Materials Literature
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Abstract The process of electrospinning is very suitable for obtaining fibers with a diameter on a nanometer scale. Such fibers can be spun from almost all kinds of known polymers, copolymers, and polymer blends. In this work, we present cellulose nanofibers obtained by the electrospinning process from spinning dopes…
A sufficiently large unpolarized current can cause a spin-wave instability in thin nanomagnets with asymmetric contacts. The dynamics beyond the instability is understood in the perturbative regime of small spin-wave amplitudes, as well as by numerically solving a discretized model. In the absence of an applied magnet…
Ferroelectricity has been found to occur in several insulating systems, such as TbMnO$_3$ (TMO) and Ni$_3$V$_2$O$_8$ (NVO) which have more than one phase with incommensurately modulated long-range magnetic order. Here we give a phenomenological model which relates the symmetries of the magnetic structure as obtained f…
We have performed self-consistent calculations of the dynamical response of the (111) surface of the noble metals Cu, Ag, and Au. Our results indicate that the partially occupied surface-state band in these materials yields the existence of acoustic surface plasmons with linear dispersion at small wave vectors. Here w…
We predict the existence of surface waves in layered superconductors in the THz frequency range, below the Josephson plasma frequency $ω_J$. This wave propagates along the vacuum-superconductor interface and dampens in both transverse directions out of the surface (i.e., towards the superconductor and towards the vacu…
A time-resolved ferromagnetic resonance technique was used to investigate the magnetization dynamics of a 10 nm thin Permalloy film. The experiment consisted of a sequence of magnetic field pulses at a repetition rate equal to the magnetic systems resonance frequency. We compared data obtained by this technique with c…
The fabrication and performances of cantilevered probes with reduced parasitic capacitance starting from a commercial Si3N4 cantilever chip is presented. Nanomachining and metal deposition induced by focused ion beam techniques were employed in order to modify the original insulating pyramidal tip and insert a conduct…
The pure Fano-effect in angle-integrated valence-band photo-emission of ferromagnets has been observed for the first time. A contribution of the intrinsic spin polarization to the spin polarization of the photo-electrons has been avoided by an appropriate choice of the experimental parameters. The theoretical descript…
We investigate the effect of anisotropy and weak dipolar interactions on the magnetization of an assembly of nanoparticles with distributed magnetic moments, i.e., assembly of magnetic nanoparticles in the one-spin approximation, with textured or random anisotropy. The magnetization of a free particle is obtained eith…
Effects of side reactions during the formation of high quality colloidal nanocrystals were studied using ZnO as a model system. In this case, an irreversible side reaction, formation of esters, was identified to accompany formation of ZnO nanocrystals through the chemical reaction between zinc stearate and an excess a…
Following our previous papers on the mechanism of ε-caprolactone (CL) and l, l -lactide (LA) polymerization initiated by tin(II) octoate [(tin(II) bis(2-ethylhexanoate), (Sn(Oct) 2 )] in the presence of the hydroxyl-group-containing compounds [H 2 O, alcohols or hydroxy-carboxylic acids (ROH)] the present work shows t…
A DPD model of PEO-based block copolymer vesicles in water is developed by introducing a new density based coarse graining and by using experimental data for interfacial tension. Simulated as a membrane patch, the DPD model is in excellent agreement with experimental data for both the area expansion modulus and the sc…
In this paper we reported, to the best of our knowledge, the first deposition of highly oriented thin films (with thickness of about 90 nm) of NdCoO3 and Nd0.8Sr0.2CoO3 cobaltites on single-crystalline STO and LAO substrates. Our investigation has shown that highly oriented single phase thin films of NCO and NSCO can…
We propose how to control the THz radiation generated by fast moving Josephson vortices in spatially modulated (either along the c-axis or the ab-plane) samples of Bi-2212 and related superconducting compounds. We show that the JVs moving in a subset of weaker junctions can generate out-of-ab-plane and outside-the-con…
Sol–gel switching is triggered by counteranion guest exchange. The secondary structures of reversible coordination polymers can interconvert from a folded helical conformation (gel) into an unfolded zigzag conformation (sol) and back again in aqueous media (see picture).
Traditionally, SWNTs have been prepared by electric arc-discharge, laser ablation, or chemical vapor deposition (CVD) methods, yielding tubes of various diameter and length distributions. However, without exception, as-prepared SWNTs are contaminated with a number of impurities, decreasing the overall yield of usable…
Upon decreasing temperature or increasing pressure, a noncrystallizing liquid will vitrify; that is, the structural relaxation time, taualpha, becomes so long that the system cannot attain an equilibrium configuration in the available time. Theories, including the well-known free volume and configurational entropy mod…
We explore two routes to wave function engineering in elongated colloidal CdSe/CdS quantum dots, providing deep insight into the intrinsic physics of these low-dimensional heterostructures. Varying the aspect ratio of the nanoparticle allows control over the electron-hole overlap (radiative rate), and external electri…
Summary form only given. The complete presentation was not made available for publication as part of the conference proceedings.
Abstract The reaction of arsenic, arsenic trichloride and AlCl 3 with sulfur or selenium, respectively, in closed glass ampoules at 80 °C leads to melts from which on slow cooling to 50 °C (As 3 S 5 )[AlCl 4 ] and (As 3 Se 4 )[AlCl 4 ] can be obtained in the form of yellow and red crystals. The crystal structures ((As…