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Influence of composition on properties of nylon 6/EVOH blends

Loredana Incarnato、Domenico Acierno、Pietro Russo 等 5 位作者1999-09-01Journal of Polymer Science Part B Polymer Physics

In this work, the relationships between composition and properties of Ny6/EVOH system were examined by means of several techniques and the results were interpreted in terms of level of compatibility. Blends of different ratio of Ny6 and EVOH have been processed in a laboratory-based film blowing extrusion apparatus. R…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Foaming and Composites

Fabrication of Compliant Hybrid Grafts Supported with Elastomeric Meshes

Teisei Kobashi、Takehisa Matsuda1999-09-01Cell Transplantation

We devised tubular hybrid medial tissues with mechanical properties similar to those of native arteries, which were composed of bovine smooth muscle cells (SMCs) and type I collagen with minimal reinforcement with knitted fabric meshes made of synthetic elastomers. Three hybrid medial tissue models that incorporated s…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Molecular structure evolution in peroxide‐initiated crosslinking of an ethylene vinyl acetate copolymer and a metallocene polyolefin elastomer

Horng‐Jer Tai1999-09-01Polymer Engineering and Science

Abstract A combination of molecular theories and chemical reaction kinetics was employed to study the molecular structure evolution in the ethylene vinyl acetate and dicumyl peroxide, EVA/DCP, and metallocene polyolefin elastomer, m‐POE/DCP crosslinking systems. Premixed EVA/DCP and m‐POE/DCP compounds were cured at d…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersSilicone and Siloxane Chemistry

Imprint Model Based on Thermionic Electron Emission Under Local Fields in Ferroelectric Thin Films

Dai Nagasawa、Hiroshi Nozawa1999-09-01Japanese Journal of Applied Physics

We investigated the origin of the imprint mechanism of ferroelectric thin films such as PbZr x Ti 1- x O 3 (PZT) or SrBi 2 Ta 2 O 9 (SBT) by considering thermionic field emission under local fields. The electric fields inside the ferroelectric films are represented. Since the poled ferroelectric capacitors have strong…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesElectronic and Structural Properties of Oxides

Growth and Temperature Dependence of Optical Properties of Er Doped and Undoped n-Type InSe

Bekir Gürbulak、Muhammet Yıldırım、Aytunç Ateş 等 5 位作者1999-09-01Japanese Journal of Applied Physics

n-InSe and Er doped n-InSe (n-InSe:Er) single crystals were grown by the modified Bridgman-Stockbarger method. The prepared InSe and InSe:Er single crystal ingots were 12 mm in diameter and about 80 mm in length. The ingots had no cracks or voids on the surface. The absorption measurements were carried out for n-InSe,…

Chalcogenide Semiconductor Thin FilmsSemiconductor materials and interfacesSolid-state spectroscopy and crystallography

An experimental study of foamed polyethylene in rotational molding

Shih‐Jung Liu、Chia‐Hsun Tsai1999-09-01Polymer Engineering and Science

Abstract Rotational molding of foamed polyethylene has increasingly become an important process in industry because of its thicker walls, low sound transfer, high stiffness and good thermal insulation. However, the foaming process of polyethylene during rotational molding has not been well studied. The focus of this a…

Polymer Nanocomposites and PropertiesRheology and Fluid Dynamics StudiesPolymer Foaming and Composites

A Polyoxometalate Transfer Reagent: Synthesis, Structure, and Reactivity of Zirconocene Polyoxometalate [(PNbW11O40)2ZrCp2]6-

E. Radkov、Victor G. Young、Robert Beer1999-09-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTA Polyoxometalate Transfer Reagent: Synthesis, Structure, and Reactivity of Zirconocene Polyoxometalate [(PNbW11O40)2ZrCp2]6-Emil V. Radkov, Victor G. Young, and Robert H. BeerView Author Information Departments of Chemistry Fordham University, Bronx, New York 10458 Co…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Reactions

Micro-Raman and Resistance Measurements of Epitaxial La0.7Sr0.3MnO3 Films

V. Dediu、J. L�pez、F.C. Matacotta 等 7 位作者1999-09-01physica status solidi (b)

The Channel-Spark method was used for deposition of highly oriented ferromagnetic La0.7Sr0.3MnO3 films on NdGaO3 substrates. It was found that additional oxygen decreases the film quality suppressing the Curie temperature and metal–insulator transition below room temperature. To achieve the best quality of the films t…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsMagnetic Properties of Alloys

Microstructural investigation of the brittle-to-ductile transition in Al-Pd-Mn quasicrystals

Markus Wollgarten、H. Saka、Akihisa Inoue1999-09-01Philosophical magazine. A/Philosophical magazine. A. Physics of condensed matter. Structure, defects and mechanical properties

Icosahedral Al-Pd-Mn single quasicrystals were deformed between room temperature and 400°C by Vickers hardness testing. The surface morphology was investigated by profiling and scanning electron microscopy. Specimens were prepared for cross-sectional observation in transmission electron microscopes using a focused ion…

Microstructure and mechanical propertiesQuasicrystal Structures and PropertiesX-ray Diffraction in Crystallography

Influence of Fiber Surface Treatment on the Creep Behavior of Jute Fiber-Reinforced Polypropylene

Jochen Gassan、Andrzej K. Błędzki1999-09-01Journal of Thermoplastic Composite Materials

Improvements in the characteristic properties of jute-polypropylene composites were obtained with the application of MAH grafted PP copolymers as a coupling agent to the fiber. SEM investigations demonstrated that fiber pull-out is reduced after the modification with the coupling agent. This improved fiber-matrix adhe…

Mechanical Behavior of CompositesPolymer crystallization and propertiesNatural Fiber Reinforced Composites

Functionality of Rice and Sorghum Flours in Baked Tortilla and Corn Chips

Ximena Quintero-Fuentes、Cassandra M. McDonough、L. W. Rooney 等 4 位作者1999-09-01Cereal Chemistry

ABSTRACT The effects of raw and gelatinized sorghum and rice flours on the structure and texture of baked corn and tortilla chips were evaluated. Dry masa flour was hydrated into masa, sheeted, and cut. Corn chips were baked in an air‐impingement oven, and tortilla chips were baked first in a three‐tier oven and then…

Natural Fiber Reinforced CompositesTextile materials and evaluationsPolymer Foaming and Composites

Accessibility and order of water sites in and around proteins: A crystallographic time-averaging study

Celia A. Schiffer、Wilfred F. van Gunsteren1999-09-01Proteins Structure Function and Bioinformatics

Water plays an essential role in most biological processes. Water molecules solvating biomolecules are generally in fast exchange with the environment. Nevertheless, well-defined electron density is seen for water associated with proteins whose crystal structure is determined to high resolution. The relative accessibi…

Protein Structure and DynamicsEnzyme Structure and FunctionErythrocyte Function and Pathophysiology

Tight-binding model of selenium disordered phases

D. Molina、E. Lomba、Gerhard Kahl1999-09-01Physical review. B, Condensed matter

Following the parametrization scheme first introduced by Goodwin, Skinner, and Pettifor, we propose here a model of the empirical tight-binding Hamiltonian for selenium, based on the fitting of cohesive energy curves obtained from density-functional calculations for solid phases, rings, and chains structures. We have…

Material Dynamics and PropertiesPhase-change materials and chalcogenidesnanoparticles nucleation surface interactions

Dielectric and pyroelectric properties of (Pb1-xBax)(Zr0.70Ti0.30) O3 [x=0.25÷0.35] ceramics exhibiting the relaxor ferroelectrics behaviour

J. Hańderek、M. Adamczyk、Z. Ujma1999-09-01Ferroelectrics

Dielectric constant, loss factor and remanent polarization were investigated as a function of temperature for PBZT - type ceramics with Zr/Ti ratio equal 70/30 and Ba contents x = 0.25÷-0.35. Additionally measurements of pyroelectric and thermally stimulated depolarization currents were carried out. The reported exper…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesDielectric materials and actuators

Optical Properties of Germanium Nanocrystals

Maurizia Palummo、Giovanni Onida、R. Del Sole1999-09-01physica status solidi (a)

We study the electronic structure and the optical properties of germanium clusters up to about 103 atoms, by using a semi-empirical tight-binding approach. Germanium nanocrystals are related to quantum dots growing, by a self-organization process, in sapphire matrices. The optical properties of such dots are experimen…

Quantum Dots Synthesis And PropertiesSilicon Nanostructures and PhotoluminescenceSemiconductor materials and interfaces

Solid-state 29 Si MAS NMR studies of illite and illite-smectite from shale

Soren K. Lausen、Holger Lindgreen、Hans J. Jakobsen 等 4 位作者1999-09-01American Mineralogist

A new method to extract quantitative information from poorly resolved 29 Si magic-angle spinning (MAS) nuclear magnetic resonance (NMR) spectra of natural mixed-layer illite-smectite (I-S) clays is presented. The Si-Al distribution in layered aluminosilicates are used to link the intensities of 29 Si resonances from a…

Advanced NMR Techniques and ApplicationsClay minerals and soil interactionsNMR spectroscopy and applications

Synthese, Kristallstrukturen und thermisches Verhalten von Er2(SO4)3 · 8 H2O und Er2(SO4)3 · 4 H2O

Mathias S. Wickleder1999-09-01Zeitschrift für anorganische und allgemeine Chemie

Beim Einengen einer Lösung von Er2(SO4)3 in Wasser erhält man Er2(SO4)3 · 8 H2O in Form von blaßrosa Einkristallen. Nach Auskunft der Einkristallstrukturanalyse kristallisiert die Verbindung monoklin (C2/c, Z = 8, a = 1346,1(3), b = 667,21(1), c = 1816,2(6) pm, β = 101,90(3)°, Rall = 0,0169) mit achtfacher Koordinatio…

Luminescence Properties of Advanced MaterialsCrystal Structures and PropertiesRadioactive element chemistry and processing

Photochemistry without Light: Oxidation of Rubrene in a Microemulsion with a Chemical Source of Singlet Molecular Oxygen (1O2, 1Dg)

Véronique Nardello、Marie-Josée Marti、Christel Pierlot 等 4 位作者1999-09-01Journal of Chemical Education

This simple experiment illustrates the main features of excited oxygen in the singlet state 1 O 2 ( 1 D g ): (i) its high oxidizing power and its selectivity towards unsaturated organic compounds, (ii) its low excitation energy which allows its access by various chemical processes and (iii) its long lifetime compared…

Porphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research StudiesOxidative Organic Chemistry Reactions

Structure of an insulin dimer in an orthorhombic crystal: the structure analysis of a human insulin mutant (B9 Ser→Glu)

Zhiping Yao、Zong-Hao Zeng、Hongmin Li 等 6 位作者1999-09-01Acta Crystallographica Section D Biological Crystallography

The structure of human insulin mutant B9 (Ser-->Glu) was determined by an X-ray crystallographic method at 2.5 A resolution with an R factor of 0.165 under non-crystallographic restraints. The crystals were grown at low pH (<3.8) and belong to the orthorhombic P2(1)2(1)2(1) space group with unit-cell dimensions a = 44…

Protein Structure and DynamicsEnzyme Structure and FunctionMetabolism, Diabetes, and Cancer

A Single-Point Mutation in the Extreme Heat- and Pressure-Resistant Sso7d Protein from Sulfolobus solfataricus Leads to a Major Rearrangement of the Hydrophobic Core,

Roberto Consonni、Laura Santomo、Paola Fusi 等 5 位作者1999-09-01Biochemistry

Sso7d is a basic 7-kDa DNA-binding protein from Sulfolobus solfataricus, also endowed with ribonuclease activity. The protein consists of a double-stranded antiparallel beta-sheet, onto which an orthogonal triple-stranded antiparallel beta-sheet is packed, and of a small helical stretch at the C-terminus. Furthermore,…

Protein Structure and DynamicsDNA Repair MechanismsEnzyme Structure and Function