Chen2009-01-01Journal of Materials Chemistry

A novel spherical ordered mesoporous carbon with a high surface area and cage-type porous structure was prepared by direct carbonization of silica/triblock copolymer/butanol composite using F127 and butanol as both structure-directing agent and carbon precursor.

Supercapacitor Materials and FabricationMesoporous Materials and CatalysisLayered Double Hydroxides Synthesis and Applications

Localized Approach to Galvanic Coupling in an Aluminum–Magnesium System

Loïc Lacroix、Christine Blanc、Nadine Pébère 等 5 位作者2009-01-01Journal of The Electrochemical Society

The corrosion behavior of a pure aluminum/pure magnesium couple in a weakly conductive sodium sulfate solution was investigated. Potential and current distributions on the surface of the model couple at the beginning of immersion were obtained by solving the Laplace equation using a finite element method algorithm. Ma…

Corrosion Behavior and InhibitionConcrete Corrosion and DurabilityAnodic Oxide Films and Nanostructures

Effect of NaOH Treatments on Jute and Coir Fiber PP Composites

Nguyễn Minh Hải、Byung-Sun Kim、Soo In Lee2009-01-01Advanced Composite Materials

Changes occurring in jute and coir fiber composites with 2–8% concentration of a NaOH treatment for 24 h were investigated, respectively, for void content, microscopy images, mechanical properties and water absorption. The jute and coir fibers were vacuum dried before molding composite specimens. Mechanical properties…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research StudiesElectromagnetic wave absorption materials

Tensile Characterization of Carbon Nanotube-Reinforced Polymer Composites at Cryogenic Temperatures: Experimens and Multiscale Simulations

Т. Такеда、Yasuhide Shindo、Fumio Narita 等 4 位作者2009-01-01MATERIALS TRANSACTIONS

The purpose of this research is to experimentally and numerically evaluate the mechanical performance of carbon nanotube (CNT)-reinforced polymer composites subjected to tension in a cryogenic environment. Cryogenic tensile tests were conducted on CNT/polycarbonate composites to identify the effects of CNTs on their t…

Carbon Nanotubes in CompositesFiber-reinforced polymer compositesNanotechnology research and applications

Preparation of hollow silica spheres with holes on the shells

Yuanli Chen、Yi Li、Yuxia Chen 等 7 位作者2009-01-01Chemical Communications

Hollow silica spheres with holes on the shells were prepared using l-16Ala6PyBr via a sol-gel method.

Photonic Crystals and ApplicationsMesoporous Materials and CatalysisDiatoms and Algae Research

Solvatochromism of novel donor–π–acceptor type pyridinium dyes in halogenated and non-halogenated solvents

Yousuke Ooyama、Risa Asada、Shogo Inoue 等 6 位作者2009-01-01New Journal of Chemistry

Donor–π–acceptor type pyridinium dyes that have been newly synthesized showed bathochromic shift of the absorption band with decreasing dielectric constant (εr) of solvent (negative solvatochromism), and the bathochromic shifts in halogenated solvents were larger than those in non-halogenated solvents of similar εr va…

Molecular Sensors and Ion DetectionPhotochemistry and Electron Transfer StudiesPhotochromic and Fluorescence Chemistry

Self-assembly of amphiphilic fluorescent dyes showing aggregate-induced enhanced emission: temperature dependence of molecular alignment and intermolecular interaction in aqueous environment

Takashi Hirose、Kenji Matsuda2009-01-01Chemical Communications

A 1-cyano-1,2-bis(biphenyl)ethene derivative having hexa(ethylene glycol) groups as amphiphilic side chains showed aggregate-induced enhanced emission in water; upon heating the intensity of the enhanced emission was attenuated in a lower temperature range than the temperature range where exciton interaction is still…

Organic Light-Emitting Diodes ResearchLuminescence and Fluorescent MaterialsPhotochromic and Fluorescence Chemistry

Photoinduced electron transfer in aqueous carbon nanotube/block copolymer/CdS hybrids: application in the construction of photoelectrochemical cells

Grigoris Mountrichas、Atula S. D. Sandanayaka、Solon P. Economopoulos 等 7 位作者2009-01-01Journal of Materials Chemistry

Pristine and shorted multi-walled carbon nanotubes (pMWCNT and sMWCNT, respectively) non-covalently modified with a block copolymer (poly[sodium (2-sulfamate-3-carboxylate) isoprene-b-styrene]—abbreviated as CSI) are used for the formation of CdS semiconductor nanohybrids. The CdS nanoparticles are preferentially loca…

Organic Electronics and PhotovoltaicsCarbon Nanotubes in CompositesConducting polymers and applications

The role of the interface in the electronic structure of adsorbed metal(II) (Co, Ni, Cu) phthalocyanines

Jie Xiao、P. A. Dowben2009-01-01Journal of Materials Chemistry

We compare the electronic structures of metal(II) (Co, Ni, Cu) phthalocyanines adsorbed on conducting and insulating substrates: Au(111) and the organic ferroelectric polyvinylidene fluoride (PVDF). The different 3d orbital contributions to the metal phthalocyanines result in different substrate interactions, and diff…

Porphyrin and Phthalocyanine ChemistryTransition Metal Oxide NanomaterialsElectronic and Structural Properties of Oxides

Traditional medicine in Oman: Its role in ophthalmology

Radha Shenoy、A. Bialasiewicz、Rajiv Khandekar 等 5 位作者2009-01-01Middle East African Journal of Ophthalmology

AIM: To present three patients with ocular disease who developed a range of complications following use of traditional medications. SETTINGS AND DESIGN: Case series METHODS: Three patients who were examined in the Ophthalmic department of a tertiary care teaching hospital in the Sultanate of Oman between 2003 and 2004…

Nail Diseases and TreatmentsOcular Infections and TreatmentsPhytochemistry and Bioactive Compounds

Formation of mesoporous oxide fibers in polycarbonate confined spaces

Yusuke Yamauchi、Norihiro Suzuki、Tatsuo Kimura2009-01-01Chemical Communications

Mesoporous oxide fibers were prepared in one-pot by permeating surfactant-containing clear precursor solutions into the confined spaces of polycarbonate membranes and subsequent calcination.

Supercapacitor Materials and FabricationMesoporous Materials and CatalysisCovalent Organic Framework Applications