Materials Literature
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The growth of atomically-flat thin films of ferroelectric PbTiO3 on SrTiO3 substrates, using molecular beam epitaxy, is reported. The main issue in the growth of these materials is the high volatility of lead. This can be largely overcome by using PbO, instead of Pb, as a source and by using atomic oxygen during growt…
In the present paper a plastic-damage model for concrete is discussed. Based on the fact that for isotropic materials the elastic trial stress and the projected plastic stress states have the same eigenvec-tors, the loading surface is formulated in the principal stress space rather than using the invariants of stress…
The lower critical solution temperature (LCST) of the poly(2-alkyl-2-oxazoline)s (POx) was precisely tuned over a broad range of temperatures via the well-defined gradient or random copolymerization between 2- n -propyl-2-oxazoline ( n PrOx) and either 2-isopropyl-2-oxazoline ( i PrOx) or 2-ethyl-2-oxazoline (EtOx). A…
We have developed new inorganic-based drug delivery systems through the hybridization of indole-3-acetic acid (IAA) and layered metal hydroxide such as zinc basic hydroxide salt (ZBS) and zinc aluminum layered double hydroxide (ZALDH). A coprecipitation method as well as an ion-exchange route is found to be commonly e…
We study the existence and topological stability of Fermi points in a graphene layer and stacks with many layers. We show that the discrete symmetries (space-time inversion) stabilize the Fermi points in monolayer, bilayer, and multilayer graphenes with orthorhombic stacking. The bands near $k=0$ and $ϵ=0$ in multilay…
Photovoltaic performance of the hybrid devices consisting of polymer/fullerene/ZnO nanorod array was studied. The dependence of the photovoltaic performance on the ZnO nanorod length and the organic layer thickness was investigated, and it is concluded that the ZnO nanorod array plays an important role in collecting p…
We present the analytical solution of the wave function and energy dispersion of armchair graphene nanoribbons (GNRs) based on the tight-binding approximation. By imposing the hard-wall boundary condition, we find that the wave vector in the confined direction is discretized. This discrete wave vector serves as the in…
The geometry, electronic, and structural properties of an unusually stable boron cage made of 80 boron atoms are studied, using ab initio calculations. The shape of this cluster is very similar to that of the well-known C60 fullerene, but in the B80 case, there is an additional atom in the center of each hexagon. The…
Abstract Recent advancements in morphology control and surface functionalization of mesoporous silica nanoparticles (MSNs) have enhanced the biocompatibility of these materials with high surface areas and pore volumes. Several recent reports have demonstrated that the MSNs can be efficiently internalized by animal and…
We successfully developed 256Mb Phase Change Random Access Memory (PRAM) based on 0.10μ m-CMOS technologies using ring type contact. The writing current with uniform CD process variation of Bottom Electrode Contact (BEC) was achieved by improving CMP process and developing core dielectric material. Also, the ring type…
Mit feinem Überzug: Monodisperse Mn3O4-Nanopartikel mit dünner MnO2-Schale bilden nach ihrer Herstellung selbstorganisierte dreidimensionale Anordnungen mit kubischer Symmetrie (siehe Transmissionselektronenmikroskopiebild). Infolge starker Wechselwirkungen zwischen Kern und Schale verhalten sich die Nanopartikel wie…
Vor und zurück: Ausgeprägte dynamische Strukturänderungen werden in den Komplexen [{P2W15O54(H2O)2}2Zr]12− und [{P2W15O54(H2O)2}Zr{P2W17O61}]14− durch vollständig reversible Mehrfachprotonierungen ausgelöst – vergleichbar mit der Anspannung eines Muskels (siehe Bild). Die pH-Titration des ersten Komplexes spricht für…
To dry chemically bound moisture of AlF3·3H2O efficiently and with less hydrolyzation, the thermal decomposition mechanism and kinetics of AlF3·3H2O were established by the thermo-gravimetric technique. The results indicated that the thermal decomposition process of AlF3·3H2O consisted of two stages: a rapid dehydrati…
Abstract Undoped and vanadium‐doped ZnO thin films were prepared on single‐crystalline p‐type Si(100) substrates by a sol–gel process and further annealed in an oxygen atmosphere. The influence of vanadium doping on the structural, surface morphological and optical properties of ZnO thin films was investigated by X‐ra…
The Si-C bond breakings in tetramethylsilane (TMS) when interacting with H/H2 and the successive H abstractions from SiH4/CH4 in the gas mixture of H2/ CH4/TMS were studied at the CCSD(T)/6-311+G**//MP2/6-31+G** level of theory. Their rate constants between 1500 and 2500 K were estimated using a conventional transitio…
Oriented M-type hexaferrite thin films are deposited using the alternating target laser ablation deposition (ATLAD) technique utilizing PbO and Fe2O3 targets. Crystallographic, dc magnetic, and microwave characterization results confirming the presence of a hexagonal PbFe12O19 phase are presented. We conclude that the…
The interactions of a range of monocarboxylic acids with tetramethoxysilane Si(OMe)(4) (TMOS), in methanol (MeOH), have been investigated by using (1)H, (13)C and (29)Si solution-phase NMR spectroscopy and electrospray mass spectrometry (ESMS). Si(OMe)(4) acts as a catalyst/reagent in the selective methylation of 2-hy…
The hexaazamacrocycle 1,4,7,10,13,16-hexaazacyclooctadecane, [18]ane-N6, forms mono- and dinuclear derivatives with copper chloride depending on the reaction stoichiometries and times. The mononuclear derivative, [Cu([18]ane-N6)]Cl2.H2O, presents the macrocycle wrapped around the metal atom in a distorted octahedral c…
${\mathrm{Mn}}_{3}\mathrm{Zn}\mathrm{C}$ possesses a magnetic phase transition at ${T}_{t}=233\phantom{\rule{0.3em}{0ex}}\mathrm{K}$ from a ferromagnetic phase to a ferrimagnetic one with a noncollinear magnetic structure. The transition is accompanied by a structural change from cubic to tetragonal. The experimentall…
Magnesium hydroxide precipitate was prepared using magnesium chloride and urea as starting materials via a homogenous precipitation method. Before it was calcined to obtain magnesium oxide nanoparticles, the precipitate was pretreated and dried using different pretreatments and drying methods. The as-prepared magnesiu…