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Development of O/W Emulsions with Annato Oil (Bixa orellana) Containing Liquid Crystal

Gilsane G. Morais、Orlando David Henrique dos Santos、Daniela S. Masson 等 5 位作者2005-09-01Journal of Dispersion Science and Technology

O/W emulsions with liquid crystals are complex systems for the delivery of actives into the skin surface since they modulate the release rate in the structure, and they increase the stability and solubility of slightly soluble substances in oil or aqueous phase and support moisturing by decreasing the transepidermal w…

Proteins in Food SystemsPickering emulsions and particle stabilizationSensory Analysis and Statistical Methods

Orientation Dependence of Epitaxial and One-Axis-Oriented (Ba0.5Sr0.5)TiO3 Films Prepared by RF Magnetron Sputtering

Sin-ichi Ito、Kenji Takahashi、Shoji Okamoto 等 6 位作者2005-09-01Japanese Journal of Applied Physics

The dependences of electrical properties on (111) and (100) orientations were investigated for (Ba 0.5 Sr 0.5 )TiO 3 films with in-plane random (one-axis-oriented films) and aligned orientations (epitaxial films) prepared by RF magnetron sputtering. Epitaxial films with (100) and (111) orientations were grown on (100)…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Structure of a new crystal modification of the bacterial NAD-dependent formate dehydrogenase with a resolution of 2.1 Å

E.V. Filippova、K. M. Polyakov、Т.В. Тихонова 等 6 位作者2005-09-01Crystallography Reports

Formate dehydrogenase (FDG) from methylotrophic bacteria Pseudomonas sp. 101 catalyzes the reaction of oxidation of the formate ion to carbon dioxide, which is accompanied by the reduction of nicotinamid adenine dinucleotide (NAD + ). The structures of the apo and holo (enzyme-NAD-azide triple complex) forms of the en…

Protein Structure and DynamicsEnzyme Structure and FunctionMicrobial metabolism and enzyme function

Synthesis and Characterization of Functionalizable and Photopatternable Poly(ε-caprolactone-co-RS-β-malic acid)

Bin He、Mary B. Chan‐Park2005-09-01Macromolecules

To create a functionalizable and photopatternable biodegradable polyester, 2-hydroylethyl methacrylate (HEMA) grafted poly(ε-caprolactone- co -RS-β-malic acid) (PCLMAc) was synthesized. The ring-opening random copolymerization of ε-caprolactone (CL) and RS-β-benzyl malolactonate (MA) using stannous octoate catalyst wa…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsAdditive Manufacturing and 3D Printing Technologies

Phonon–phason coupling in a Mg–Ga–Al–Zn icosahedral quasicrystal

Keiichi Edagawa2005-09-01Philosophical Magazine Letters

Precise X-ray diffraction measurements have revealed that phonon (conventional) strain is introduced at the phase transition from an icosahedral quasicrystal to its orthorhombic crystal approximant in a Mg–Ga–Al–Zn alloy. From the magnitude of the measured phonon strain, the phonon–phason coupling constant has been ev…

Quasicrystal Structures and PropertiesX-ray Diffraction in Crystallography

Origin of kaolin deposits in the ‘Los Menucos’ area, Río Negro Province, Argentina

Silvina Andrea Marfil、Pedro Maiza、Esteve Cardellach 等 4 位作者2005-09-01Clay Minerals

Abstract Kaolinite deposits, hosted by rhyolitic tuffs, are found in the SE of the ‘Los Menucos’ area (Province of Rio Negro, Argentina). The most representative examples are from the Blanquita and Equivocada mines. To discover the origin of these deposits, a mineralogical, geochemical (major and trace element) and st…

Geological and Geochemical AnalysisGeology and Paleoclimatology ResearchClay minerals and soil interactions

Relationship of Processing Conditions to Structure and Properties in PMDA‐ODA Polyimide

V. A. Bershteĭn、Т. Е. Суханова、Timothy D. Krizan 等 10 位作者2005-09-01Journal of Macromolecular Science Part B

A combined wide angle X‐ray diffraction (WAXD)/small‐angle X‐ray scattering (SAXS)/scanning electron microscopy (SEM)/density study of structure and morphology was carried out for a large series of pyromellitic dianhydride‐oxydianiline (PMDA‐ODA) polyimide (PI) samples processed using different powder metallurgy techn…

Polymer Nanocomposites and PropertiesSynthesis and properties of polymersTribology and Wear Analysis

Effects of Guanidine on the Liquid-Phase Catalytic Oxidation of p-Xylene to Terephthalic Acid

Youwei Cheng、Xi Li、Qinbo Wang 等 4 位作者2005-09-01Industrial & Engineering Chemistry Research

In previous papers [Wang, Q.; Li, X.; Wang, L.; Cheng, Y.; Xie, G. Ind. Eng. Chem. Res . 2005, 44 (2), 261−266; 2005, 44 (13), 4518−4522], a lumped kinetic scheme and a fractional kinetic model for the liquid-phase oxidation of p -xylene catalyzed by Co−Mn−Br was proposed and tested and the effect of water on the oxid…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsOxidative Organic Chemistry Reactions

Coating Materials Containing Gold Nanoparticles

Ayako Iwakoshi、Taizo Nanke、Toshikatsu Kobayashi2005-09-01Gold bulletin

Highly concentrated pastes of gold nanoparticles were successfully produced by using a special type of protective polymer and a mild reductant. The solid part of these pastes comprises up to 85wt% of gold nanoparticles, 10≈30 nm in diameter and a residual protective polymer. This component can be diluted at arbitrary…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsNanomaterials for catalytic reactions

Dynamics of the Rise around a Fiber: Experimental Evidence of the Existence of Several Time Scales

Maria-Jesus Vega、David Seveno、G. Lemaur 等 5 位作者2005-09-01Langmuir

We study experimentally the dynamics of the spontaneous rise of a meniscus made of polydimethylsiloxane of various viscosities on the outside of a micrometric fiber made of monofilament in polyethyleneterephthalate. Optical methods are used to measure simultaneously the height of the liquid interface and the associate…

Surface Modification and SuperhydrophobicityFluid Dynamics and Heat TransferPlant Surface Properties and Treatments

Comment on “Physical Limits on Electronic Nonlinear Molecular Susceptibilities”

Benoı̂t Champagne、Bernard Kirtman2005-09-01Physical Review Letters

A Comment on the Letter by Mark G. Kuzyk, The authors of the Letter offer a Reply.Received 1 March 2005DOI:https://doi.org/10.1103/PhysRevLett.95.109401©2005 American Physical Society

Molecular Junctions and NanostructuresNonlinear Optical Materials ResearchSpectroscopy and Quantum Chemical Studies

Comparison of Oxidation Behaviors of Different Grades of Nuclear Graphite

Xiaowei Luo、Jean-Charles Robin、Suyuan Yu2005-09-01Nuclear Science and Engineering

The oxidation behaviors of different grades of nuclear graphite—PAEB, PCEB, PPEA, and IG-11—were studied thermogravimetrically at 400, 800, and 1200°C as a part of work to select one grade of nuclear graphite for use in a gas turbine-modular helium reactor (GT-MHR). The results showed that all grades of nuclear graphi…

Graphene research and applicationsFiber-reinforced polymer compositesGraphite, nuclear technology, radiation studies

Electrochemical impedance spectroscopy study of surface films formed on copper in aqueous environments

Krishna Srivastava、R. Balasubramaniam2005-09-01Materials and Corrosion

Abstract The electrochemical behavior of pure copper has been studied in aqueous environments using linear polarization and electrochemical impedance spectroscopy (EIS) techniques as a function of immersion time. The effect of pollutants (like chloride, sulfide and ammonium ions) on the nature of films formed on the c…

Corrosion Behavior and InhibitionConcrete Corrosion and DurabilityAnodic Oxide Films and Nanostructures

New Unsymmetrical Zinc‐Phthalocyanine Conjugated with One Azo‐Dye Moiety: Synthesis via Opening the Fused Triazole Ring and Spectral Properties

Xavier Àlvarez Micó、Sergei I. Vagin、L. R. Subramanian 等 5 位作者2005-09-01European Journal of Organic Chemistry

Abstract A new method for the preparation of compounds containing an azo‐dye moiety via opening the activated triazole ring upon coupling with nucleophiles was successfully applied to a mono‐triazole‐fused phthalocyaninato zinc complex 1 . The prepared unsymmetrical zinc‐phthalocyanine 3 conjugated with a 2‐hydroxy‐1‐…

Porphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research StudiesMetal-Catalyzed Oxygenation Mechanisms

A continuum-atomistic method for incorporating Joule heating into classical molecular dynamics simulations

Clifford W. Padgett、Donald W. Brenner2005-09-01Molecular Simulation

A hybrid atomistic-continuum method is presented for incorporating Joule heating into large-scale molecular dynamics (MD) simulations. When coupled to a continuum thermostat, the method allows resistive heating and heat transport in metals to be modeled without explicitly including electronic degrees of freedom. Atomi…

Graphene research and applicationsDiamond and Carbon-based Materials ResearchMolecular Junctions and Nanostructures

Temperature-Dependent Raman Spectroscopic Study of the Nematic Liquid Crystal 4- n -Pentyl-4′-Cyanobiphenyl

Dae Seung Kang、Ki‐Sun Kwon、Sung Il Kim 等 7 位作者2005-09-01Applied Spectroscopy

The spectral behaviors of 4-n-pentyl-4'-cyanobiphenyl (5 CB) have been studied by means of temperature-dependent Raman spectros-copy in the range between --70 and 70 degrees C. The nu(C identical with N) bands in the Raman spectra were found splitting below the transition temperature from the solid to the nematic liqu…

Liquid Crystal Research AdvancementsPlant and animal studiesMolecular spectroscopy and chirality

Shear Flow Properties and Melt Spinning of Thermoplastic Polyvinyl Alcohol Melts

Te-Hsing Ku、Chin-An Lin2005-09-01Textile Research Journal

Polyvinyl alcohol (PVA) is a water-soluble polymer, which is difficult to process in melt form owing to its poor processability and thermoplasticity. The thermoplastic polyvinyl alcohol (TPVA) prepared in this study is a brand new material for use in melt spinning. Satisfactory processability of TPVA can be obtained e…

Polymer crystallization and propertiesPolymer Foaming and CompositesPolymer Science and PVC

Local structure of technologically modified g-GeS2: resonant Raman and absorption edge spectroscopy combined withab initiocalculations

R. Holomb、Patrik Johansson、В. Міца 等 4 位作者2005-09-01The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics

We have used resonant Raman and absorption edge spectroscopy together with first-principle calculations in order to study the structure of GeS2 glasses (g-GeS2). The glasses were prepared under different melt temperatures and cooling rates, which are shown to significantly influence the g-GeS2 structure at the nano-sc…

Chalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenidesSolid-state spectroscopy and crystallography

Formulation of Corn Zein Chewing Gum and Evaluation of Sensory Properties by the Time‐Intensity Method

Bridget A. McGowan、Graciela W. Padua、Soo‐Yeun Lee2005-09-01Journal of Food Science

ABSTRACT: This study was conducted to determine the feasibility of using corn zein as a natural gum base to be an alternative to the currently used synthetic gum base. The objectives were to (1) develop a corn zein chewing gum and (2) evaluate the taste, texture, and aroma qualities compared with synthetic gum base us…

Food composition and propertiesNanocomposite Films for Food PackagingPolysaccharides Composition and Applications

129Xe and 131Xe NMR of Gas Adsorption on Single- and Multi-Walled Carbon Nanotubes

Catherine F. M. Clewett、T. Pietraβ2005-09-01The Journal of Physical Chemistry B

129Xe and 131Xe nuclear magnetic resonance (NMR) spectroscopy was used to study the adsorption of xenon gas on as-produced single-walled and multi-walled carbon nanotubes. Overall, the adsorption was weak, with slightly stronger interaction between xenon and multi-walled nanotubes. Temperature-dependent spectra, relax…

Carbon Nanotubes in CompositesNanopore and Nanochannel Transport StudiesQuantum, superfluid, helium dynamics