Materials Literature
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Multisegmented one-dimensional hybrid structures of carbon nanotubes and metal nanowires were fabricated using the alumina templates. Metal nanowires are first grown inside part of the nanochannel using electrodeposition technique, which is followed by the growth of carbon nanotubes using chemical vapor deposition. We…
The authors have fabricated a field-effect transistor (FET) based on a rutile TiO2 active channel. Top-gate transistor structure with an amorphous LaAlO3 insulator was fabricated on the ultrasmoothed rutile single crystals. Reproducible n-type FET actions were observed only by the use of ultrasmoothed TiO2 surfaces. M…
Chiral propeller architectures (see figure and inside cover) are constructed from achiral molecules via hydrogen bonding self-assembly in addition to Frank–Pryce spherulitic droplet and fingerprint textures. It is found, for the first time, that neither molecular chirality nor a molecular bend is necessary to form a c…
The growth mechanism of pentacene film formation on $\mathrm{Si}{\mathrm{O}}_{2}$ substrate was investigated with a combination of atomic force microscopy measurements and numerical modeling. In addition to the diffusion-limited aggregation (DLA) that has already been shown to govern the growth of the ordered pentacen…
Ge 2 Sb 2 Te 5 (GST) film in the crystalline state was nitrogen doped using the reactive sputtering method in order to increase sheet resistance. High-resolution x-ray absorption spectroscopy revealed that molecular nitrogen (N2) existed in the N-doped GST film. This finding implies that both molecular nitrogen and at…
Spintronics, which takes advantage of both spin and charge degrees of freedom, is a promising key technique relevant to future applications of information and data storage. Ferromagnetic transition metal oxides, including perovskite manganites, represent the most promising materials for use as devices controlling magn…
We perform density-functional calculations to investigate the effect of adsorbed water molecules on carbon nanotubes (CNTs). Noting that the H2O molecule has much wider energy gap than the CNT, we find that the charge transfer between them is negligible. We discuss that several recent publications, which claimed a sub…
The authors experimentally demonstrate strong light confinement and enhancement of emission at 1.54μm in planar silicon-on-insulator waveguides containing a thin layer (slot) of SiO2 with Er3+ doped Si nanoclusters. Angle-resolved attenuated total reflectance is used to excite the slab guided modes, giving a direct ev…
Abstract Canola oil (CO) gels were formed using ricinelaidic acid (REA), a hydroxylated fatty acid, and the time, temperature, and concentration dependence of the resulting gel structure was studied using small‐deformation rheology, light microscopy, and powder X‐ray diffraction (XRD). Between 5 °C and 30 °C, REA conc…
This paper reports an experimental study on the synthesis and electrochemical properties of InVO4 nanotube arrays fabricated by capillary-enforced sol-filling in templates in combination with solvent-evaporation induced deposition. InVO4 sol was synthesized using the sol–gel route from vanadium oxoisopropoxide and ind…
Abstract A transmission line (TL) model describing the propagation of electric signals along metallic single wall carbon nanotube (CNT) interconnects is derived in a simple and self‐consistent way within the framework of the classical electrodynamics. The conduction electrons of metallic CNTs are modelled as an infini…
The authors report a complete set of elastic, dielectric, and piezoelectric coefficients of rhomboheral phase 0.93Pb(Zn1∕3Nb2∕3)O3–0.07PbTiO3 single crystal poled along [011] measured at room temperature. It was found that the electromechanical coupling coefficients k32 and k33 of this domain engineered single crystal…
The synthesis of supramolecular conducting nanowires can be achieved by using DNA and pyrrole. Oxidation of pyrrole in DNA-containing solutions yields a material that contains both the cationic polypyrrole (PPy) and the anionic DNA polymers. Intimate interaction of the two polymer chains in the self-assembled nanowire…
Epitaxial ferri(ferro)magnetic Fe3−xZnxO4 thin films (x=0–0.9) were prepared using a pulsed-laser deposition technique. The electrical conductivity and magnetic properties of Fe3−xZnxO4 thin film were systematically modulated for the entire range of Zn substitution. Anomalous Hall coefficient measurements revealed the…
The dynamics of multivacancy defects in a graphene layer is investigated by tight-binding molecular dynamics simulations and by first principles calculation. The simulations show that four single vacancies in the graphene layer first coalesce into two double vacancies, each consisting of a pentagon-heptagon-pentagon (…
Abstract ZnO–Sb 2 O 3 –B 2 O 3 glasses containing different concentrations of chromium ions (introduced as CrO 2– 4 ) ranging from 0 to 1.0 mol% were prepared. A number of studies viz., differential thermal analysis, infrared, optical absorption, Raman and ESR spectra and dielectric properties (constant ε ′, loss tan…
A giant current-to-voltage (I-V) gyration effect was found in magnetostrictive Tb1−xDyxFe2−y and piezoelectric Pb(Zr,Ti)O3 laminated composites. An equivalent circuit theory was developed for magnetoelectric gyration, which predicted that I-V conversion is reduced by a frequency transfer function ZR(f) and that the ma…
We calculate the exchange interaction parameters of a classical Heisenberg Hamiltonian for Mn-doped ZnO (Mn concentration between 5% and 20%) by an ab initio Korringa-Kohn-Rostoker coherent-potential-approximation method in the framework of density functional theory. A weak antiferromagnetic exchange interaction is ob…
Ultrasound has been used to trigger release of encapsulated material from polyelectrolyte multilayer capsules. Sonication was found to destroy both plain and nanoparticle-modified capsules. Cavitation occurs through the collapse of generated microbubbles and the resulting shear forces should cause the destruction of t…
Octahedral nanoparticles of gold are prepared via a short thermal decomposition of auric acid loaded polystyrene-block-poly(2-vinylpyridine) copolymer solutions. Thermal treatment of a monolayer of HAuCl4-loaded block copolymers on silicon leads to quantitative Au0 production, of which > 70 % is in the form of sub-100…