Materials Literature
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The authors proposed a new type of gas sensor for high sensitive detection of decomposition products generated by partial discharge (PD) in SF/sub 6/ gas. The sensor employed carbon nanotubes (CNTs) as gas sensing transducer and was fabricated by electrokinetic manipulation of CNTs using dielectrophoresis. Due to comp…
Nous avons resolu la structure cristalline de l'allochalcoselite, Cu+Cu2+5Pb02(Se03)2Cl5, nouvelle espece minerale provenant des fumerolles du volcan Tolbachik, dans la peninsule de Kamchatka, en Russie, avec des donnees en diffraction X prelevees sur monocristal, traitees par methodes directes, et affinees jusqu'a un…
The concept of syncrystallization was reinvestigated by focusing on phthalic acid (PA) grown with methyl red (MR). Crystals are alternately red and yellow in adjacent growth sectors. X-ray structures of MR and its cocrystals, revealing MR in the neutral, zwitterionic, and protonated states, as well as measurements of…
The effect of CO2 and NaCl on the initial stage of atmospheric corrosion of AZ91 magnesium alloy was studied. The observation of surface morphology by optical microscopy (OM), scanning electron microscopy (SEM) and the analysis of corrosion products by X-ray diffraction (XRD) were integrated to investigate corrosion e…
Abstract The crystal structure of the aluminosilicate, ZSM-10 (T 108 O 216 , where T = Si, Al), has been determined from electron diffraction and powder X-ray diffraction data. The material crystallizes in space group P 6/ mmm , where a = 31.390(2), c = 7.5147(8) Å. The framework [001] projection was determined indepe…
Although the failure of X-52 linepipe steel due to stress corrosion cracking (SCC) remains a concern in the oil and gas industry, the mechanisms responsible for crack initiation and propagation are not well understood. In this work, SCC from a section of in-service X-52 linepipe steel was investigated. Features of int…
Abstract Interface modifications optimized for fire retardancy require detailed research. Confocal Raman microscopy was used to analyze the degradation locally in the area of the nanotube and clay additives. The double‐walled carbon nanotube (DWCNT), containing Co catalyst residue, accelerates the deacetylation proces…
We found new bands in the absorption spectra of Pt(II) and Pd(II) complexes of octaethylporphyrin and tetraphenylporphyrin that differ in the nature, number, and position of their side substituents. The bands are observed at 295 K in the range 570–690 nm and are attributed to spin-forbidden transitions from the ground…
The geometric representation at a fixed frequency of the wave vector (or dispersion) surface omega(k) for lossless, homogeneous, dielectric-magnetic uniaxial materials is explored for the case when the elements of the relative permittivity and permeability tensors of the material can have any sign. Electromagnetic pla…
Spurious forces are shown to arise when dislocations interact with atom/continuum interfaces in some classes of multiscale models due to the use of linear elasticity in continuum descriptions of the material deformations and/or the singular dislocation fields. For Al, such forces can reach 500MPa for dislocations with…
The present investigation assessed the corrosion protection performance of different Zn sacrificial coating system configurations during constant immersion in artificial seawater. Visual observations and electrochemical measurements (including electrochemical impedance spectroscopy, EIS) were made periodically through…
The actual stator bars of 18 kV/300 MW generator were used for accelerated multi-stress aging tests to investigate the degradation of epoxy mica insulation. The stator insulation of large generator was a composition system of epoxy resin, mica and glass fiber. Ultra-wide band PD detecting technique was introduced to m…
Abstract The distribution and ageing of polyethylene glycol (PEG) in the Vasa warship has been examined and compared with other archaeological shipwrecks which have also been impregnated with PEG. The distribution of the PEG has been characterised using a variety of mass spectrometric and FT‐IR techniques. Our results…
By using a method of two-photon absorption, it has been observed that monodisperse In2O3 nanocrystals (NCs) with sizes equal to approximately 14-24 nm show significant increase of two-photon absorption at low temperatures. When T = 40 K, the two-photon absorption coefficients for low-sized samples drastically increase…
The phenomenon whereby sudden changes in helicoidal pitch occur in thin chiral nematic devices with strong surface anchoring has been studied experimentally. This has been done with the aim of examining the underlying process in the context of existing theory. Thin devices (∼2.5 µm thick) containing two commercially a…
Abstract This work examines the synthesis of polyurethane (PU)—polydimethylsiloxane (PDMS) hybrid in order to provide low flammability to PU. Chemical characterization of PU/PDMS hybrid by solid state NMR of carbon and FT‐IR shows that some PDMS segments are incorporated in the macromolecular chains of PU. Heat stabil…
[reaction: see text] A new triradical molecule, 2,6,10-tris(dianisylaminium)-3,7,11-tris(hexyloxy)triphenylene 1(3+), was synthesized by oxidative trimerization, palladium-catalyzed amination, and subsequent oxidation. It was chemically stable with a half-life > 1 month and displayed the magnetic parameter of S = 3/2…
The purpose of this book is to review the current, state-of-the-art application of isotopic methods to the field of heterogeneous catalysis. Isotopic studies are arguably the ultimate technique in in situ methods for heterogeneous catalysis. In this review volume, chapters have been contributed by experts in the field…
The effect of aging on the dielectric strength of epoxy-inorganic particle composites used for insulators in the high voltage industry is reported. A differential scanning calorimetry analysis of an insulator aged twenty years in actual service conditions indicated both a chemical degradation and a structural recovery…
Abstract The selective hydrogenation of cyclic and acyclic dienes to monoolefins occurs under very mild conditions, in the presence of silica‐supported PAMAM‐Pd complexes. The activity and selectivity of this reaction is sensitive to the dendrimer structure. These dendritic complexes display excellent recycle properti…