Materials Literature
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We studied the electric and magnetic resonances of U-shaped SRRs. We showed that higher order excitation modes exist in both of the electric and magnetic resonances. The nodes in the current distribution were found for all the resonance modes. It turns out that the magnetic resonances are the modes with odd-number of…
DOX–magnetic PLGA nanoparticles conjugated with well-tailored antibodies were synthesized for the detection and therapy of breast cancer. Magnetic nanocrystals embedded in polymeric nanoparticles did not inhibit the nanoparticle formulation or drug release kinetics. The multimodal nanoparticles demonstrated remarkable…
Photophysical properties are reported for a series of cyclometalated platinum and iridium complexes that can serve as photosensitizers for singlet oxygen. The complexes have the formula (C;N)(2)Ir(O;O) or (C;N)Pt(O;O) where C;N is a monoanionic cyclometalating ligand such as 2-(phenyl)pyridyl and 2-(phenyl)quinolyl, a…
Hydrides of period 2 and 3 elements are promising candidates for hydrogen storage, but typically have heats of reaction that are too high to be of use for fuel cell vehicles. Recent experimental work has focused on destabilizing metal hydrides through mixing metal hydrides with other compounds. A very large number of…
We examine contributions to the dc-current of mesoscopic samples which are non-linear in applied voltage. In the presence of a magnetic field, the current can be decomposed into components which are odd (antisymmetric) and even (symmetric) under flux reversal. For a two-terminal chaotic cavity, these components turn o…
Beautiful theories of magnetic hysteresis based on random microscopic disorder have been developed over the past ten years. Our goal was to directly compare these theories with precise experiments. To do so, we first developed and then applied coherent x-ray speckle metrology to a series of thin multilayer perpendicul…
The ability to control the crystallization behaviour (including its absence) of particles, be they biomolecules such as globular proteins, inorganic colloids, nanoparticles, or metal atoms in an alloy, is of both fundamental and technological importance. Much can be learnt from the exquisite control that biological sy…
Magnetic nanoparticles of γ-MnxFe2–xO3 (0 ≤ x ≤ 1.3) have been synthesized successfully using a single step process wherein the respective inorganic salts were thermally decomposed in ethylene glycol at 200 °C. Single phase formation is evident in the as prepared dried samples without any further treatment. XRD line b…
The microstructure and electronic structure of environmentally relevant carbons such as Euro IV heavy duty diesel engine soot, soot from a black smoking diesel engine, spark discharge soot as model aerosol, commercial furnace soot and lamp black are investigated by transmission electron microscopy, electron energy-los…
Progress in metallodendritic architectures is discussed as it relates to catalysis, luminescence, sensors, and molecular switches. It is intended that the reader will gain an appreciation for the different roles that metals can play in dendritic connectivity as well as their vast potential for application-oriented nan…
ECM is composed of different collagenous and non-collagenous proteins. Collagen nanofibers play a dominant role in maintaining the biological and structural integrity of various tissues and organs, including bone, skin, tendon, blood vessels, and cartilage. Artificial collagen nanofibers are increasingly significant i…
The performance of several negative (fuel) and positive (air) electrode compositions for use in reversible solid oxide fuel cells capable of operating both as a fuel cell and as an electrolyzer was investigated in half-cell and full-cell tests. Negative electrode compositions studied were a nickel/zirconia cermet and…
Nanometer-scale particles of Mn O 2 have been synthesized by microemulsion route for electrochemical supercapacitor studies. The Mn O 2 has been found to be in α-cyrstallographic form with tetragonal unit cell. Particles in the spherical/hexagonal shape with about 50 nm size have been observed in scanning electron mic…
The synthesis, photophysical and photochemical properties of the 4-({3,4,5-tris-[2-(2-ethoxyethoxy)ethyloxy]benzyl}oxy) and 4-({3,4,5-tris-[2-(2-ethoxyethoxy)ethyloxy]benzyl}thio) zinc(ii) phthalocyanines are reported for the first time. The new compounds have been characterized by elemental analysis, IR, (1)H and (13…
Polymeric micelles are nano-delivery systems formed through self-assembly of amphiphilic block copolymers in an aqueous environment. The nanoscopic dimension, stealth properties induced by the hydrophilic polymeric brush on the micellar surface, capacity for stabilized encapsulation of hydrophobic drugs offered by the…
Biodegradable polymers, such as poly(glycolic acid) (PGA), poly(L-lactic acid) (PLLA) and poly(lactic-co-glycolic acid) (PLGA), were dissolved individually in the proper solvents and then subjected to electrospinning process to make nanofibrous scaffolds. Their surfaces were then chemically modified using oxygen plasm…
We describe predictions made using the Rosetta structure prediction methodology for both template-based modeling and free modeling categories in the Seventh Critical Assessment of Techniques for Protein Structure Prediction. For the first time, aggressive sampling and all-atom refinement could be carried out for the m…
We present preliminary results of our joint investigations to monitor and mitigate environmental pollution, a leading contributor to chronic and deadly health disorders and diseases affecting millions of people each year. Using nanotechnology-based gas sensors; pollution is monitored at several ground stations. The se…
Structural properties of polycrystalline single-phased BiMnO3 samples prepared at 6 GPa and 1383 K have been studied by selected area electron diffraction (SAED), convergent beam electron diffraction (CBED), and the Rietveld method using neutron diffraction data measured at 300 and 550 K. The SAED and CBED data showed…
Trivalent-cation-doped has fairly high protonic conductivity at intermediate temperatures. This paper deals with the effects of the kind of dopant, M in (, Tm, Yb, Lu, In, or Sc), on the electrical (ionic) conductivity at and chemical stability. It was found that the two properties are both governed by the ionic radii…