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Synthesis, Structure and Dynamics of a C2‐symmetrical Bis(oxazolinylmethylene)pyrrolinato‐Zinc Complex

Carmine Capacchione、Hubert Wadepohl、Lutz H. Gade2007-10-01Zeitschrift für anorganische und allgemeine Chemie

Abstract Reaction of 2,5‐bis(cyanomethyl)pyrrole with L ‐valinol in presence of zinc trifluoromethansulfonate and subsequent work‐up with aqueous NaCl gave the corresponding zinc complex 2 , in which the double bonds of the pyrrole ring isomerize to give rise to a conjugated chromophore. Its molecular structure displa…

Porphyrin and Phthalocyanine ChemistrySynthesis and Characterization of PyrrolesSynthesis and Reactions of Organic Compounds

Thermal stability of tin charge states in the structure of the (As2Se3)0.4(SnSe)0.3(GeSe)0.3 glass

Г. А. Бордовский、R. A. Castro、А. В. Марченко 等 4 位作者2007-10-01Glass Physics and Chemistry

Two valence states of tin atoms (namely, the doubly charged Sn 2+ and quadruply charged Sn 4+ states) in the structure of the (As 2 Se 3 ) 0.4 (SnSe) 0.3 (GeSe) 0.3 glasses are identified by 119 Sn Mössbauer spectroscopy. It is demonstrated that the concentration ratio of the doubly charged Sn 2+ and quadruply charged…

Glass properties and applicationsChalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenides

Annealing effects on conductivity and optical properties of the PAni layer in ITO/PAni/PPV+DBS/Al polymer light-emitting diodes

Luiz Carlos Poças、Silmar Antonio Travain、José Leonil Duarte 等 6 位作者2007-10-01Journal of Physics Condensed Matter

In this work we present the electrical and optical characterization of polymer light-emitting diodes (PLEDs) using indium-tin oxide (ITO), polyaniline (PAni), poly(p-phenylene vinylene) (PPV) +dodecylbenzenesulfonate (DBS) and aluminum (Al). To minimize the conversion temperature and reduce the structural defects of P…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Mixed-ligand palladium(II) complexes with amino acids, cytosine, and adenine

A.K. Molodkin、N. Ya. Esina、Maxim V. Tachaev 等 4 位作者2007-10-01Russian Journal of Inorganic Chemistry

pH titration shows that 1 : 1 : 1 mixed-ligand complexes are formed in the systems palladium(II)-Cyt-Glu-H 2 O (loggB = 19.73) and palladium(II)-Cyt-Lys-H 2 O (logβ = 16.20). Complexes Pd(C 5 H 5 N 5 )(C 5 H 8 NO 4 )Cl, Pd(C 5 H 5 N 5 )(C 6 H 13 N 2 O 2 )Cl, Pd(C 4 H 5 N 3 O)(C 6 H 13 N 2 O 2 )Cl, and Pd(C 4 H 5 N 3 O…

Metal complexes synthesis and propertiesLanthanide and Transition Metal ComplexesChemical Synthesis and Characterization

Ultra-High Oxidation Resistance of Suspended Single-Wall Carbon Nanotube Bundles Grown by an "All-Laser" Process

Ji-Hyun Yi、Brahim Aïssa、My Alı El Khakani2007-10-01Journal of Nanoscience and Nanotechnology

Single-wall carbon nanotubes (SWCNTs) were laterally grown on SiO2/Si substrates by means of an "all-laser" growth process. Our "all-laser" process stands out by its exclusive use of the same pulsed UV laser, first, to deposit the CoNi nanocatalyst and, second, to grow SWCNTs through the laser ablation of a pure graph…

Carbon Nanotubes in CompositesDiamond and Carbon-based Materials ResearchAdvanced Materials Characterization Techniques

Evaluation of anti-cancer effect of Daucus carota on the human promyelocytic leukemia HL-60 cells

Mona Diab‐Assaf、Samir El-Sharif、Mohamad Mroueh2007-10-01Clinical Cancer Research

B56 Introduction: Daucus carota, Apiaceae, commonly used in Lebanese folklore medicine for the treatment of leukemia. The anti-cancer aqueous extract of DC was examined by evaluating its effect on the induction of differentiation and inhibition of proliferation of the human promyelocytic leukemia HL-60 cells. Material…

Cancer Treatment and PharmacologyPlant chemical constituents analysisPhytochemistry and Bioactive Compounds

Effects of Low Doses of Radiation: Joint Statement from the Following Participants at the 15 th Pacific Basin Nuclear Conference, Sessions Held in Sydney, Australia, Wednesday 18 October 2006

Donald Higson、Douglas R. Boreham、Antone L. Brooks 等 7 位作者2007-10-01Dose-Response

The results of research presented at the 15th Pacific Basin Nuclear Conference (15PBNC) directly challenge the assumption, made for the purposes of radiation protection, that risks observed at acute doses of 500–1000 mGy can be extrapolated reliably down to zero dose and to low dose rates (the LNT model). The research…

Radioactivity and Radon MeasurementsGraphite, nuclear technology, radiation studiesNuclear and radioactivity studies

The necessary length of carbon nanotubes required to optimize solar cells

Majid Vaezzadeh、Mohammad Reza Saeedi、Tirdad Barghi 等 4 位作者2007-10-01Chemistry Central Journal

BACKGROUND: In recent years scientists have been trying both to increase the efficiency of solar cells, whilst at the same time reducing dimensions and costs. Increases in efficiency have been brought about by implanting carbon nanotubes onto the surface of solar cells in order to reduce the reflection of sunrays, as…

Carbon Nanotubes in CompositesChemical and Physical Properties of MaterialsNanotechnology research and applications

Nonreciprocal microwave transmission in metastructures with transversely magnetized ferrite plate and a grating of resonant elements

V. S. Butylkin、Г. А. Крафтмахер2007-10-01Technical Physics Letters

Nonreciprocal transmission of a linearly polarized electromagnetic wave at a ferromagnetic resonance (FMR) frequency has been observed in a metastructure comprising a transversely magnetized ferrite plate and a grating of resonant elements. The nonreciprocity of wave transmission is observed for the metastructure arra…

Metamaterials and Metasurfaces ApplicationsMicrowave Engineering and WaveguidesAdvanced Antenna and Metasurface Technologies

Estudo comparativo da eficiência da difenilcarbazida e do óleo de coco saponificado microemulsionados na inibição da corrosão de aço carbono

Cátia Guaraciara F. T. Rossi、H. Scatena、Maria Aparecida M. Maciel 等 4 位作者2007-10-01Química Nova

<abstract language="eng">The effectiveness of microemulsions (ME) of saponified coconut oil (OCS-ME) and diphenylcarbazide (DC-ME) on a carbon steel corrosion inhibition process was evaluated using an electrochemical method of polarization resistance. The ME was prepared with OCS, butanol, kerosene and saline solution…

Corrosion Behavior and InhibitionSurfactants and Colloidal SystemsMaterial Properties and Processing

Influence of cutting conditions of cast-metal cutting tools on their wear and durability: Analysis of cutting conditions of tools

А. С. Чаус、Ф. И. Рудницкий2007-10-01Journal of Friction and Wear

The conditions of operation of metal-cutting tools in various applications and of various standard dimensions are analyzed. Long-standing statistical observations at a number of industrial facilities have revealed the dominating mechanisms of wear and the main causes of failure of the tools have been established in re…

Metal Alloys Wear and PropertiesEngineering and Environmental StudiesPolymer Science and Applications

Urea Hydrolysis of Tea Soils as Influenced by Incubation Period, Soil pH, and Nitrification Inhibitor

S. Venkatesan、V. Sudhahar、V. K. Senthurpandian 等 4 位作者2007-10-01Communications in Soil Science and Plant Analysis

Laboratory incubation studies were conducted with south Indian tea soils to investigate the influence of soil pH, incubation period, and nitrification inhibitor on urea hydrolysis. The soils used in this experiment were sampled from six different regions of south India. The physicochemical properties, urea hydrolysis…

Soil Carbon and Nitrogen DynamicsSoil and Unsaturated FlowClay minerals and soil interactions

Novel Integration Approach for In situ Monitoring of Temperature in Micro-direct Methanol Fuel Cell

Chi‐Yuan Lee、Ren-De Huang、Chih‐Wei Chuang2007-10-01Japanese Journal of Applied Physics

In this work, a porous silicon layer is fabricated as the gas diffusion layer (GDL) of a micro-direct methanol fuel cell (µDMFC) using micro-electro-mechanical-systems (MEMS) technology. Platinum is deposited on surface of the porous silicon layer to improve the electrical conductivity of the µDMFC. Physical vapor dep…

Fuel Cells and Related MaterialsSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Single crystalline BaTiO3 thin films synthesized using ion implantation induced layer transfer

Young-Bae Park、Kenneth Diest、Harry A. Atwater2007-10-01Journal of Applied Physics

Layer transfer of BaTiO3 thin films onto silicon-based substrates has been investigated. Hydrogen and helium ions were co-implanted to facilitate ion-implantation-induced layer transfer of films from BaTiO3 single crystals. From thermodynamic equilibrium calculations, we suggest that the dominant species during cavity…

Ferroelectric and Piezoelectric MaterialsSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Luminescence investigations of cubic boron nitride doped with beryllium

Е. М. Шишонок、Takashi Taniguchi、Takashi Sekiguchi2007-10-01Physics of the Solid State

The cathodoluminescence and photoluminescence spectra of cubic boron nitride doped with beryllium under high-pressure and high-temperature conditions are investigated. It is revealed that, upon doping of cubic boron nitride with beryllium, the cathodoluminescence spectra exhibit a broad stable band. An increase in the…

Luminescence Properties of Advanced MaterialsDiamond and Carbon-based Materials ResearchBoron and Carbon Nanomaterials Research

Collagen type I fibril packing in vivo and in vitro

Т. И. Николаева、E. I. Tiktopulo、E. N. Il’yasova 等 4 位作者2007-10-01BIOPHYSICS

Reviewed are works concerning the mechanisms of collagen (type I) fibril packing and the influence of macromolecular structure and physicochemical parameters of the medium on the process.

Bone Tissue Engineering MaterialsCollagen: Extraction and CharacterizationBone and Dental Protein Studies

Birefringence and anisotropic optical absorption in porous silicon

A. I. Efimova、E. Yu. Krutkova、L. A. Golovan’ 等 6 位作者2007-10-01Journal of Experimental and Theoretical Physics

The refractive indices and the coefficients of optical absorption by free charge carriers and local vibrations in porous silicon (por-Si) films, comprising nanometer-sized silicon residues (nanocrystals) separated by nanometer-sized pores (nanopores) formed in the course of electrochemical etching of the initial singl…

Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Novel liquid crystal trimers exhibiting a monolayer smectic C phase containing strong macroscopic fluctuations

Atsushi Yoshizawa、Naoki Uehara、Mariko Kurauchi 等 4 位作者2007-10-01Liquid Crystals

We prepared a homologous series of novel liquid crystal trimers, 1,4‐bis(4‐{ω‐[4‐(5‐dodecylpyrimidine‐2‐yl)phenyloxy]alkyloxyphenyl}carbonyloxy)benzene, I‐(m, n), and investigated their physical properties using optical microscopy, differential scanning calorimetry and X‐ray diffraction. All the compounds exhibited en…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

Preparation of (Pb,La)(Zr,Ti)O3 Epitaxial Thin Films by Modified Sol–Gel Method and Their Crystallinity Evaluation

Masahiro Echizen、Takashi Nishida、Takashi Nozaka 等 6 位作者2007-10-01Japanese Journal of Applied Physics

Preparation of (Pb,La)(Zr,Ti)O3 Epitaxial Thin Films by Modified Sol–Gel Method and Their Crystallinity Evaluation, Echizen, Masahiro, Nishida, Takashi, Nozaka, Takashi, Takeda, Hiroaki, Uchiyama, Kiyoshi, Shiosaki, Tadashi

Ferroelectric and Piezoelectric MaterialsGlass properties and applicationsPhase-change materials and chalcogenides

Radiation-Induced Recrystallization of U-Mo Fuel Particles and Radiation-Induced Amorphization of Interaction Products in U-Mo/Al Dispersion Fuel

Ho Jin Ryu、Yeon Soo Kim、G.L. Hofman 等 6 位作者2007-10-01Materials science forum

Two kinds of radiation-induced structural changes were observed in U-Mo/Al dispersion fuel: radiation-induced recrystallization of U-Mo fuel particles and radiation-induced amorphization of interaction products. During irradiation, U-Mo fuel showed refined microstructures of submicron-size grains due to dynamic recrys…

Nuclear reactor physics and engineeringRadioactive element chemistry and processingNuclear Materials and Properties