Materials Literature
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The reaction of cyclohexylphosphonic acid (C(6)H(11)PO(3)H(2)), anhydrous CuCl(2) and 2,2'-bipyridine (bpy) in the presence of triethylamine followed by a metathesis reaction with KNO(3) afforded [Cu(4)(mu-Cl)(2)(mu(3)-C(6)H(11)PO(3))(2)(bpy)(4)](NO(3))(2) (1). In an analogous reaction involving Cu(OAc)(2).H(2)O, the…
The tension/compression asymmetries of yield and creep strengths of three kinds of single-crystal superalloys-PWA1480, CMSX-4, and TMS-75 - and a DS superalloy, Mar-M247LC, were investigated at intermediate and high temperatures. In PWA1480, tensile yield strength was higher than the compressive strength from 20°C to…
Electrochemical and microstructural measurements of membrane electrode assemblies (MEAs) cycled under cold-start conditions are reported. An experimental protocol using a single-cell fixture was developed for MEA durability tests under cold-start cycling. Electrochemical diagnostics using high-frequency resistance and…
Aqueous solution of micelles prepared from novel PS-b-PNIPAM with fluorescent group CEA at the junction between two blocks displays logical responsive switches on temperature and fluorescence; at lower temperature, stretching of PNIPAM chains causes high mobility of CEA leading to formation of more excimer species; at…
We report a study of the effects of confinement in multi-walled carbon nanotubes and mesoporous silica glasses (SBA-15) on the solid structure and melting of both H(2)O and D(2)O ice, using differential scanning calorimetry, dielectric relaxation spectroscopy, and neutron diffraction. Multi-walled nanotubes of 2.4, 3.…
BACKGROUND: Ectocarpus siliculosus virus-1 (EsV-1) is a lysogenic dsDNA virus belonging to the super family of nucleocytoplasmic large DNA viruses (NCLDV) that infect Ectocarpus siliculosus, a marine filamentous brown alga. Previous studies indicated that the viral genome is integrated into the host DNA. In order to f…
We revisit the reactivity of trapped pure gold (Au(n)+, n < 26) and silver gold alloy cluster cations (Ag(m)Au(n)+, m + n < 7) with carbon monoxide as studied in a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. The experimental results are discussed in terms of ab initio computations which provi…
Peptide rod-coil molecules, composed of a stiff polyproline rod and a hydrophilic cell-penetrating peptide Tat coil, self-assemble into nanocapsules and mediate efficient intracellular delivery of entrapped hydrophilic molecules.
This paper introduces a smart textile for posture classification. A distributed sensing and processing architecture is implemented into a loose fitting long sleeve shirt. Standardized interfaces to remote periphery support the variable placement of different sensor modalities at any location of the
Supermolecules with olefins organized by hydrogen-bond donor and acceptor templates and that react in the solid state rapidly form co-crystals via solvent-free and liquid-assisted grinding.
A series of homoleptic complexes with non-innocent ligands derived from N,N'-bis(pentafluorophenyl)-o-phenylenediamine (H(2)(F)pda) are reported. [Ni(II)((F)sbqdi)(2)] (1), [Pd(II)((F)sbqdi)(2)] (2), [Co(II)((F)sbqdi)(2)] (3), and [Cu(II)((F)sbqdi)(2)] (4) were synthesized, where ((F)sbqdi)(1-) represents a radical an…
The aim of this study was to evaluate hydroxyapatite (HA) coatings produced by dynamic voltage during electrophoretic deposition (EPD). Dynamic voltages from 0 to 200 V were incrementally applied in three interims. The as-deposited coating was sintered at 800 degrees C and its properties evaluated. Structure and phase…
The first intermediate of the photochemical transformation of ortho-nitrobenzaldehyde to ortho-nitrosobenzoic acid in acetonitrile solvent has been characterized by femtosecond spectroscopy and time-dependent density functional theory (TDDFT) calculations. Femtosecond stimulated Raman spectroscopy (FSRS) indicates tha…
Textiles have long undergone surface modification to improve their softness, dyeability, absorbance, and wettability. Recent advances in textile chemistry have also approached textile surface modification to impart antimicrobial activity, decreased skin irritation, and even enhancing fragrance. Chitosan is an effectiv…
The structural elucidations of microbial lipases have been of prime interest since the 1980s. Knowledge of structural features plays an important role in designing and engineering lipases for specific purposes. Significant structural data have been presented for few microbial lipases, while, there is still a structure…
The effects of selected superdisintegrants on the dissolution behavior of several cationic drugs with varying water solubility were evaluated.All formulations were made with fixed disintegrant concentration and equal drug load using a model formulation.Tablets were made by direct compression and were compressed to equ…
Abstract We present the origins and synthesis of helical polyacetylene (H‐PA) by focusing on its peculiar spiral morphology. Interfacial polymerization of acetylene was carried out in an asymmetric reaction field consisting of chiral nematic liquid crystal (N*‐LC) and Ziegler–Natta catalyst. As the N*‐LC is composed o…
The physical stability, dissolution rate, and solubility enhancement of indomethacin amorphized by co-grinding with 6 pharmaceutical silicates were investigated. Mixtures of indomethacin and silicates were co-ground to amorphous states at room temperature and 75% relative humidity (RH) in a rolling jar mill. The fract…
A novel nanostructure of a PtAu catalyst, alloyed PtAu nanodendrites, has been synthesized via a reproducible single-step hydrothermal co-reduction of Pt and Au inorganic precursors and shows exceptionally high catalytic activity towards the electrooxidation of formic acid.
The self-assembly of rhenium-based rectangular boxes with a large inner cavity can be achieved via a simple one-step synthetic route; these molecules selectively recognize planar aromatic molecules, benzene in particular.