Materials Literature
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In this article, imaging applications of luminescent complexes and recent advances in the design and photophysical behaviour of near‐IR responsive complexes are reviewed. Various properties of the luminescent lanthanide complexes are also discussed in detail.
A metamaterial-based electronically controlled transmission-line structure is presented and demonstrated as a novel leaky-wave (LW) antenna with tunable radiation angle and beamwidth functionalities. This structure is, in essence, a composite right/left-handed (CRLH) microstrip structure incorporating varactor diodes…
An increasing number of potential applications for polyoxometalates in human medicine have been reported in the literature. These inorganic complexes are composed of early transition metals (mainly molybdenum, tungsten and vanadium) and oxygen. The present review gives an introduction into the chemistry of these compo…
An actively controlled battery/ultracapacitor hybrid has broad applications in pulse-operated power systems. A converter is used to actively control the power flow from a battery, to couple the battery to an ultracapacitor for power enhancement, and to deliver the power to a load efficiently. The experimental and simu…
Abstract The potential energy surface of curcumin [1,7‐bis(4‐hydroxy‐3‐methoxyphenyl)‐1,6‐heptadiene‐3,5‐dione] was explored with the DFT correlation functional B3LYP method using 6‐311G* basis. The single‐point calculations were performed at levels up to B3LYP/6‐311++G**//B3LYP/6‐311G*. All isomers were located and r…
Abstract Oxides with the nominal chemical formula Li 6 ALa 2 Ta 2 O 12 (A = Sr, Ba) have been prepared via a solid‐state reaction in air using high purity La 2 O 3 , LiOH·H 2 O, Sr(NO 3 ) 2 , Ba(NO 3 ) 2 , and Ta 2 O 5 and are characterized by powder X‐ray diffraction (XRD) in order to identify the phase formation and…
▪ Abstract Development and optimization of multifunctional devices for fluidic manipulation of films, drops, and bubbles require detailed understanding of interfacial phenomena and microhydrodynamic flows. Systems are distinguished by a large surface to volume ratio and flow at small Reynolds, capillary, and Bond numb…
The size and shape dependent electronic and chemical properties of metal nanoparticles has drawn the attention of chemists, physicists, biologists, and engineers who wish to use them for the development of new generation nanodevices. In this article, we report the synthesis of gold nanotriangles using tamarind leaf ex…
There is a growing need to develop clean, nontoxic and environmentally friendly ("green chemistry") procedures for synthesis and assembly of nanoparticles. The use of biological organisms in this area is rapidly gaining importance due to its growing success and ease of formation of nanoparticles. Presently, the potent…
Homogeneously dispersed organic–inorganic hybrid nanocomposites can be obtained by increasing the interfacial interactions between both components via the formation of hydrogen bonds or covalent bonds, by mixing various polymers or via the adequate choice of the inorganic precursors. The mechanical response of these a…
Since mesoporous silicates (M41S) were first discovered in the early 1990s, organic–inorganic assembly combined with sol–gel processes by using surfactants as structure-directing agents had been considered to be the major pathway for creating mesoscaled periodic materials. However, unfortunately, many mesostructured m…
Sol–gel derived films exhibit a high potential as substitutes for the environmentally unfriendly chromate metal-surface pre-treatment methods. Inorganic sol–gel derived films offer good adhesion between metals and organic paint. However, they cannot provide adequate corrosion protection due to their high crack-forming…
This paper presents a new computational framework for modeling chemically reacting flow in anode-supported solid-oxide fuel cells ͑SOFC͒.Depending on materials and operating conditions, SOFC anodes afford a possibility for internal reforming or catalytic partial oxidation of hydrocarbon fuels.An important new element…
With more and more plastics being employed in human lives and increasing pressure being placed on capacities available for plastic waste disposal, the need for biodegradable plastics and biodegradation of plastic wastes has assumed increasing importance in the last few years. This review looks at the technological adv…
Mesoporous carbons with ordered channel structure (COU-1) have been successfully fabricated via a direct carbonization of an organic-organic nanocomposite.
This tutorial review illustrates how work on the reversible interconversion between the colorless and colored forms of photochromic compounds can be exploited to modulate electron and energy transfer processes. Indeed, a photochrome can be designed to accept electrons or energy from a complementary donor in one of its…
Because the Roman god Janus was usually represented with two heads placed back to back, the term Janus is used for the description of particles whose surfaces of both hemispheres are different from a chemical point of view. So, they could be used as building blocks for supraparticular assemblies, as dual-functionalize…
This article reviews the most relevant chemical and structural aspects that influence the spin-crossover phenomenon (SCO). Special attention is focussed on the recent development of SCO coordination polymers. The different approaches currently being explored in order to achieve multifunctionality in SCO materials are…
Water-repellency is a property of some materials, either natural or synthetic, which makes water hardly stick to them: drops roll very easily off these solids, and bounce back upon impacting them. Here we discuss recent advances in this field, which has been particularly lively in recent years. We first examine the ph…
The conditions required for supramolecular electronics, e.g. nano-sized optoelectronic devices, will be illustrated on the basis of the programmed self-assembly of pi-conjugated systems into individual nanosized wires. Using the supramolecular design rules nanowires can be created from almost any polymeric and oligome…