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Multiphoton Fluorescence Quenching of Conjugated Polymers for TNT Detection

Aditya Narayanan、Oleg Varnavski、Timothy M. Swager 等 4 位作者2008-01-01The Journal of Physical Chemistry C

High Resolution Image Download MS PowerPoint Slide The use of conjugated organic compounds in fluorescence sensing applications has been demonstrated to provide an impressive method to detect energetic nitro-aromatic compounds. The amplified fluorescence quenching in conjugated polymers was used for trace detection of…

Organic Electronics and PhotovoltaicsLuminescence and Fluorescent MaterialsNonlinear Optical Materials Studies

High-conductivity poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) film for use in ITO-free polymer solar cells

Yu‐Sheng Hsiao、Wha‐Tzong Whang、Chih‐Ping Chen 等 4 位作者2008-01-01Journal of Materials Chemistry

In this study, we devised a simple method to enhance the conductivity of poly(3,4-ethylenedioxythiophene)-poly(styrene-sulfonate) (PEDOT:PSS) films through spin-coating with various surface-modified compounds, and then applied this technique to the preparation of ITO-free polymer solar cells (PSCs). The electrical con…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsSemiconductor materials and interfaces

Novel iron titanate catalyst for the selective catalytic reduction of NO with NH3 in the medium temperature range

Fudong Liu、Hong He、Changbin Zhang2008-01-01Chemical Communications

An iron titanate catalyst with a crystallite phase, prepared by a co-precipitation method, showed excellent activity, stability, selectivity and SO(2)/H(2)O durability in the selective catalytic reduction of NO with NH(3) in the medium temperature range.

Advanced Photocatalysis TechniquesCatalytic Processes in Materials ScienceIndustrial Gas Emission Control

Feature article - Polymeric HVDC cable design and space charge accumulation. Part 2: insulation interfaces

S. Delpino、Davide Fabiani、Gian Carlo Montanari 等 8 位作者2008-01-01IEEE Electrical Insulation Magazine

The electric field distribution of cable insulation systems under HVDC can be affected significantly at interfaces due to space charge build-up. In this article, the second part of a three-article series, face and space charge accumulation are analyzed first in terms of macroscopic physics, then through approximate ma…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaPower Transformer Diagnostics and Insulation

Oxygen diffusion in nanocrystalline yttria-stabilized zirconia: the effect of grain boundaries

Roger A. De Souza、Martha J. Pietrowski、Umberto Anselmi‐Tamburini 等 6 位作者2008-01-01Physical Chemistry Chemical Physics

The transport of oxygen in dense samples of yttria-stabilized zirconia (YSZ), of average grain size d ≈ 50 nm, has been studied by means of 18O/16O exchange annealing and secondary ion mass spectrometry (SIMS). Oxygen diffusion coefficients (D*) and oxygen surface exchange coefficients (k*) were measured for temperatu…

Catalytic Processes in Materials ScienceAdvancements in Solid Oxide Fuel CellsNuclear materials and radiation effects

Type-II CdS nanoparticle–ZnO nanowire heterostructure arrays fabricated by a solution process: enhanced photocatalytic activity

Youngjo Tak、Hyeyoung Kim、Dong-Wook Lee 等 4 位作者2008-01-01Chemical Communications

We report a two-step, solution-based synthetic method to fabricate CdS nanoparticles-sensitized ZnO nanowire heterostructure arrays which showed enhanced photocatalytic activities in comparison with bare ZnO nanowire arrays.

Advanced Photocatalysis TechniquesZnO doping and propertiesQuantum Dots Synthesis And Properties

Tissue engineering with nano-fibrous scaffolds

Laura A. Smith Callahan、Xiaohua Liu、X. Peter2008-01-01Soft Matter

Tissue Engineering is a rapidly evolving field in terms of cell source and scaffold fabrication. As the template for three dimensional tissue growth, the scaffold should emulate the native extracellular matrix, which is nano-fibrous. Currently, there are three basic techniques capable of generating nano-fibrous scaffo…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

A facile route to hollow nanospheres of mesoporous silica with tunable size

Zhange Feng、Yongsheng Li、Dechao Niu 等 10 位作者2008-01-01Chemical Communications

Hollow mesoporous silica nanospheres (HMSNs) with tunable sizes of both sphere diameter (around 100 nm) and shell thickness have been successfully fabricated.

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisLayered Double Hydroxides Synthesis and Applications

Gadolinium-Contrast Toxicity in Patients with Kidney Disease: Nephrotoxicity and Nephrogenic Systemic Fibrosis

Mark A. Perazella2008-01-01Current Drug Safety

Gadolinium is widely employed as a contrast agent for magnetic resonance imaging (MRI) and has generally been considered to be safe. As with iodinated radiocontrast, concern for contrast-induced nephropathy existed with gadolinium-contrast as it possessed many similar qualities (hyperosmolar, renal excretion via glome…

Luminescence Properties of Advanced MaterialsLanthanide and Transition Metal ComplexesCerebrospinal fluid and hydrocephalus

Not ready to use – overcoming pitfalls when dispersing nanoparticles in physiological media

Christine Schulze、Christine Schulze、Alexandra Kröll 等 12 位作者2008-01-01Nanotoxicology

Industrial nanoparticles are not developed to be compatible with in vitro cell culture assays which are carried out in isotonic solutions at physiological pH and often in the presence of proteins. The tendency of nanoparticles to deagglomerate or agglomerate is strongly sensitive to these parameters. The state of aggl…

Nanoparticle-Based Drug DeliveryNanoparticles: synthesis and applicationsMicroplastics and Plastic Pollution

Engineering space for light via transformation optics

Alexander V. Kildishev、Vladimir M. Shalaev2008-01-01OpenAlex

Conceptual studies and numerical simulations are performed for imaging devices that transform a near-field pattern into magnified far-zone images and are based on high-order spatial transformation in cylindrical domains. A lens translating a near-field pattern from an almost circular input boundary onto a magnified fa…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchAdvanced Antenna and Metasurface Technologies

Flame-retardant-wrapped carbon nanotubes for simultaneously improving the flame retardancy and mechanical properties of polypropylene

Pingan Song、Lihua Xu、Zhenghong Guo 等 5 位作者2008-01-01Journal of Materials Chemistry

Covalently functionalized carbon nanotubes (CNTs) wrapped in intumescent flame retardant were successfully fabricated and characterized. By adjusting the ratio of CNTs and flame retardant, the diameter of the functionalized CNTs was effectively controlled to 20–90 nm. Compared with pristine CNTs, the functionalized CN…

Carbon Nanotubes in CompositesFlame retardant materials and propertiesFiber-reinforced polymer composites

A two-step spin crossover mononuclear iron(ii) complex with a [HS–LS–LS] intermediate phase

Sylvestre Bonnet、Maxime A. Siegler、José Sánchez Costa 等 8 位作者2008-01-01Chemical Communications

The two-step spin crossover of a new mononuclear iron(ii) complex is studied by magnetic, crystallographic and calorimetric methods revealing two successive first-order phase transitions and an ordered intermediate phase built by the repetition of the unprecedented [HS-LS-LS] motif.

Metal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

WASTEWATER CHARACTERISTICS IN TEXTILE FINISHING MILLS

Irina-Isabella Savin、Romen Butnaru2008-01-01Environmental Engineering and Management Journal

The aim of this paper was to accurately analyze the sources of water pollution and loading concentrations in textile finishing mills.A process data collection was performed and integrated with a characterization of the process effluents in terms of treatability and reusability.In order to evaluate properly the wastewa…

Additive Manufacturing and 3D Printing TechnologiesTextile materials and evaluations

Selective turn-on fluorescence detection of cyanide in water using hydrophobic CdSe quantum dots

Ángeles Touceda-Varela、Emily Stevenson、José A. Galve-Gasión 等 5 位作者2008-01-01Chemical Communications

The ability of 2,2'-bipyridine-bound copper(ii) ions to quench the photoluminescence of hydrophobic CdSe quantum dots is used to create a novel, selective turn-on fluorescence cyanide sensor.

Molecular Sensors and Ion DetectionCarbon and Quantum Dots ApplicationsAdvanced Nanomaterials in Catalysis

Effects of carbon blacks with various structures on vulcanization and reinforcement of filled ethylene-propylene-diene rubber

Ziqi Li、J. Zhang、S. J. Chen2008-01-01eXPRESS Polymer Letters

The effects of carbon blacks on vulcanization and mechanical properties of filled ethylene-propylene-diene rubber (EPDM) are investigated, by comparing with five types of rubber-grade carbon blacks.Curing kinetics is studied by rheometer and the results indicate that the curing characteristics are influenced by combin…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer composites and self-healing

A BODIPY boronium cation for the sensing of fluoride ions

Todd W. Hudnall、François P. Gabbaı̈2008-01-01Chemical Communications

In the presence of iodide ions, the cationic p-dimethylaminopyridine adduct of 1,3,5,7,8-pentamethylpyrromethene-boron fluoride [-DMAP](+) reacts with fluoride ions to afford the corresponding brightly fluorescent difluoride -F.

Molecular Sensors and Ion DetectionPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Ordered mesoporous Co3O4 as highly active catalyst for low temperature CO-oxidation

Harun Tüysüz、Massimiliano Comotti、Ferdi Schüth2008-01-01Chemical Communications

Cubic ordered mesoporous Co3O4, prepared via the nanocasting pathway using KIT-6 as hard template, was found to be an excellent catalyst for low temperature CO oxidation, with the activity clearly depending on surface area and pore systems of the catalysts.

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisCatalysis and Oxidation Reactions

Zinc ferrite nanoparticles as MRI contrast agents

Carlos Bárcena、Amandeep K. Sra、Girija S. Chaubey 等 6 位作者2008-01-01Chemical Communications

Mixed spinel hydrophobic ZnxFe1-xO x Fe2O3 (up to x = 0.34) nanoparticles encapsulated in polymeric micelles exhibited increased T2 relaxivity and sensitivity of detection over clinically used Feridex.

Nanoparticle-Based Drug DeliveryMagnetic Properties and Synthesis of FerritesCharacterization and Applications of Magnetic Nanoparticles