Materials Literature
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The structures of (MePh 3 P)[M(dca) 3 ] (M = Fe, Co, Ni and dca = dicyanamide, N(CN) 2 - ) are isomorphous and contain anionic [M(dca) 3 ] - networks in which octahedral metal ions are bridged by bidentate μ 1,5 dca anions, to generate three-dimensional (3D) five-connected networks. The structures of (EtPh 3 P)[M(dca)…
Abstract The possibility for global climate change has sparked the interest in CO2 removal from natural gas and other sources. Pipelines are considered for transportation of CO2 from source to storage site. This can to a large extent be done in carbon steel pipelines as pure, dry CO2 is essentially non-corrosive. Howe…
Abstract Majority of microbiologically influenced corrosion failure cases is reported at or near welds. Experiments on bacterial attachment on AISI type 304 stainless steel welds and base metals were carried out to investigate whether factors other than surface roughness influence the attachment. Coupon exposure studi…
Abstract In selecting materials for corrosive sour oil field environments, both age-hardened and cold-worked solid solution nickel-base alloys offer many advantages such as high-strength, toughness and excellent corrosion resistance. Alloy 028 (UNS N08028), alloy 825 (UNS N08825), alloy G-3 (UNS N06985), alloy 050 (UN…
Abstract The combination of high strength and corrosion resistance makes super duplex stainless steel attractive for a number of applications both in sour process fluids and seawater. Several superduplex alloys exist and each has its own proprietary chemical composition and UNS designation. This paper considers one su…
Abstract The proposed engineering barriers for the high-level nuclear waste repository in Yucca Mountain include a double walled container and a detached drip shield. The candidate material for the external wall of the container is Alloy 22 (N06022). One of the anticipated degradation modes for the containers could be…
Abstract H2S corrosion is controlled by processes occurring across the corrosion product (FeS) layer and by chemical effects which affect the properties of this layer. Laboratory data are reviewed which clearly demonstrate the parabolic nature of the corrosion kinetics. Along with the corrosion rates the film growth r…
Abstract Corrosion of a pipeline that had been laid in HVAC utility corridors was investigated. Severe AC corrosion occurred resulting in four holes in the pipeline after only five months life and before operation had begun. This represents a corrosion rate of over 400 mpy. An “intelligent” pig survey identified 18 ad…
Abstract The carbon dioxide corrosion electrochemistry of mild steel has been studied in the presence of high CO2 partial pressures and acetic acid (HAc). Potentiodynamic sweeps, linear polarization resistance (LPR) and weight loss (WL) experiments have been conducted to investigate the effects of flow velocity, CO2 p…
Hitherto, adsorption has been traditionally used to study only the porous structure in disordered materials, while the structure of the solid phase skeleton has been probed by crystallographic methods such as X-ray diffraction. Here we show that for carbons density functional theory, suitably adapted to consider heter…
Abstract Weight loss (WL) and linear polarization resistance (LPR) measurements have been used to verify the effect of acetic acid (HAc) on the anodic and cathodic reactions in CO2 corrosion of carbon steel. The experiments were performed using a standard rotating cylinder three-electrode system, in a 3% NaCl solution…
The parallel and perpendicular orientation of lamellae in free-surface thin films of symmetric diblock copolymers is studied in the strong segregation approximation. In contrast to films, which are confined between two hard walls, the period of the parallel lamellar structure in the free-surface films is determined fr…
Abstract Experiments were conducted to determine the effect of an incremental change in the solution pH, from 4 to 6.6, on CO2 corrosion rates of AISI 1018 steel in the presence of H2S in both single phase flow (Vsl = 1 m/s) and multiphase flow (Vsg=3 m/s, Vsl= 1 m/s) in a large scale multiphase flow loop. Linear pola…
Abstract This paper deals with the phenomena of corrosion by acetic acid and carbon dioxide at the top of a horizontal pipeline under dewing conditions. The effect of different parameters known to influence the Top of the Line Corrosion (TLC), such as the condensation rate and the bulk temperature is studied. The free…
Novel dipyridyl compounds containing a mono- and bisbenzothiadiazole unit were synthesized using the Stille coupling reaction. Their pyridinium salts, viologen analogues, were also prepared by the N-alkylation. The X-ray crystallographic analysis of the compounds containing a benzothiadiazole ring revealed nonplanar m…
A novel diisocyanate, 1,2-bis(isocyanate)ethoxyethane (TEGDI), whose backbone is ether bonds was used for the preparation of polyurethane elastomers (PUEs). 1,6-Hexamethylene diisocyanate (HDI) was also used as a control. The PUEs were prepared with either TEGDI or HDI, poly(oxytetramethylene) glycol (PTMG), and curin…
Novel adsorbents that have an excellent adsorption capacity for Au(III) were prepared by immobilization of bayberry tannins and larch tannins onto collagen fiber matrixes. When the initial concentration of Au(III) was 478 mg/L and the amount of adsorbent was 20.0 mg, the adsorption capacities at equilibrium of immobil…
The electrochemical properties of two commercial (Condias, Sumitomo) boron-doped diamond thin-film electrodes were compared with those of two types of boron-doped diamond thin film deposited in our laboratory (microcrystalline, nanocrystalline). Scanning electron microscopy and Raman spectroscopy were used to characte…
We explored the magnetic behavior of a common two-phase nanomagnetic system by Monte Carlo computer simulation of a modified Heisenberg model on a 3D complex lattice with single- and cluster-spins. The effect of exchange coupling between two component magnetic phases was studied on the enhancement in Curie temperature…
The spectrum of acoustic vibrational modes of an inhomogeneous elastic continuum are analyzed with application to a spherical nanoparticle embedded in an infinite glass block. The relationship of these modes to the discrete vibrational spectrum of a free sphere is studied. The vibrational modes of a sphere with a fixe…