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On the transport and speciation of ruthenium in high temperature oxidising conditions

Ulrika Backman、Maija Lipponen、Ari Auvinen 等 6 位作者2005-05-01Radiochimica Acta

Summary In this paper, the transport and speciation of ruthenium under conditions simulating an air ingress accident was studied. Ruthenium dioxide was exposed to an oxidising environment at high temperatures (>1200 °C) in a tubular flow furnace. At these conditions, volatile ruthenium species were formed. A major…

Radioactive element chemistry and processingNuclear Materials and PropertiesThermal and Kinetic Analysis

Aspect Ratio Controlled Growth of MnOOH in Mixtures of Mn3O4 and MnOOH Single Crystals for Supercapacitors

Yuan-Ting Wu、Chi‐Chang Hu2005-05-01Electrochemical and Solid-State Letters

Single crystals of MnOOH and were synthesized through a simple sol-gel route. From transmission electron microscopy. Fourier transform infrared, X-ray diffraction, and selected area electron diffraction analyses, manganese oxides prepared in this work are demonstrated to be a mixture consisting of MnOOH and single cry…

Advancements in Battery MaterialsZnO doping and propertiesSupercapacitor Materials and Fabrication

Comparison of ZnO metal–oxide–semiconductor field effect transistor and metal–semiconductor field effect transistor structures grown on sapphire by pulsed laser deposition

C. J. Kao、Yong Wook Kwon、Young-Woo Heo 等 7 位作者2005-05-01Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures Processing Measurement and Phenomena

ZnO thin film field effect transistors with 1.5–20μm gate width were fabricated using either a metal gate [metal–semiconductor field effect transistor (MESFET)] or a metal–oxide–semiconductor (MOS) gate. In both cases we found that use of a thick (∼0.8–0.9μm) ZnO buffer was necessary on the sapphire or glass substrate…

ZnO doping and propertiesSemiconductor materials and devicesThin-Film Transistor Technologies

The Effect of Degradation and Stabilization on the Mechanical Properties of Polymers Using Polypropylene Blends as the Main Example

H. H. Kausch2005-05-01Macromolecular Symposia

Abstract Degradation can result from a variety of chemical, physical and mechanical mechanisms, most of them involving a reduction of molecular weight and thus a decrease in the mechanical performance of the degraded polymer. A clear understanding and control of these mechanisms is absolutely essential: without stabil…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Science and PVC

Texture development and deformation mechanisms during uniaxial straining of U–Nb shape-memory alloys

Robert D. Field、Donald W. Brown、Dan J. Thoma2005-05-01The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics

The shape–memory effect is well documented in uranium–niobium alloys near the α″–γo metastable phase boundary. In situ neutron diffraction measurements during uniaxial loading indicate that U–14 at.% Nb (in the α″ monoclinic phase field) deforms by stress–induced twin reorientation. Alternatively, U–16 at.% Nb (initia…

High-pressure geophysics and materialsRare-earth and actinide compoundsNuclear Materials and Properties

Phenomenological Theory of Morphotropic Phase Boundary with Monoclinic Phase in Solid-Solution Systems of Perovskite-Type Oxide Ferroelectrics

Makoto Iwata、Yoshihiro Ishibashi2005-05-01Japanese Journal of Applied Physics

The phase diagram with monoclinic phase near the morphotropic phase boundary (MPB) and the dielectric constant in a solid-solution system of perovskite-type ferroelectrics are discussed on the basis of the Landau–Devonshire-type free-energy function expressed in terms of polarization components. It is confirmed that t…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Reduced modeling of eddy current-driven electromechanical system using conductor segmentation and circuit parameters extracted by FEA

S.-H. Lee、Se-Hee Lee、Hong Soon Choi 等 4 位作者2005-05-01IEEE Transactions on Magnetics

To analyze the mechanical dynamic characteristics of electromechanical system, we present a new and fast method using the reduced modeling technique for the levitated conductor. As of now, to solve this electromechanical system, the finite element method (FEM) or the boundary element method (BEM) employing the finite…

Electric Motor Design and AnalysisMagnetic Properties and ApplicationsNon-Destructive Testing Techniques

Extended Structures and Magnetic Properties of Lanthanide–Copper Complexes with Picolinic Acids as Bridging Ligands

A‐Qing Wu、Guang‐Hua Guo、Chun Yang 等 9 位作者2005-05-01European Journal of Inorganic Chemistry

Abstract The first examples of 3d–4f heterometallic complexes containing picolinic acid ligands were synthesized and characterized. Three series of complexes were obtained by the reaction of presynthesized “metallo ligands” Cu(pic) 2 and Ln(ClO 4 ) 3 in 2:1, 3:1, and 4:1 mole ratios. Complexes 1 – 3 ( denoted as the f…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Preparation and Characterization of Binary Grafted Polymeric Blends of Polyvinyl Alcohol and Gelatin and Evaluation of their Water Uptake Potential

A. K. Bajpai、Manish Sharma2005-05-01Journal of Macromolecular Science Part A

Binary hydrophilic blends of poly(acrylamide‐co‐methylene bis acrylamide) grafted polyvinyl alcohol (PVA) and gelatin (GEL) were prepared by redox polymerization method and the end product was characterized by infra red (IR) spectral analysis, differential scanning calorimety (DSC) measurements, and scanning electron…

Hydrogels: synthesis, properties, applicationsbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications

Synthesis of asymmetricallymeso-substituted porphyrins bearing amino groups as potential cationic photodynamic agents

Daniel A. Caminos、Edgardo N. Durantini2005-05-01Journal of Porphyrins and Phthalocyanines

Novel asymmetrically meso-substituted porphyrins bearing amino groups have been synthesized as precursors of cationic photodynamic agents. The amphiphilic character of these porphyrins was increased by the presence of a high lipophilic trifluoromethyl group. Different patterns of porphyrin structures were obtained fro…

Porphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research StudiesPorphyrin Metabolism and Disorders

Epstein frame: how and when it can be really representative about the magnetic behavior of laminated magnetic steels

Elettra Antonelli、E. Cardelli、Antonio Faba2005-05-01IEEE Transactions on Magnetics

In this paper, using suitable three-dimensional finite element method (FEM) approaches, either in frequency or in time domain, we will analyze the real magnetic behavior of a commercial Epstein machine, prescribed as standard magnetic measurement system. The analysis of magnetic field and eddy currents explains some f…

Microstructure and Mechanical Properties of SteelsMagnetic Properties and ApplicationsNon-Destructive Testing Techniques

Studies on Electrical Properties of Natural Fiber: HDPE Composites

Jitendra Naik、Satyendra Mishra2005-05-01Polymer-Plastics Technology and Engineering

: The composites of banana, hemp, and agave with HDPE resin were separately prepared in different ratios, 60:40, 55:45, 50:50, and 45:55 (wt/wt). These fibers were also treated with maleic anhydride and the effect of maleic anhydride was studied on surface resistivity and volume resistivity of wood polymer composites.…

Advanced Sensor and Energy Harvesting MaterialsNatural Fiber Reinforced CompositesConducting polymers and applications

Contactless Tip‐Selective Electrodeposition of Palladium onto Carbon Nanotubes and Nanofibers

Jean‐Claude Bradley、Sundar Babu、Patrick Ndungu2005-05-01Fullerenes Nanotubes and Carbon Nanostructures

Palladium was electrodeposited onto the tips of isolated carbon nanofibers and carbon nanopipes using an electric field. The amount of Pd deposited on the tips was controlled by varying the field application time. The morphology obtained varied from agglomerate of small particles that just covers the end of the nanotu…

Carbon Nanotubes in CompositesForce Microscopy Techniques and ApplicationsNanopore and Nanochannel Transport Studies

Polymeric Materials in Automobiles

Nada Štrumberger、Alen Gospočić、Čedomir Bartulić2005-05-01DOAJ (DOAJ: Directory of Open Access Journals)

Polymeric materials in automobiles have experienced a realboom in the last twenty years, and their application is increasingwith a tendency of further growth. The basic functions ofsuch wide application of polymeric materials in vehicles dictatethe appearance of the automobiles, their functionality, economyand low fue…

Vehicle emissions and performanceTribology and Wear AnalysisMaterial Properties and Applications

Electrical breakdown of thin polymer films

В. А. Закревский、N. T. Sudar’2005-05-01Physics of the Solid State

Data are presented on the dielectric strength of thin polymer films. The conclusion is drawn that the electron avalanche concept is inapplicable to the breakdown of thin films. It is proposed to consider electrical breakdown as a consequence of an abrupt local field enhancement induced by evolution of the space charge…

Advanced Sensor and Energy Harvesting MaterialsHigh voltage insulation and dielectric phenomenaElectrohydrodynamics and Fluid Dynamics

Current-Induced Plastic Deformation of Double-Walled Carbon Nanotubes

Yoshikazu Nakayama、Atsuko Nagataki、Osamu Suekane 等 5 位作者2005-05-01Japanese Journal of Applied Physics

We induced a permanent plastic deformation in an originally straight double-walled nanotube by applying current to an individual nanotube that had been bent elastically under mechanical duress. This method is controllable and allows nanotubes' application as building blocks in nanostructures. Inserting pentagon–heptag…

Carbon Nanotubes in CompositesForce Microscopy Techniques and ApplicationsMechanical and Optical Resonators

Time Dependent Density Functional Theory of X-ray Absorption Spectroscopy of Alkaline-Earth Oxides

G. Fronzoni、R. De Francesco、Mauro Stener2005-05-01The Journal of Physical Chemistry B

The time dependent density functional theory (TDDFT) has been employed to calculate the X-ray absorption spectra of the alkaline-earth oxides at the metal K and L and oxygen K edges. Cluster models to mimic the bulk are considered, embedded within an array of point charges to simulate the Madelung potential. Compariso…

Crystal Structures and PropertiesX-ray Diffraction in CrystallographyCrystallography and Radiation Phenomena

3-D computation of transformers overheating under nonlinear loads

Anthony Lefèvre、Laurence Miègeville、J. Fouladgar 等 4 位作者2005-05-01IEEE Transactions on Magnetics

This paper deals with a mixed analytical and numerical method to study the electromagnetic and thermal behavior of a dry type transformer under nonlinear loads. First a three-dimensional finite element method (FEM) using a magnetic scalar potential formulation is applied to compute the magnetic field in the free and i…

Silicon Carbide Semiconductor TechnologiesMagnetic Properties and ApplicationsInduction Heating and Inverter Technology

The Use of Fingernails as a Means of Assessing Bone Health: A Pilot Study

Indira Pillay、D. Lyons、Matthew J. German 等 9 位作者2005-05-01Journal of Women s Health

BACKGROUND: Anecdotally, patients volunteer reports of increasing hardness of their fingernails within months of starting diverse treatments for osteoporosis. The properties of both nail and bone may be linked in a comparable, measurable way. METHODS: We examined the fingernails of two groups of patients, with (n = 9)…

Bone health and osteoporosis researchNail Diseases and TreatmentsCollagen: Extraction and Characterization