Materials Literature
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In this paper we report on experimental data for the frequency and temperature dependence of the thermal properties of supercooled glycerol and propylene glycol. By using a photopyroelectric method the specific heat capacity and thermal conductivity were separately determined in a bandwidth of several decades. We have…
In a previous work [Heinz, Castelijns, and Suter, J. Am. Chem. Soc. 115, 9500 (2003)], we developed an accurate force field and simulated the phase transitions in C18-mica (octadecyltrimethylammonium-mica) as well as the absence of such transitions in 2C18-mica (dioctadecyldimethylammonium-mica) between room temperatu…
Heat conduction in a one-dimensional chain of equivalent rigid particles in the field of the external on-site potential is considered. The zero diameters of the particles correspond to the integrable case with the divergent heat conduction coefficient. By means of a simple analytical model it is demonstrated that for…
Surface relief gratings on azobenzene containing polymer films were prepared under irradiation by actinic light. Finite element modeling of the inscription process was carried out using linear viscoelastic analysis. It was assumed that under illumination the polymer film undergoes considerable plastification, which re…
Delamination of advanced composite materials due to various scenarios such as low velocity and ballistic impacts and high strain rate is one of the major problems for aerospace and automotive structural applications. The low velocity impact does not immediately induce any visible damage on the surface of structures wh…
Two Bacillus subtilis genes encoding two proteins (currently annotated ThiD and YjbV) were overexpressed and characterized. YjbV has 4-amino-5-hydroxymethyl-2-methylpyrimidine and 4-amino-5-hydroxymethyl-2-methylpyrimidine pyrophosphate kinase activity and should be reannotated ThiD, and B. subtilis ThiD has pyridoxin…
A nanocomposite of a multiwalled carbon nanotube and polythiophene was prepared by functionalizing the nanotube surface with a polythiophene, poly[3-(2-hydroxyethyl)-2,5-thienylene], containing pendant hydroxyl groups. The composite was characterized by IR, high resolution TEM and conductivity measurements. The poly[3…
Transport properties including collective and tracer diffusivities of nitrogen, modeled as a diatomic molecule, in single walled carbon nanotubes have been studied by equilibrium molecular dynamics at different temperatures and as a function of pressure. It is shown that while the asymptotic decay of the translational…
Orthorhombic KNbO 3 thin films were deposited on SrTiO 3 (100) and LiTaO 3 (001) substrates by low-temperature hydrothermal epitaxy at 180−210 °C using aqueous solutions containing Nb 2 O 5 and KOH. The films were thoroughly characterized by X-ray diffraction, Rutherford backscattering, and scanning electron microscop…
Membranen aus Gold-Nanoröhren in Polycarbonatfilmen wurden zur Untersuchung katalytischer Reaktionen an Gasflüssig-Grenzflächen verwendet, die zeigen, dass die katalytischen Eigenschaften von Gold bei der Oxidation von CO mit O2 durch Wasser verbessert und durch Erhöhung des pH-Werts der Lösung optimiert werden. Die M…
Since their discovery in 1990, the study of sp2 bonded carbon nanotubes has grown into a field of research in it's own right; however the development of the sp3 analog, diamond nanowires, has been slow. A number of theoretical models have been proposed to compare the relative stability of diamond and graphite at the n…
Poly(vinyl alcohol) (PVA) and polyamidoamine (PAMAM) dendrimers are water-soluble, biocompatible and biodegradable polymers, which have been widely applied in biomedical fields. In this paper, novel physically cross-linked hydrogels composed of PVA and amine-terminated PAMAM dendrimer G6-NH(2) were prepared by cyclic…
Abstract Natürlich vorkommende Polymere werden seit langem als Werkstoffe verwendet, wegen ihrer eingeschränkten thermoplastischen Verarbeitbarkeit jedoch nur begrenzt. In jüngerer Zeit hat die mikrobielle Synthese von Polyestern unmittelbar aus Kohlenhydraten starkes Interesse gefunden. Polymilchsäure wird auf der Ba…
Hochkristalline und monodisperse MnO- oder Mn3O4-Nanopartikel entstehen bei der thermischen Zersetzung von [Mn(acac)2] in Oleylamin in Inertatmosphäre in Gegenwart bzw. bei Abwesenheit geringer Mengen Wasser (siehe Bild). Die Teilchengröße beider Manganoxidsysteme, von der auch das magnetische Verhalten abhängt, lässt…
In this article we report the first calculations of second harmonic generation second hyperpolarizability of liquid water using coupled cluster/molecular mechanics (CC/MM) methods or coupled cluster/dielectric continuum (CC/DC) methods. The latter approach treats the solvent as an isotropic homogeneous fluid while the…
We present a novel approach to probe elastic properties of polyelectrolyte multilayer microcapsules. The method is based on measurements of the capsule load-deformation curves with the atomic force microscope. The experiment suggests that at low applied load deformations of the capsule shell are elastic. Using elastic…
β‐Glucuronidase enzymes have been attached to a porous silicon surface through a direct silicon–carbon bond based linking system (see Figure). The attached enzymes display high activity and the photoluminescent (PL) properties and surface stability of the porous silicon are retained. Quenching of the PL is observed up…
Utilizing a novel solvent of cellulose, 6 wt % NaOH/5 wt % thiourea aqueous solution, for the first time, we prepared the thermally induced cellulose gel. We investigated the thermal gelation of cellulose solutions with rheometry and the structure of the gel with 13C NMR, wide-angle X-ray diffraction, environmental sc…
A relaxing time: A dramatic increase of the energy barrier (Ueff) in tetrairon(III) single-molecule magnets can be achieved by simple chemical modification. Site-specific replacement of the six methoxide bridges in [Fe4(OMe)6(dpm)6] (Hdpm=dipivaloylmethane; Ueff/kB=3.5 K) with two tripodal 1,1,1-tris(hydroxymethyl)eth…
This Letter deals with the investigation of the electromagnetic radiation focusing using a plane-parallel plate of a material with negative real parts of the permittivity and permeability. The reasons are demonstrated for the restriction of the limiting attainable resolution of the system. The possibility of obtaining…