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Chromium(VI) Separation from Tannery Wastes Utilizing Hydrotalcites

Sonia Martínez‐Gallegos、Verónica Martínez-Miranda、S. Bulbulian2004-02-12Separation Science and Technology

Laboratory scale tests were developed to study the high consumption of water in a tannery in Toluca City, Mexico, needed to decrease the biological oxygen demand (BOD) in the wastewater. Biological oxygen demand is generally reduced by reducing the organic material with sodium hypochlorite. However, Cr(VI) is formed i…

Mesoporous Materials and CatalysisLayered Double Hydroxides Synthesis and ApplicationsPhosphorus and nutrient management

Lithography-free high aspect ratio submicron quartz columns by reactive ion etching

Dagou A. Zeze、D. C. Cox、B.L. Weiss 等 4 位作者2004-02-12Applied Physics Letters

We describe lithography-free fabrication of sub-micron surface features on quartz substrates by the reactive ion etching (RIE) in a CF4/Ar atmosphere. These submicron glass columns are well defined, have a high aspect ratio, with the underlying substrate being very flat. The geometry of the fabricated surface columns…

Photonic and Optical DevicesAdvanced MEMS and NEMS TechnologiesOptical Coatings and Gratings

Fatigue and Corrosion Fatigue of High-Nitrogen Austenitic Stainless Steel

Markus Diener、Markus O. Speidel2004-02-12Materials and Manufacturing Processes

High nitrogen contents in solid solution as well as appropriate strengthening mechanisms in austenitic stainless steels can result in very high corrosion resistance. This is true in both air environment and in simulated human body fluids (corrosion fatigue). High cycle corrosion fatigue data are listed and compared wi…

Metal and Thin Film MechanicsHydrogen embrittlement and corrosion behaviors in metalsTitanium Alloys Microstructure and Properties

Chemical Recycling, Kinetics, and Thermodynamics of Alkaline Depolymerization of Waste Polyesters

A. S. Goje、Y. P. Chauhan、Satyendra Mishra2004-02-12Polymer-Plastics Technology and Engineering

Depolymerization of waste poly (ethylene terephthalate) and poly (butylene terephthalate) were undertaken in various alkaline solutions at different reaction parameters at 1 atm in a batch operation. Results were evaluated in terms of weight loss of both the waste polyesters as well as products obtained during depolym…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

Cure Characteristics and Mechanical Properties of Maleic Anhydride Grafted Reclaimed Rubber/Styrene Butadiene Rubber Blends

Paul A. Nelson、Sunil K. Narayanankutty2004-02-12Polymer-Plastics Technology and Engineering

Blends of styrene butadiene rubber (SBR) with maleic anhydride grafted whole tire reclaim (MA-g-WTR) have been prepared and the cure and mechanical properties have been studied with respect to the reclaim content. The grafting was carried out in the presence of dicumylperoxide (DCP) in a Brabender Plasticorder at 150°…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesTribology and Wear Analysis

Carrier redistribution in organic/inorganic (poly(3,4-ethylenedioxy thiophene/poly(styrenesulfonate)polymer)-Si) heterojunction determined from infrared ellipsometry

M. Schubert、Carsten Bundesmann、Holger von Wenckstern 等 9 位作者2004-02-12Applied Physics Letters

Charge redistribution in organic/inorganic heterojunction between poly(3,4-ethylenedioxy thiophene)/poly(styrenesulfonate) polymer (PEDOT/PSS) is observed contact-less by infrared spectroscopic ellipsometry. Hole accumulation or depletion layer formation is detected according to the different work functions of n- and…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsSemiconductor materials and interfaces

Temperature Dependence of the Structure and Interaction of Starlike PEG-Based Block Copolymer Micelles

Cornelia Sommer、Jan Skov Pedersen2004-02-12Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTTemperature Dependence of the Structure and Interaction of Starlike PEG-Based Block Copolymer MicellesCornelia Sommer and Jan Skov PedersenView Author Information Department of Chemistry and iNANO Interdisciplinary Nanoscience Cente…

Advanced Polymer Synthesis and CharacterizationPolymer Surface Interaction StudiesBlock Copolymer Self-Assembly

Electrical field freezing effect on laser floating zone (LFZ)-grown Bi2Sr2Ca2Cu4O11superconducting fibres

M.F. Carrasco、R.F. Silva、Joaquim M. Vieira 等 4 位作者2004-02-12Superconductor Science and Technology

The electrical assisted laser floating zone (EALFZ) solidification process makes the tailoring of fibre microstructures possible. The application of a dc electrical current of during the solidification process of Bi2Sr2Ca2Cu4O11 nominal composition fibres strongly modified phase development, crystal shapes and effecti…

Solidification and crystal growth phenomenananoparticles nucleation surface interactionsMetallurgical and Alloy Processes

Control of polytype formation in silicon carbide heteroepitaxial films by pulsed-laser deposition

Takeshi Kusumori、Hachizo Muto、Manuel E. Brito2004-02-12Applied Physics Letters

Control of silicon carbide (SiC) polytype formation has been achieved. 3C, 2H, and 4H SiC heteroepitaxial films are fabricated on a sapphire (0001) substrate at a low temperature of 1100 °C using a pulsed-laser deposition (PLD) method. Images made by transmission electron microscopy clearly show that each film consist…

ZnO doping and propertiesSemiconductor materials and devicesDiamond and Carbon-based Materials Research

Lattice effects of orbital and charge orderings in the perovskite manganitePr1−xCaxMnO3

Hirofumi Hazama、Terutaka Gotô、Yuichi Nemoto 等 6 位作者2004-02-12Physical Review B

We have made ultrasonic measurements of ${\mathrm{Pr}}_{1\ensuremath{-}x}{\mathrm{Ca}}_{x}{\mathrm{MnO}}_{3}$ $(x=0.35,$0.40,0.50) with the colossal magnetoresistance in order to investigate the lattice effects due to orbital and charge degrees of freedom in the systems. As a result, we observe three types of elastic…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

High-throughput growth temperature optimization of ferroelectric SrxBa1−xNb2O6 epitaxial thin films using a temperature gradient method

I. Ohkubo、Hans M. Christen、Sergei V. Kalinin 等 6 位作者2004-02-12Applied Physics Letters

We have developed a multisample film growth method on a temperature-gradient substrate holder to quickly optimize the film growth temperature in pulsed-laser deposition. A smooth temperature gradient is achieved, covering a range of temperatures from 200 to 830 °C. In a single growth run, the optimal growth temperatur…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAcoustic Wave Resonator Technologies

Possible origin of the proton conduction mechanism of CsH 2 PO 4 crystals at high temperatures

Jongho Park2004-02-12Physical Review B

The high-temperature transformation of ${\mathrm{CsH}}_{2}{\mathrm{PO}}_{4}$ was studied by means of impedance spectroscopy, differential thermal analysis, and thermogravimetric methods. The dielectric constant showed a high-temperature anomaly around ${T}_{p}=230\ifmmode^\circ\else\textdegree\fi{}\mathrm{C}.$ The the…

Crystal Structures and PropertiesAdvanced NMR Techniques and ApplicationsSolid-state spectroscopy and crystallography

Monolayer and Multilayer Films of [Mn12O12(O2CMe)16]

Jonathan S. Steckel、Nicole S. Persky、Chelsea R. Martinez 等 9 位作者2004-02-12Nano Letters

The manganese oxo-cluster, [Mn 12 O 12 (O 2 CMe) 16 (H 2 O) 4 ]·2(HO 2 CMe)·4(H 2 O), (Mn-12), has been the subject of intense interest for its novel magnetic properties. Although it is a model system for nanoscale magnetic data storage, no methods for forming films or attaching the cluster to surfaces have been repor…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesNanocluster Synthesis and Applications

Effect of Mn concentration on the structural, optical, and magnetic properties of GaMnN

G. T. Thaler、R. M. Frazier、B. Gila 等 8 位作者2004-02-12Applied Physics Letters

The room temperature magnetization of GaMnN films grown by molecular beam epitaxy on (0001) sapphire substrates with Mn concentrations varying from 0 to 9 at. % was found to depend on Mn concentration, with a maximum magnetization found at ∼3 at. % Mn. High-resolution x-ray diffraction measurements show that the c-pla…

ZnO doping and propertiesGaN-based semiconductor devices and materialsGa2O3 and related materials

The new materials processing beamline at the SRS Daresbury, MPW6.2

Robert J. Cernik、P. Barnes、G. Bushnell-Wye 等 15 位作者2004-02-12Journal of Synchrotron Radiation

A new beamline (MPW6.2) has been designed and built for the study of materials during processing where three synchrotron techniques, SAXS, WAXS and XAS, are available simultaneously. It has been demonstrated that Rietveld refinable data can be collected from silicon SRM 640b over a 60 degrees range in a time scale of…

Enzyme Structure and FunctionX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques

Resonance Raman Intensity Analysis of Merocyanine Dimers in Solution

Weinan Leng、Frank Würthner、Anne Myers Kelley2004-02-12The Journal of Physical Chemistry B

Resonance Raman excitation profiles and absolute cross sections are presented for three closely related merocyanine dyes as monomers in dichloromethane solution and as H-dimers in dioxane solution. For both monomers and dimers the absorption spectra and the resonance Raman intensities of the 24 to 30 strongest vibrati…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesSpectroscopy and Quantum Chemical Studies

Effect of deposition parameters on properties of ITO films prepared by reactive middle frequency pulsed dual magnetron sputtering

A.I. Rogozin、M. Vinnichenko、A. Kolitsch 等 4 位作者2004-02-12Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

ITO layers with low resistivity and high visible transmittance were produced by means of middle frequency reactive dual magnetron sputtering. The influence of base pressure, Ar/O2 ratio and magnetron pulse duration on the film composition, structure, electrical, and optical properties has been investigated. The deposi…

ZnO doping and propertiesMetal and Thin Film MechanicsGas Sensing Nanomaterials and Sensors

Luminescence enhancement in Eu3+-doped α- and γ-Al2O3 produced by pressure-assisted low-temperature combustion synthesis

Oscar Ozuna、Gustavo A. Hirata、Joanna McKittrick2004-02-12Applied Physics Letters

Intense red luminescence in Eu3+-doped gamma (γ) and alpha (α) alumina (Al2O3) phosphors obtained by direct and indirect combustion synthesis at low-temperatures is reported. γ and α-(Al1−xEux)2O3 are easily produced by combustion synthesis at 280 °C in the range of x=0.001–0.06 at. %. The well-defined direct synthesi…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsLuminescence and Fluorescent Materials

Low-temperature chemical vapor deposition and scaling limit of ultrathin Ru films

Q. Wang、John G. Ekerdt、D. Gay 等 5 位作者2004-02-12Applied Physics Letters

Thermal chemical vapor deposition at temperatures as low as 423 K, using Ru3(CO)12 with no accompanying reactive gas, forms pure, uniform, and smooth Ru films on Ta and low-resistivity films on SiO2. A 2.5-nm-thick Ru film fully covers the underlying Ta and the Ru film is thermally stable up to 573 K. Unlike Ta, Ru fi…

Semiconductor materials and devicesElectrodeposition and Electroless CoatingsCopper Interconnects and Reliability