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Fluorescence enhancement and cofluorescence in complexes of terbium(III) with trimellitic acid

Xia Zhao、Kun Huang、Fang Jiao 等 5 位作者2006-04-01Rare Metals

The fluorescence of terbium (III) was enhanced by about three orders of magnitude in the presence of trimellitic acid (benzene-1, 2, 4-tricarboxylic acid (TLA)) in aqueous solution at pH 6. The fluorescence intensity could be greatly increased when the system of Tb 3+ -TLA was treated with La 3+ (or Gd 3+ ) and Triton…

Analytical chemistry methods developmentRadioactive element chemistry and processingLanthanide and Transition Metal Complexes

Phase separation and ordering in the Fe-Co system

Yu. I. Ustinovshikov、Б. Е. Пушкарев、И. В. Сапегина2006-04-01Inorganic Materials

The Fe 50 Co 50 , Fe 65 Co 35 , and Fe 35 Co 65 alloys heat-treated between 500 and 1300°C were characterized by x-ray diffraction and transmission electron microscopy. The surface layer of the alloys was found to phase-separate in the range 900–1300°C, leading to the formation of alternating α and γ zones on the orde…

Microstructure and Mechanical Properties of SteelsMagnetic Properties of AlloysMetallurgical and Alloy Processes

Ab Initio Molecular Dynamics Simulation of NO Reactivity on the CaO(001) Surface

Cristiana Di Valentin、Gianfranco Pacchioni、Marco Bernasconi2006-04-01The Journal of Physical Chemistry B

Ab initio molecular dynamics (MD) is used to investigate NO reaction processes on the (001) surface of CaO. A novel path is proposed for the first steps of nitrogen oxides reactivity catalyzed by the CaO surface. The mechanism consists of the formation of anionic dimers, adsorbing on the surface cations, at the expens…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceGas Sensing Nanomaterials and Sensors

Changes in surface morphology of Tencel fabric during the fibrillation process

Cheuk Ming Mak、C.W.M. Yuen、S. K. A. Ku 等 4 位作者2006-04-01Journal of the Textile Institute

The changes in surface morphology of Tencel fabric at each step of the fibrillation process were investigated by means of scanning electron microscopy. The results showed that after the removal of sizing materials in the desizing process, fibrillation started to occur and the fibrillation effect was further enhanced w…

Advanced Cellulose Research StudiesDyeing and Modifying Textile FibersTextile materials and evaluations

Modeling Transverse Behavior of Kevlar® KM2 Single Fibers with Deformation-induced Damage

Ming Cheng、Weinong Chen2006-04-01International Journal of Damage Mechanics

A phenomenological continuum model is adapted to describe the transverse mechanical behavior of Kevlar ® KM2 single fibers in compression. This model could be used for numerical simulations of the mechanical behaviors of fabrics made of Kevlar ® KM2 fibers. An equivalent fiber model is used to form the phenomenologica…

Mechanical Behavior of CompositesElasticity and Material ModelingTextile materials and evaluations

Maleic anhydride grafting of polypropylene: peroxide and solvent effects

L. E. Krause-Sammartino、Juan C. Lucas、M. M. Reboredo 等 4 位作者2006-04-01Plastics Rubber and Composites Macromolecular Engineering

The grafting of polyolefins with maleic anhydride (MA) has been incorporated into industrial practice to generate copolymers that can act as coupling agents between the non-polar polyolefins and different polar fillers and reinforcements. In the present study, two different peroxides were used to initiate the MA graft…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Poppiite, the V3+ end-member of the pumpellyite group: Description and crystal structure

Maria Franca Brigatti、Enrico Caprilli、Marco Marchesini2006-04-01American Mineralogist

Poppiite, a new mineral from Gambatesa mine (Val Graveglia, Genova, Northern Italy), is the V 3+ end-member of the pumpellyite group [ [VII] (Ca 7.68 Na 0.27 K 0.03 Rb 0.02 ) Σ8.00 [VI] (V 3+ 1.26 Fe 3+ 1.02 Mg 0.78 Mn 2+ 0.59 Al 0.31 Cu 2+ 0.04 ) Σ4.00 [VI] (V 3+ 6.89 Al 1.07 Ti 0.04 ) Σ8.00 [IV] (Si 11.69 Al 0.31 )…

Crystal Structures and PropertiesChemical Synthesis and CharacterizationX-ray Diffraction in Crystallography

Carbon nanotube as NEMS sensor - effect of chirality and stone-wales defect intend

V. Gayathri、R. Geetha2006-04-01Journal of Physics Conference Series

Having nanosize and unique electrical properties, carbon nanotubes (CNTs) attract lot of interest among scientific community all over the world. One of the recent observations is its role as nanosensors. Obviously the nanosize and high strength of CNT are most preferred parameter for technical and electromechanical fi…

Carbon Nanotubes in CompositesGraphene research and applicationsMechanical and Optical Resonators

High-pressure synchrotron X-ray powder diffraction studies of zeolites

Joseph A. Hriljac2006-04-01Crystallography Reviews

Zeolites are crystalline porous aluminosilicate framework solids. Although there are many reports of how the structures change as a function of temperature, similar studies as a function of high pressure are relatively scarce. With the increasing availability of synchrotron X-ray sources and greater knowledge in the c…

Zeolite Catalysis and SynthesisCrystal Structures and PropertiesX-ray Diffraction in Crystallography

Pressure–temperature phase diagrams for four higher members (nonyl–dodecyl) of the homologous series of4′-alkyl-4-isothiocyanato-biphenyl (nBT)

Stanisław Urban、J. Czub、R. Dąbrowski 等 4 位作者2006-04-01Phase Transitions

Differential thermal analysis (DTA) method was applied to study the pressure–temperature phase diagrams for four members of the 4′-alkyl-4-isothiocyanato-biphenyl (nBT) homologous series (n = 9–12). These compounds exhibit a smectic E polymorphism enriched by a smectic A phase for two longest members. Measurements wer…

Liquid Crystal Research AdvancementsMolecular spectroscopy and chiralitySynthesis of Organic Compounds

Evaluation of Chenille Yarn Abrasion Behavior with Abrasion Tests and Image Analysis

Erhan Kenan Çeven、Özcan Özdemir2006-04-01Textile Research Journal

Chenille yarns are vulnerable to abrasion because of easy pile loss. In this study different chenille yarns were produced from sirospun and two-folded ring, 100% wool and 50% wool-50% polyester blend yarns of different fiber fineness. A yarn abrasion device was designed in order to measure the abrasion resistance of c…

Dyeing and Modifying Textile FibersTextile materials and evaluationsCollagen: Extraction and Characterization

Activated carbon fiber composites for ammonia, methane and hydrogen adsorption

L. L. Vasiliev、L. E. Kanonchik、А. Г. Кулаков 等 6 位作者2006-04-01International Journal of Low-Carbon Technologies

Complex compound material (activated carbon fiber, saturated with salts, or metal hydrides) was developed as an efficient gas (ammonia, methane, hydrogen) adsorbent for new gas storage and transportation system application. To enhance the performance and thermodynamic efficiency of the gas storage vessels a heat pipe…

Hydrogen Storage and MaterialsAdsorption and Cooling SystemsAerogels and thermal insulation

In‐situ thickness measurement of porous alumina by atomic force microscopy and the reflectance wavelength measurement from 400–1000 nm

Dongxian Zhang、Haijun Zhang、Yulin He2006-04-01Microscopy Research and Technique

This article presents a novel method to measure the in situ thickness of porous alumina (PA) films. The PA films were prepared in oxalic acid at 30, 40, and 60 V direct current. Based on the atomic force microscope measurements, PA film porosities and refractive indexes measurements were acquired. With the observation…

Force Microscopy Techniques and ApplicationsAnodic Oxide Films and NanostructuresNear-Field Optical Microscopy

High Strength Aluminum Alloys Reinforced by Nanosize Quasicrystalline Particles for Elevated Temperature Application

Yu.V. Milman、A.I. Sirko、M.O. Iefimov 等 6 位作者2006-04-01High Temperature Materials and Processes

Article High Strength Aluminum Alloys Reinforced by Nanosize Quasicrystalline Particles for Elevated Temperature Application was published on April 1, 2006 in the journal High Temperature Materials and Processes (volume 25, issue 1-2).

Microstructure and mechanical propertiesAluminum Alloys Composites PropertiesQuasicrystal Structures and Properties

Electrical resistivity of liquid Bi–Sb alloys

Fang‐Qiu Zu、Yuanxing Li、Hou-Fu Ding 等 4 位作者2006-04-01Phase Transitions

The electrical resistivities of liquid Bi–Sb alloys have been measured by DC four-probe method within Bi-rich composition through a wide temperature range. The distinct anomaly of a hump shape was observed on resistivity–temperature (ρndash;T) curves for liquid Bi–Sb alloys on heating at the relatively high temperatur…

Material Dynamics and PropertiesPhase-change materials and chalcogenidesThermodynamic and Structural Properties of Metals and Alloys

Laser processing of diamondlike carbon thin films for medical prostheses

Roger J. Narayan2006-04-01International Materials Reviews

Diamondlike carbon thin films may provide next generation medical device surfaces with unique hardness, friction, wear, corrosion, and cell interaction properties. In the present paper, laser processing, mechanical properties, and medical applications for diamondlike carbon thin films are reviewed. Diamondlike carbon…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchPolymer Nanocomposite Synthesis and Irradiation

Nano-Tribological Analysis by Molecular Dynamics Simulation—A Review

L. C. Zhang、Kausala Mylvaganam2006-04-01Journal of Computational and Theoretical Nanoscience

The advent of super computers for large scale atomic simulations and the invention of proximal testing devices such as atomic force microscope, friction force microscope, surface force apparatus, nanoScratcher etc., have led to the development of micro- and nano-tribology. This paper reviews some fundamental concepts…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchForce Microscopy Techniques and Applications

Protein rejecting properties of PEG-grafted nanoparticles: influence of PEG-chain length and surface density evaluated by two-dimensional electrophoresis and bicinchoninic acid (BCA)-proteinassay.

Andrea Gessner、B.‐R. Paulke、Rainer Müller 等 4 位作者2006-04-01PubMed

Poly (ethylene glycol) (PEG)-grafted nanoparticles have been described as potential intravenously injectable, long-circulating drug carriers. The in vivo behaviour of intravenous administered nanoparticles is decisively influenced by the interaction of the particles with the blood proteins. Two-dimensional electrophor…

Nanoparticle-Based Drug DeliveryPolymer Surface Interaction StudiesAdvanced Drug Delivery Systems

A Numerical Study of the Size and Rate Effects on the Mechanical Response of Single Crystal Diamond and UNCD Films

Luming Shen、Zhen Chen2006-04-01International Journal of Damage Mechanics

To better understand the mechanical response of ultrananocrystalline diamond (UNCD) and its grain boundary mechanism, a numerical study is performed of the specimen size and rate effects on the mechanical properties of single crystal diamond and UNCD films under uniaxial and shear loading paths, respectively. To compa…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchAdvanced materials and composites

Thermal conductivity studies on wool fabrics with conductive coatings

Jinfeng Wang、Akif Kaynak、Lijing Wang 等 4 位作者2006-04-01Journal of the Textile Institute

Methods of improving the thermal conductivity of wool fabrics have been investigated. Thermal conductivity measurement techniques, influence of synthesis parameters on the thermal conductivity of polypyrrole (PPy)-coated wool fabrics, and the relationship between electrical conductivity and thermal conductivity of PPy…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsSilk-based biomaterials and applications