Materials Literature
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Abstract Azobenzene chromophores can be switched between two geometric isomers using visible light. This photoisomerization is rapid, reversible, and of high quantum yield, and the wavelengths effecting the transformation can be tuned synthetically with substituent groups to the chromphores. Upon isomerization, there…
The first stable pi-dimer of a tetrathiafulvalene (TTF) cation radical encapsulated in the cavity of cucurbit[8]uril has been isolated at room temperature and fully characterized; it shows absorption bands at 400, 540 and 760 nm, characteristic of the TTF cation radical dimer.
This paper reports a novel immunoassay based on surface-enhanced Raman scattering (SERS) and immunogold labelling with silver staining enhancement. Immunoreactions between immunogold colloids modified by a Raman-active probe molecule (e.g., 4-mercaptobenzoic acid) and antigens, which were captured by antibody-assemble…
Ni-free Ti-base shape memory alloys (SMA) have been systematically developed by our group for biomedical applications in order to replace Ti-Ni SMAs which posses the possibility of Ni-hypersensitivity. In this study, superelastic behavior of solution-treated Ti-24 mol%Nb-3 mol%Al alloy was investigated by means of ten…
In this review, we examine the role of oxide support defects, cluster size-dependence, cluster structural fluxionality, and impurity doping on the catalytic properties of size-selected metal clusters on surfaces. By combining experimental results from the oxidation of CO on size-selected gold clusters with ab-initio c…
Luminescent semiconductor quantum dots (QDs) are a new class of fluorescent label with wide-ranging applications for cell imaging. The electron density and elemental composition of these materials permit the extension of their use as probes in conventional electron microscopy (TEM) and energy-filtered TEM (EFTEM). Her…
Einstein and Smoluchowski's treatment of the Brownian motion has been discussed. It is shown that although the diffusion equations derived from both treatments are mathematically identical, Smoluchowski's equation defines a somewhat concentration-dependent diffusion coefficient, while Einstein's equation defines a con…
Monolithic silica gel microhoneycombs, which have an array of straight macropores within their structure and developed micro/mesopores inside their walls, were prepared using pseudosteady state growth of ice crystals which occurs during the unidirectional freeze-gelation of freshly gelled aqueous silica hydrogels, fol…
Electrochemical oxidation of methanol, ethanol, glycerol and ethylene glycol (EG) on novel Pt-CeO(2)/C catalysts in alkaline media has been studied and shows an improved performance in terms of the electrode activity and the poisoning resistance.
This paper describes a method to fabricate short bamboo fiber reinforced “green” composites (BFGC) and evaluate their mechanical properties. The composites were prepared by hot-pressing a mixture of starch-based resin and short bamboo fibers. Their tensile strength and flexural strength were characterized. The effects…
The synthesis of the unsymmetrically substituted beta-diketimine, 2-(2-methoxyphenylimino)-4-(2,6-diisopropylphenylamido)pent-2-ene, (BDI-2)H, is described and its complexation chemistry with magnesium and zinc is explored. Emphasis is placed on the preparation of alkoxide and amide derivatives for the ring-opening po…
Hierarchical inorganic porous monoliths have been prepared using concentrated emulsion and micellar templates. The texture of these monoliths has to be tuned varying either the pH of the continuous aqueous phase, the emulsification process or the oil volumic fraction. These materials show interconnected macroporosity…
Silver nanoparticles of different morphologies were prepared using the polyol process and then dispersed on alpha-alumina. Catalysts were tested for the selective oxidation of styrene in the gas phase. Activity and selectivity were strongly dependent on the morphology of the silver nanoparticles.
The search for alternative anode materials for solid oxide fuel cells (SOFCs) has been reviewed in the light of structure, stability, conductivity, chemical and thermal compatibility with electrolyte YSZ. In this review, we have presented the advantages and disadvantages of the traditional Ni-YSZ anode for SOFCs. The…
Dendrimers, alkylthiol-gold nanoparticles and gold-nanoparticle-cored dendrimers containing tethers terminated by a redox group (typically an iron sandwich) attached to a hydrogen-bonding group (amido, amino, silyl) are selective and efficient exo-receptors for the recognition, sensing and titration of oxo-anions, inc…
The conjugation of inorganic materials with biological systems has attracted research interest, as a consequence of the availability of the sol–gel process, operating under experimental conditions compatible with biomolecules and whole cells. In Section 2, the merits and limitations of alkoxide-based sol–gel silica as…
Encapsulating enzymes in mesoporous silica spheres via immobilization, followed by assembling an organic/inorganic nanocomposite shell on the particle surface leads to high loadings, high enzymatic activity and stability, and protection from proteolysis.
Mono-dispersed mesoporous silica spheres with highly ordered hexagonal regularity were obtained with tetramethoxysilane (TMOS)–alkyltrimethylammonium chloride–methanol–water–sodium hydroxide. Just by changing the methanol ratio in the solvent, mono-dispersed particles were obtained with C14TMACl, C16TMACl and C18TMACl…
Cuprous oxide has been prepared by the photoelectrochemical reduction of a CuO film formed on a conducting substrate by the anodic deposition from an alkaline solution of a Cu(II)-amino acid complex. Both copper oxide films thus prepared are found to be typical p-type semiconductors. The onset of the cathodic photocur…
Highly uniform Cu2O nanocubes can be prepared by using a simple solution approach. Copper(II) salts in water are reduced with ascorbic acid in air in the presence of polyethylene glycol (PEG) and sodium hydroxide. The average edge length of the cubes can be controlled from 25 to 200 nm by changing the order of additio…