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Crystal forms of highly “dynamic” 18-crown[6] complexes with M[HSO4] and M[H2PO4] (M+ = NH4+, Rb+, Cs+): thermal behaviour and solid-state preparation

Dario Braga、Enrico Modena、M. Polito 等 5 位作者2008-01-01New Journal of Chemistry

The hydrated complexes 18-crown[6]·[NH4][H2PO4]0.5[HSO4]0.5·H2O (1), 18-crown[6]·Rb[H2PO4]0.5[HSO4]0.5·3H2O (2), 18-crown[6]·Cs[H2PO4]0.5[HSO4]0.5·3H2O (3) and 18-crown[6]·Cs[HSO4]·2H2O (4) have been quantitatively prepared by the mechanical mixing of crystalline 18-crown[6], and M[H2PO4] and/or M[HSO4] inorganic salt…

Crystal structures of chemical compoundsCrystallography and molecular interactionsSolid-state spectroscopy and crystallography

Effect of Temperature on Frequency and Damping Properties of Polymer Matrix Composites

Mehmet Çolakoğlu2008-01-01Advanced Composite Materials

The effect of temperature on natural frequency and damping is investigated in two different composite materials, Kevlar 29 fiber woven and polyethylene cloth, used especially to design ballistic armor. A damping monitoring method is used experimentally to measure the frequency response curve and it is also modeled num…

Mechanical Behavior of CompositesNatural Fiber Reinforced CompositesEpoxy Resin Curing Processes

Fluorescence detection of protoporphyrin IX in living cells: a comparative study on single- and two-photon excitation

Sijia Lü、Ji-Yao Chen、Yu Zhang 等 6 位作者2008-01-01Journal of Biomedical Optics

Photodynamic therapy (PDT) involves a combination of a lesion-localizing photosensitizer with light and has been established as a new modality for some medical indications. Much evidence has shown the correlation between subcellular localization of a photosensitizer with its photodynamic efficiency. However, the fluor…

Nanoplatforms for cancer theranosticsPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies

The relevance of chirality in space group analysis: A database study of common hydrogen-bonding motifs and their symmetry preferences

Archan Dey、Elna Pidcock2008-01-01CrystEngComm

Datasets of common hydrogen bonding motifs have been generated using the functionality available in the Materials Module of Mercury 2.0. These datasets were divided on the grounds of space group type (centrosymmetric, Sohncke and non-centrosymmetric/non-Sohncke) and chirality. Comparisons of the populations of the sub…

Crystallography and molecular interactionsCrystallization and Solubility StudiesMolecular spectroscopy and chirality

A spectroscopic study of self-assembled monolayer of porphyrin-functionalized oligo(phenyleneethynylene)s on gold: the influence of the anchor moiety

Somsakul Watcharinyanon、Daniel Nilsson、Ellen Moons 等 8 位作者2008-01-01Physical Chemistry Chemical Physics

Porphyrin-functionalized oligo(phenyleneethynylene)s (OPE) are promising molecules for molecular electronics applications. Three such molecules (1-3) with the common structure P-OPE-AG (P and AG are a porphyrin and anchor group, respectively) and different anchor groups, viz. an acetyl protected thiol, -S-COCH3 (1), a…

Quantum Dots Synthesis And PropertiesMolecular Junctions and NanostructuresSemiconductor materials and interfaces

A snapshot of a coordination polymer self-assembly process: the crystallization of a metastable 3D network followed by the spontaneous transformation in water to a 2D pseudopolymorphic phase

Thierry Bataille、Ferdinando Costantino、Andrea Ienco 等 6 位作者2008-01-01Chemical Communications

A metastable copper(II) 3D hybrid with 4,4'-bipyridine (4,4'-bipy) and P,P'-diphenylethylenediphosphinate (pc2p(2-)) undergoes a spontaneous, quantitative, transformation to a stable 2D polymorphic species either spontaneously in water, or after thermal dehydration followed by hydration.

Metal-Organic Frameworks: Synthesis and ApplicationsSupramolecular Chemistry and ComplexesCovalent Organic Framework Applications

Effects of the modification of gas diffusion electrodes by organic redox catalysts for hydrogen peroxide electrosynthesis

Juliane C. Forti、Cristiane E. Venâncio、Marcos R.V. Lanza 等 4 位作者2008-01-01Journal of the Brazilian Chemical Society

This paper reports a comparative study of the electrochemical performance of in situ hydrogen peroxide electrogeneration on gas diffusion electrodes modified by organic redox catalysts 2-ethylanthraquinone, 2-terc-butylanthraquinone and azobenzene in medium of 0.1 mol L-1 H2SO4 plus 0.1 mol L-1 K2SO4, pH = 1. Hydrogen…

Conducting polymers and applicationsElectrochemical Analysis and ApplicationsAdvanced battery technologies research

A Scroll Compressor With a High-Performance Induction Motor Drive for the Air Management of a PEMFC System for Automotive Applications

Benjamin Blunier、Marcello Pucci、Abdellatif Miraoui2008-01-01IEEE Transactions on Industry Applications

This paper proposes a technological solution with a scroll compressor driven by a high-performance induction machine drive for the air management of proton exchange membrane fuel cells (PEMFC) for automotive applications. The torque-speed characteristics of a real scroll compressor have been measured and then emulated…

Advancements in Solid Oxide Fuel CellsFuel Cells and Related MaterialsElectric and Hybrid Vehicle Technologies

Detonation Performance of Aluminium - Ammonium Nitrate Explosives

Józef Paszula、W. A. Trzciński、K. Sprzątczak2008-01-01OpenAlex

Abstract: The research on an effect of aluminium contents on detonation characteristics of ammonium nitrate explosives was carried out. Measurements of detonation velocity were performed. Parameters of blast waves produced by charges of the investigated explosives detonating in an open space were measured by the use o…

Energetic Materials and CombustionCombustion and Detonation ProcessesThermal and Kinetic Analysis

Review of Ultracapacitor Technology and its Applications

Varsha A. Shah、Jivanadhar A. Joshi、Ranjan Maheshwari 等 4 位作者2008-01-01OpenAlex

An efficient electrical energy storage media are essential and are considered as a short term and an enabling infrastructure power technology. Energy storage technologies do not represent energy sources but they provide value added benefits to improve system stability, power quality and reliability of supply. As batte…

Supercapacitor Materials and FabricationAdvanced Battery Technologies ResearchElectric and Hybrid Vehicle Technologies

Phase and Microstructure of Brick-Clay Soil and Fired Clay-Bricks From Some Areas in Peshawar Pakistan

Safeer Ahmad、Yaseen Iqbal、Fazal Ghani2008-01-01OpenAlex

Objectives: Bricks being the most frequently used product in the local construction industry. However, there has been very little or no relevant information about the manufacturing standards and quality of locally-made bricks as compared to that in developed countries. It is the aim of this study to provide some infor…

Concrete and Cement Materials ResearchRecycling and utilization of industrial and municipal waste in materials productionClay minerals and soil interactions

Low Emissions Combustion System Development for the GE Energy High Hydrogen Turbine Program

Ben Lacy、Willy Steve Ziminsky、John Lipinski 等 6 位作者2008-01-01OpenAlex

Progress on the joint GE Energy/US Department of Energy (DOE) High Hydrogen Turbine Program is presented. A summary of GE’s current integrated gasification combined cycle (IGCC) experience is provided. The Phase I approach is discussed with selected results included. The program follows the well-established GE approac…

Advanced Combustion Engine TechnologiesCatalytic Processes in Materials ScienceCombustion and flame dynamics

Recent Advances in the HELIOS-2 Lattice Physics Code

C.A. Wemple、M. Gheorghiu2008-01-01OpenAlex

Major advances have been made in the HELIOS code, resulting in the impending release of a new version, HELIOS-2. The new code includes a method of characteristics (MOC) transport solver to supplement the existing collision probabilities (CP) solver. A 177-group, ENDF/B-VII nuclear data library has been developed for i…

Nuclear reactor physics and engineeringNuclear Materials and PropertiesNuclear and radioactivity studies

Bacillus Amyloliquefaciens: A new Keratinolytic Feather-degrading Bacteria

Mariana Cortezi、Eduardo Maffud Cilli、Jonas Contiero2008-01-01Current Trends in Biotechnology and Pharmacy

Feather-degrading microorganisms were isolated from a poultry processing industry. The microorganism that presented high degradation of feathers was LM16, reaching 97.7% after 72 h of fermentation. Using morphological and biochemical tests [API 20 E (Bio-Merieux)], the strain was identified as Bacillus amyloliquefacie…

Protein Hydrolysis and Bioactive PeptidesEnzyme Production and CharacterizationSilk-based biomaterials and applications

Application of FIB system to ultra-high-pressure Earth science

Masaaki Miyahara、Takeshi Sakai、Eiji Ohtani 等 10 位作者2008-01-01Journal of Mineralogical and Petrological Sciences

The conventional focused ion beam (FIB) sample preparation technique “lift-out method” was modified for the reliable analysis of a laser-heated diamond anvil cell (LHDAC) sample. Box-shaped grooves were prepared in the LHDAC specimen in order to recover a block using a gallium ion beam in the vicinity of the area to b…

Geological and Geochemical AnalysisHigh-pressure geophysics and materialsDiamond and Carbon-based Materials Research

A ground-state-directed optimization scheme for the Kohn–Sham energy

Stinne Høst、Branislav Jansı́k、Jeppe Olsen 等 6 位作者2008-01-01Physical Chemistry Chemical Physics

Kohn-Sham density-functional calculations are used in many branches of science to obtain information about the electronic structure of molecular systems and materials. Unfortunately, the traditional method for optimizing the Kohn-Sham energy suffers from fundamental problems that may lead to divergence or, even worse,…

Advanced Chemical Physics StudiesCatalysis and Oxidation ReactionsMachine Learning in Materials Science

Preparation and properties as positive electrodes of PANI–LiNi0.8Co0.2O2 nanocomposites

Eduardo Pérez Cappe、Yodalgis Mosqueda Laffita、Ricardo Martínez 等 10 位作者2008-01-01Journal of Materials Chemistry

PANI–LiNi0.8Co0.2O2 nanocomposite material with improved properties as positive electrode was prepared by a new synthesis method. In a first step, LiNi0.8Co0.2O2 mixed oxide in the form of a fine powder was dispersed in aniline and this suspension was sprayed on the surface of an aqueous solution of HCl and ammonium p…

Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesConducting polymers and applications

Preferential crystallization (AS3PC mode) of modafinic acid: an example of productivity enhancement by addition of a non-chiral base

Nicolas Wermester、Olivier Lambert、Gérard Coquerel2008-01-01CrystEngComm

Modafinic acid belongs to the minor fraction of chiral components whose racemic mixture crystallizes as a stable conglomerate. Preferential crystallization attempts were carried out on a two-litre scale via the AS3PC mode (auto seeded polythermic programmed preferential crystallization): the direct entrainments of mod…

Analytical Chemistry and ChromatographyCrystallization and Solubility StudiesMolecular spectroscopy and chirality

Multiple-multipole simulation of optical nearfields in discrete metal nanosphere assemblies

Wei-Yin Chien、Thomas Szkopek2008-01-01Optics Express

We applied a multiple-multipole method to calculate the field enhancement of discrete metal nanosphere assemblies due to plasma resonance, thus performing the first full electromagnetic simulation of a variety of nanoparticle assemblies for efficient field focusing, including the self-similar geometric series of spher…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchNear-Field Optical Microscopy

The effects of autologous platelet gel on inflammatory cytokine response in human peripheral blood mononuclear cells

Antonella Naldini、Emilia Morena、Michele Fimiani 等 6 位作者2008-01-01Platelets

The potential therapeutic value and versatility of platelet-derived products has recently stimulated the research and interest in the field of regenerative medicine. Platelet gels (PG), generated by thrombin-activated platelets, represent a new biotechnology for stimulation and acceleration of tissue healing and regen…

Electrospun Nanofibers in Biomedical ApplicationsPlatelet Disorders and TreatmentsPeriodontal Regeneration and Treatments