Materials Literature
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Anomalous induced magnetic effects were observed in a directly fused square-planar porphyrin sheet 1, in that the protons above the center of the tetraporphyrin core were characteristically shifted downfield in the 1H NMR spectrum. These observations suggest a rare paratropic ring-current effect around the planar cycl…
First-principles density functional calculations were performed to study strain effects on the energy gaps in silicon nanoclusters with diameter ranging from 0.6 to 2 nm. Hydrostatic and non-hydrostatic strains have been found to affect the energy gaps differently. For the same strain energy density, non-hydrostatic s…
Multiphonon Resonant Raman scattering (RRS) excited by 351.1 and 363.8 nm lines of an Ar+ laser was studied at temperatures from 10 to 300 K in as-grown and rapid thermal annealed (RTA) aluminum doped ZnO nanorods synthesized by an aqueous chemical deposition method using zinc sulfate, aluminum sulfate, and ammonia hy…
We have studied the collapse of pseudo-bi-dimensional foams. These foams are made of uniformly sized soap bubbles packed in an hexagonal lattice sitting at the top of a liquid surface. The collapse process follows the sequence: (1) rupture of a first bubble, driven by thermal fluctuations and (2) a cascade of bursting…
It is shown that a strong impurity potential induces short-range antiferromagnetic (ferrimagnetic) order around itself in a Hubbard model on a half-filled honeycomb lattice. This implies that short-range magnetic order is induced in monolayer graphene by a nonmagnetic defect such as a vacancy with full hydrogen termin…
The structure of dicalcium heptagermanate, previously described with an orthorhombic space group, has been redetermined in the tetragonal space group P(overline4)b2. It contains three Ge positions (site symmetry 1, ..2 and 2.22, respectively), one Ca position (..2) and four O atoms, all on general 8i positions (site s…
A step forward: Large single crystals of the new magnetic solid RbNa3Fe7(PO4)6 can be grown in a salt flux. Below the ferro-to-antiferromagnetic transition temperature of 6 K, the field (H) dependence of the magnetization (M) of an oriented crystal of the compound (see graph) exhibits equally spaced steps (arrows), wh…
Size quantised cadmium sulphide (CdS) nanocrystalline thin films with different particle sizes and stoichiometric ratios were successfully grown on indium tin oxide substrates using an aqueous synthetic route. The effect of cadmium (Cd) to sulphur (S) ratio on the optical properties of CdS nanocrystalline films was in…
Adsorption characteristics of zein protein on hydrophobic and hydrophilic surfaces have been investigated to understand the orientation changes associated with the protein structure on a surface. The protein is adsorbed by a self-assembly procedure on a monolayer-modified gold surface. It is observed that zein shows h…
Allosteric activation of fructose-1,6-bisphosphatase (FBPase) from Escherichia coli by phosphoenolpyruvate implies rapid feed-forward activation of gluconeogenesis in heterotrophic bacteria. But how do such bacteria rapidly down-regulate an activated FBPase in order to avoid futile cycling? Demonstrated here is the al…
The Landau-de Gennes type continuous model is used to describe the 2D modulated structures made of bent-core liquid crystals. It is shown that modulation is a direct consequence of the chiral symmetry breaking. Structures with synclinic and anticlinic layer tilt are found to coexist in the polarization modulated and l…
A method for preparing carbon nanoparticles (CNPs) with controllable hierarchic structures is developed by combining the precursor-defined pyrolysis and the template method. Well-organized monodisperse CNPs, such as spherical particles with 3D porous structures (a), hollow carbon orbs containing small Pt particles (b)…
Glucose-1-phosphate uridylyltransferase, or UGPase, catalyzes the production of UDP-glucose from glucose-1-phosphate and UTP. Because of the biological role of UDP-glucose in glycogen synthesis and in the formation of glycolipids, glycoproteins, and proteoglycans, the enzyme is widespread in nature. Recently this labo…
The reaction of 3 equiv of the ligand 2-mercapto-3,5-di-tert-butylaniline, H2[LN,S], or 3,5-di-tert-butyl-1,2-benzenedithiol, H2[LS,S], with 1 equiv of [MoO2(acac)2] or WCl6 (acac=acetonylacetate(1-)) in methanol or CCl4 afforded the diamagnetic neutral complexes [MoV(LN,S)2(L*N,S)]0 (1), [MoV(LS,S)2(L*S,S)] (2), and…
Abstract Non linear optical (NLO) materials have acquired new significance with the advent of a large number of devices utilizing solid‐state laser sources. Several NLO materials have been used for this kind of technological applications. The Potassium di‐hydrogen phosphate (KDP) one of NLO material having superior no…
A new spectroscopic cell suitable for the analysis of heterogeneous catalysts by fluorescence EXAFS (extended X-ray absorption fine structure), transmission EXAFS and X-ray diffraction during in situ treatments and during catalysis is described. Both gas-phase and liquid-phase reactions can be investigated combined wi…
The electromagnetic response of graphene in a magnetic field is studied, with particular emphasis on the quantum features of its ground state (vacuum). The graphene vacuum, unlike in conventional quantum Hall systems, is a dielectric medium and carries an appreciable amount of electric and magnetic susceptibilities. T…
Resonance Raman spectra of individual strained ultralong single-wall carbon nanotubes (SWNTs) are studied. Torsional and uniaxial strains are introduced by atomic force microscopy manipulation. Torsional strain strongly affects the Raman spectra, inducing a large downshift in the E2 symmetry mode in the G+ band, but a…
A number of substituted zinc(II) porphycenes and porphyrins have been synthesized as potentially mesogenic materials. One of the resulting porphycenes, bearing eight decyloxy chains, exhibits two mesophases, a transient lamellar phase (Lam) and a highly ordered lamello-columnar phase (L(Col)), with remarkably differen…
We encapsulated cisplatin into stealth pH-sensitive liposomes and studied their stability, cytotoxicity and accumulation in a human small-cell lung carcinoma cell line (GLC4) and its resistant subline (GLC4/CDDP). Since reduced cellular drug accumulation has been shown to be the main mechanism responsible for resistan…