Materials Literature
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Large Ca0.28Ba0.72Nb2O6 (CBN-28) single crystals exhibit saturated ferroelectric hysteresis loops under an electric field of 115kV∕cm along the [001] direction. Their spontaneous polarization, remanent polarization and coercive field are 35.3μC∕cm2, 32.2μC∕cm2, and 38.1kV∕cm, respectively. The dielectric constant and…
We describe an approach that utilizes nonlinear peptides to direct the assembly of previously reported Self-Assembling Fibers (SAFs). The SAF system comprises two complementary linear peptides, SAF-p1 and SAF-p2a, which combine to form exclusively linear, nonbranched fibers. The Matrix-Programming (MaP) peptides descr…
The charge distribution on the surface of a biased conductive, finite-length, cylindrical nanotube, free standing above an infinite grounded plane, is investigated. The diameter range of the cylinder tube under study is 20–60 nm, which is much larger than the screening length, meaning the quantum and statistical effec…
Iridium is unique among the face-centered cubic metals in that it undergoes brittle cleavage after a period of plastic deformation under tensile stress. Atomistic simulation using a quantum-mechanically derived bond-order potential shows that in iridium, two core structures for the screw dislocation are possible: a gl…
A heteroarm star block copolymer made from seven polystyrene and seven poly(2-vinylpyridine) arms was grafted onto a solid substrate to fabricate a responsive polymer surface consisting of a densely packed monolayer of copolymer molecules. The grafted layer demonstrates a two-level hierarchical response upon external…
We present an extensive study on electrical spectroscopy of graphene ribbons and edges of highly oriented pyrolytic graphite (HOPG) using atomic force microscope (AFM). We have addressed in the present study two main issues (1) How does the electrical property of the graphite (graphene) sheet change when the graphite…
A new terpyridyl-containing Pt triad [Pt(pytpy)(p-CC-C6H4-NH-CO-C6H2(OMe)3)](PF6)2 (4), where pytpy = 4'-(4-pyridin-1-ylmethylphenyl)-[2,2';6',2' ']terpyridine and p-CC-C6H4-NH-CO-C6H2(OMe)3 = N-(4-ethynylphenyl)-3,4,5-trimethoxybenzamide, has been synthesized and structurally characterized. The related donor-chromoph…
Silica films with Ln 3+ -doped LaF 3 nanoparticles were prepared by sol gel method and their luminescent properties were studied as a function of the temperature. Significant improvements in the luminescent properties, in terms of the lifetime for the 4 I 13/2 level of Er 3+ (∼10.9 ms), 4 F 3/2 level of Nd 3+ (∼171 μs…
Magnetic attraction: The exotic 1D molecular tapes [Cu4(N3)8(CH3CN)3(bzp)2]n (1) and [Cu5(N3)10(bzp)2]n (2) were obtained from a solution of methanol or methanol/acetonitrile (see scheme; bzp=2-benzoylpyridyl). The end-on azide bridges in 1 transmit ferromagnetic interaction, whereas in 2, the central copper center of…
We computationally study the electrostatic potential profile and current carrying capacity of carbon nanotubes as a function of length and diameter. Our study is based on solving the nonequilibrium Green's function and Poisson equations self-consistently, including the effect of electron-phonon scattering. A transitio…
Magnetic nanoparticles are of considerable interest because of their potential use in high-density memory devices, spintronics, and applications in diagnostic medicine. The conditions for synthesis of these materials are often complicated by their high reaction temperatures, costly reagents, and post-processing requir…
Abstract The preparation of very hydrophobic poly(vinylidene fluoride) (PVDF) membranes was explored by using two methods. The first one was the modified phase inversion method using a water/N, N ‐dimethylacetamide (DMAc) mixture instead of pure water as a soft precipitation bath. The second method was a precipitation…
Discovered in 1991, carbon nanotubes (CNTs) have reached the forefront of many industrial research projects. Carbon nanotubes are tubular carbon molecules with remarkable mechanical, chemical, thermal and electrical properties, which make them useful in various applications. This paper reviews three methods of synthes…
The results of a systematic study of the interaction of small coinage metal clusters (Mn, n = 1-3) and extended deposition (one and two MLs; ML = monolayer) with the regular and locally defected (Fs center and divacancy) neutral MgO(100) surface are presented. The calculations have been performed at the DFT level empl…
Dissipative particle dynamics simulations of several bead-spring representations of polymer chains in dilute solution are used to demonstrate the correct static scaling laws for the radius of gyration. Shear flow results for the wormlike chain simulating single DNA molecules compare well with average extensions from e…
A novel approach to pressureless sintering based on the combination of rapid‐rate sintering, rate‐controlled sintering, and two‐step sintering under a controlled atmosphere is proposed. This combined sintering method facilitates control of grain and pore morphology. The application of this sintering approach for pure…
We obtain the distance of closest approach of the surfaces of two arbitrary ellipsoids valid at any orientation and separation, measured along their inter-center vector. This directional distance is derived from the Elliptic Contact Function. The geometric meaning behind this approach is clarified. An elliptic pair po…
We study theoretically the spin relaxation rate in quasi-one-dimensional coupled double semiconductor quantum dots. We consider InSb and GaAs-based systems in the presence of the Rashba spin-orbit interaction, which causes mixing of opposite-spin states, and allows phonon-mediated transitions between energy eigenstate…
Photochromism in single nitrogen-vacancy optical centers in diamond is demonstrated. Time-resolved optical spectroscopy shows that intense irradiation at 514 nm switches the nitrogen-vacancy defects to the negative form. This defect state relaxes back to the neutral form under dark conditions. Temporal anticorrelation…
We show that the photoluminescence intensity of single-walled carbon nanotubes is much stronger in tubes with large chiral angles--armchair tubes--because exciton resonances make the luminescence of zigzag tubes intrinsically weak. This exciton-exciton resonance depends on the electronic structure of the tubes and is…