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Preparation of a Building Block for a Pyrazole Expanded Porphyrin and Isolation of a Tripyrrolyl Ketone Decomposition Product

Alfred Häßner、Eran Fogler2009-01-01Heterocycles

Dipyrrolylpyrazole 3, obtained from 1,3-di-(1H-pyrrol-2-yl)propane-1,3-dione (2), was prepared as a building block for pyrazole-based binuclear expanded porphyrins.An unusual transformation of 2, in solution or on chromatography, afforded 1,3,3-tri-(1H-pyrrol-2-yl)prop-2-en-1-one (4) in good yield.HRMS indicated the p…

Molecular Sensors and Ion DetectionPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Inevitable Cytochrome P450 Coordination Structure for Enzyme Function: Chemical Model Approach to Elucidation of the Axial Ligand Effect

Tsunehiko Higuchi2009-01-01Journal of Synthetic Organic Chemistry Japan

A distinctive structural feature of P450 is the unusual thiolate coordination to heme. We have succeeded in the preparation of the first synthetic thiolato-iron porphyrin (SR complex) that retains its structure during catalytic oxidation.Experiments using SR complex have revealed that the thiolate ligand greatly accel…

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsHemoglobin structure and function

The microscopic theory of fission

W. Younes、D. Gogny、A. Chatillon 等 7 位作者2009-01-01AIP conference proceedings

Fission‐fragment properties have been calculated for thermal neutron‐induced fission on a 239Pu target, using constrained Hartree‐Fock‐Bogoliubov calculations with a finite‐range effective interaction. A quantitative criterion based on the interaction energy between the nascent fragments is introduced to define the sc…

Nuclear physics research studiesNuclear Materials and PropertiesNuclear Physics and Applications

Elaboração e Caracterização de Filmes Biodegradáveis de Amido de Lírio do Brejo (Hedychium coronarium) e de Amido de Fruto-doLobo (Solanum lycocarpum St. Hill)

Rejane D. P. Mota、Diego P. R. Ascheri、José Luis Ramírez Ascheri2009-01-01Revista Processos Químicos

Uma nova tecnologia vem revolucionando o mercado de descartáveis: os filmes biodegradáveis produzidos a partir de amido. A partir de amidos de fruto-de-lobo e de lírio-do-brejo foram elaborados filmes biodegradáveis usando como plastificante o glicerol. Os amidos apresentaram teor de pureza elevada e diferiram no teor…

Nanocomposite Films for Food PackagingAgricultural and Food Sciences

Phase transition kinetics in Austempered Ductile Iron (ADI)

Peter Schaaf、Salvatore Cusenza、Μ. Bamberger 等 8 位作者2009-01-01iMPULSE (Heinz Maier-Leibnitz Zentrum)

A wide range of properties in Austempered Ductile Iron (ADI) components are related to changes in the proportions and morphology of the phases present in the heat-treated microstructure. The final microstructure (and thus the properties) strongly depends on composition, as-cast microstructure and phase transformation…

Microstructure and Mechanical Properties of SteelsMetallurgy and Material FormingMetal Alloys Wear and Properties

Fractal Analysis of the Corrosion Inhibition of Carbon Steel in a Bromide Solution by Lithium Chromate

Estela Sarmiento、J.G. González-Rodrı́guez、J. Uruchurtu 等 5 位作者2009-01-01International Journal of Electrochemical Science

Electrochemical noise results obtained for mild steel corrosion conditions under a lithium bromide-ethylene glycol solution and in the presence of different concentrations of lithium chromates (Li2CrO4) as corrosion inhibitor are shown. The evaluation was performed from the fractal dimension of the electrochemical noi…

Corrosion Behavior and InhibitionTheoretical and Computational PhysicsHydrogen embrittlement and corrosion behaviors in metals

Basics Product Design 02: Material Thoughts

David Bramston2009-01-01OpenAlex

Basics Product Design: Material Thoughts is an inspirational introduction to the many different materials and processes used in product design, exploring their properties and how they have been used by some of the most innovative designers around the world. Throughout the book, David Bramston covers everything from dr…

Material Selection and PropertiesSustainable Design and DevelopmentArchitecture and Computational Design

Crystal Structure and Fluorescent Study of a Binuclear Europium(III) Complex

Yin Liu2009-01-01OpenAlex

A novel binuclear Eu(Ⅲ) complex [Eu2(dpa dioxide)2(NO3)4(bpdioxide)-(EtOH)](dpa dioxide=di-2-pyridylamine N,N′-dioxide,bpdioxide=2,2′-bipyridine N,N′-dioxide) has been synthesized and it exhibits strong and sharp fluorescent emission at 614 nm under UV radiation of 245 nm at room temperature.X-ray structural determina…

Metal complexes synthesis and propertiesRadioactive element chemistry and processingLanthanide and Transition Metal Complexes

ESTIMATING THE RELIABILITY OF WELDED JOINTS OF THIN-WALLEDSTRUCTURES BASED ON THE RESULTS OF THEIR NONDESTRUCTIVECONTROL

А. А. Миронов、Василий Михайлович Волков2009-01-01Problems of Strength and Plasticity

The problem of estimating the reliability of welded thin-walled structures under static loading is solved. The stochastic nature of the stability of structures is determined by the presence of defects in welded joints. The earlier introduced by the present authors condition when the maximum value of the membrane compo…

Fatigue and fracture mechanicsEngineering Diagnostics and ReliabilityMaterial Properties and Failure Mechanisms

Improving the performance of painted wood siding: rain screen, end-grain seal, and back priming

Edward W. Burke、Tony Bonura、Charles G. Carll 等 11 位作者2009-01-01OpenAlex

Moisture control is essential to obtain decades of service from painted wood siding. Roof design and installation, including adequate overhang, flashing at roof edges, gutters, and downspouts, are critical for controlling water. Use rain-screen installation in conjunction with water-resistive barriers to shed water th…

Wood Treatment and PropertiesRemote Sensing and LiDAR ApplicationsTextile materials and evaluations

ADSORPTION OF N-HEXANE VAPORS ONTO NON-FUNCTIONALISED HYPERCROSSLINKED POLYMERS (HYPERSOL-MACRONETTM) AND ACTIVATED CARBON: THERMODYNAMIC AND KINETIC STUDIES

Adela Marilena Buburuzan、Cezar Catrinescu、Matei Macoveanu2009-01-01Environmental Engineering and Management Journal

The adsorption characteristics of n-hexane vapors from gaseous stream onto two types of hypercrosslinked polymeric resins (MN 202 and MN 250), and a bituminous granular activated carbon (AC 20) was investigated.The n-hexane influent concentration ranged from 2100 to 4500 ppm and the adsorption processes were performed…

Polymer composites and self-healingEpoxy Resin Curing ProcessesCatalysis and Oxidation Reactions

Algas fitoplanctónicas de ambientes lénticos y lóticos de la cuenca del Río Salado: tolerancia a factores físicos

Uara Carrillo、Néstor A. Gabellone、Lía Cristina Solari2009-01-01Americanae (AECID Library)

El objetivo de este trabajo fue evaluar las relaciones entre la densidad de algas fitoplanctónicas y factores físicos como la conductividad y la temperatura en ambientes lénticos y lóticos de la cuenca del río Salado. La información se obtuvo de 352 muestras tomadas en la laguna San Miguel del Monte, en la Lacombe y e…

Diatoms and Algae Research

Correlation between physical properties of superlattices obtained by means of electrochemical deposition method and ion spraying

M. Duś-Sitek、M. Nabiałek、B. Gągorowska2009-01-01Optica Applicata

This paper compares structural and magnetic properties of Cu/Ni and Ni/Cu multilayer systems obtained by means of ion sputtering and electrochemical deposition method. The impact of both thickness of Cu and Ni sublayers and a number of bilayers repetition on magnetic properties was also investigated. The purpose of th…

Magnetic properties of thin filmsCopper Interconnects and ReliabilityNanoporous metals and alloys

Property Analysis of Natural Brucite and Its Application as Sulfur Dioxide Absorbent

Seong‐Gu Kang、Myoung-Hwan Kim、Jin‐Bae Kim2009-01-01Clean Technology

Mg(OH)2 slurry was prepared by using natural mineral brucite mined in Liaoning province in China, and its de-SOx efficiency was compared with that of Mg(OH)2 slurry prepared by thermal decomposition and hydration of magnesite. The physical and chemical characteristics of Mg(OH)2 powders prepared from brucite and magne…

Methane Hydrates and Related PhenomenaIndustrial Gas Emission ControlMagnesium Oxide Properties and Applications

Study on preparation of Chito-oligosaccharide functional milk drink.

Yun Zhang、Cai BaiYan、Deng MeiRong2009-01-01Zhongguo rupin gongye

The optimum molecular weight and concentration of chito-oligosaccharide which added to the milk drink were determined by sin-gle factor experiments and orthogonal experiments.In this research,Chito-oligosaccharide functional milk drink was prepared,which based the bacteriostasis and health-promoting function of chito-…

Nanocomposite Films for Food PackagingBiopolymer Synthesis and Applications

Aspects sécurité des nanomatériaux et nanoparticules manufacturés

Éric Gaffet2009-01-01OpenAlex

Les nanomatériaux manufacturés représentent un domaine de la recherche scientifique et de l'industrie en pleine expansion. Le développement extrêmement rapide des nanomatériaux et des nanoparticules manufacturés engendre l'exposition à ces nano-objets d'une population de plus en plus importante (opérateurs en milieu i…

Nanoparticles: synthesis and applicationsExtraction and Separation ProcessesRecycling and Waste Management Techniques

STRAIN AND DAMAGE SENSING DURING LOADING OF CARBON NANOTUBE DOPED COMPOSITES

Patrik Fernberg、Roberts Joffe、Greger Nilsson2009-01-01Epubl LTU

This work explores the possibility to use resistance changes in a carbon nanotube (CNT) doped composites to monitor deformations and damage. Most other studies in the field are done on simplified uniaxial loading whereas current work also evaluates the possibilities to monitor strain in more complex loading case, such…

Carbon Nanotubes in CompositesTransition Metal Oxide NanomaterialsSmart Materials for Construction

Technology Trends for Photoresist and Research on Photo Acid Generator for Chemical Amplified Photoresist

Sung‐Hoon Kim、Sang‐Tae Kim2009-01-01Journal of the Chosun Natural Science

Lithographic data obtained from PHS(polyhydroxy styrene) having various functionalities were investigated by using a photoacid generator based on diazo and onium type. Chemically amplified photoresist based on the KrF type photoresist was developed by using a photoacid generator and multi-functional resin. Thermal sta…

Advancements in Photolithography TechniquesSynthesis and properties of polymersPhotopolymerization techniques and applications

Syntheses of Cadmium Sulfide Nanorods and Network Nanowires by Bovine Serum Albumin

Xiao Po Wang、Hong Xu、Lei Tao 等 7 位作者2009-01-01Acta Physico-Chimica Sinica

Highly ordered CdS nanorods and network nanowires were prapared by reacting cadmium ions with thioacetamide (TAA) using bovine serum albumin (BSA) as a biomineralization template with a facile and environmentally benign biomineralization method. The morphology, elemental composition, optical property, and microelectro…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsBiotin and Related Studies