Materials Literature
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PURPOSE: To evaluate the biliary enhancement dynamics of the two gadolinium chelates Gd-BOPTA (MultiHance) and Gd-EOB-DTPA (Primovist) in normal healthy subjects. MATERIAL AND METHODS: Ten healthy volunteers were evaluated with both agents by magnetic resonance (MR) imaging at 1.5T using a breath-hold gradient-echo T1…
Gadolinium is widely used as a magnetic resonance imaging contrast agent and is considered to have a good overall safety profile. Recently, both renal and extra-renal toxicities have been reported following exposure to gadolinium in patients with underlying kidney disease. Gadolinium-related contrast-induced nephropat…
This review states recent developments in the preparation of ceramic fibers using a chemical procedure denoted as Pyrolysis of Preceramic Polymers. Synthesis strategies which are used to prepare Polymer‐Derived Ceramics (PDCs) fibers from molecular and polymeric precursors are presented by refering to the crystalline…
In this study we report the physical properties and spontaneous Raman scattering spectra of nine oxide tellurite and fluorotellurite glasses from three glass systems—sodium–zinc–tellurite (TZN), tungsten–tellurite, and fluorotellurite. Raman gain and surface damage threshold at 1064 nm are also shown for a selection o…
La2Mo2O9 (LAMOX) is a fast oxygen ion conductor which shows high oxygen ion conductivities comparable to those of yttria-sabilized zirconia (YSZ). LAMOX is subject to a structural phase transition from the nonconductive monoclinic form to the highly conductive cubic form at about 580 degrees C. The origin of the condu…
Co x Fe 3 − x O 4 -based (x=0.05–1.6) nanoparticles prepared by combustion reaction were investigated using x-ray diffraction, Raman spectroscopy, and Mössbauer spectroscopy. The Mössbauer data revealed Co2+ in both tetrahedral (site A) and octahedral (site B) sites of the cubic ferrite structure. For x⩽0.4 the experi…
This paper introduces the concept of effective structural size in titanium alloys and its importance with respect to material production routes and component lifing/design. Traditionally, process route optimization has relied on optical microscopy, which may be misleading when predicting mechanical properties. Similar…
Intramolecular electron transfer is observed for two new substituted tetrathiafulvalene (TTF)-quinone dyads 1 and 2 in the presence of metal ions. On the basis of the electrochemical studies of reference compound 5 and the comparative studies with dyad 3, it was proposed that the synergic coordination of the radical a…
Plasmons are collective oscillations of electrons that have been exploited in many applications by manipulating and guiding light at resonant frequencies. The transition from understanding the origin and fundamentals of surface plasmon resonance to its many revolutionary applications has been intriguing. Advances in n…
Indium oxide is chosen as the host material for doping Ti, V, and Cr transition metal ions. Theoretical calculations based on density functional theory within a local spin density approximation show that V–V separation of 5.6Å is more stable with a strong ferromagnetic coupling. Our calculations clearly predict that s…
Magnetic oxide nanoparticles have been studied to elucidate the effects of nanoscale finite size on the magnetic behavior of the particles. Magnetite nanoparticles synthesized by coprecipitation show superparamagnetism at room temperature with reduced saturation magnetization MS. The MS value decreases and approaches…
An experimental program is under way to assess the performance of solid-oxide cells operating in the steam electrolysis mode for hydrogen production in a temperature range from 800 to 900°C. This temperature range is consistent with the planned coolant outlet temperature range of advanced nuclear reactors. Results wer…
ZnWO 4:Eu 3+ nanocrystals were prepared by the hydrothermal method at various temperatures and pH values. Their luminescent properties including excitation and emission processes, luminescent dynamics, and local environments surrounding Eu 3+ ions were systemically studied. The results indicate that the particle size…
A series of heterobimetallic porphyrin pincer palladium complexes have been synthesized through direct cyclometalation of β, β ‘-dipyridylporphyrin. X-ray analyses elucidated their highly distorted structures of porphyrin cores induced by the outer metalation. The catalytic activity has been investigated in the typica…
Drug transporters, including efflux transporters (the ATP binding cassette (ABC) proteins) and uptake transporters (the solute carrier proteins (SLC)), have an important impact on drug disposition, efficacy, drug-drug interactions and toxicity. Identification of the interactions of chemical scaffolds with transporters…
The nanosized water phase has been discovered while studying differential scanning calorimetry (DSC) of the aqueous gel of nano-diamond particles (diameter ca. 5 nm). Two endothermic peaks were observed in the DSC traces of frozen gel upon warming; a broad peak appeared at 265 K before the melting of bulk water, which…
The structural and optical properties of SnS films deposited on glass substrates have been studied at different temperatures under a vacuum of 10−6 Torr. At room temperature, the SnS films showed orthorhombic crystal structure with lattice parameters of a=0.424, b=1.107, and c=0.3974 nm. These films also showed an opt…
A general approach of using the electric field-controllable liquid-crystal orientation to modulate the photoluminescence intensity of quantum dots is presented. Liquid-crystal gel-dispersed quantum dots of CdSe/ZnS were prepared using a cholesteric liquid crystal containing either a self-assembled physical network or…
Surface-enhanced Raman scattering (SERS) is proven to be a powerful technique for rapid identification and discrimination of microorganisms. However, due to the heterogeneous nature of the samples, the acquisition of reproducible spectra hinders the further development of the technique. In this study, we demonstrate t…
We review recent developments in surface studies of single-grain quasicrystals under ultra high-vacuum conditions, focusing on two different topics: surface structure and growth of atomic overlayers on surfaces. Quasicrystalline phases are currently used for investigation of the first topic are icosahedral (i) Al-Pd-M…