Materials Literature
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Two cobalt(II) porphyrin-C(60) malonate-linked conjugates, the mono-connected Co1 and the bis-connected trans-2 isomer Co3, have been synthesized for the first time either by direct cyclopropanation with the precursor malonate Co4 or by metalation of the bisadduct H(2)3. For the investigation of the interaction betwee…
Luminescent semiconductor quantum dot (QD)-based optical biosensors have the potential to overcome many of the limitations associated with using conventional organic dyes for biodetection. We have previously demonstrated a hybrid QD-protein-based fluorescence resonance energy transfer (FRET) sensor. Although the QD ac…
Highly organized mesoporous silica monoliths were reproducibly prepared by nanocasting mixtures of fluorinated nonionic surfactants and micelles of two hydrocarbon block copolymers. It is the special feature of this fluorocarbon/hydrocarbon template mixture that they form not mixed micelles but individual micelles ins…
Pyrochlore-group minerals are relatively common accessory constituents of calcite carbonatite at the Oka Carbonatite Complex, Quebec. This complex is a member of the Cretaceous Monteregian petrological province, and consists predominantly of calcite carbonatite and feldspathoidal silicate rocks. Mineralogical studies…
Abstract Bamboo fiber-filled poly(lactic acid) (PLA) eco-composites were prepared by mechano-chemical compositing with bamboo fiber (BF)-esterified maleic anhydride (MA) (BF-e-MA) in the presence of dicumyl peroxide as a radical initiator. Tensile properties of the composites were improved by adding BF-e-MA and the di…
Abstract Polycaprolactone (PCL) has been blended with thermoplastic starch (TPS), prepared from regular corn starch and glycerol, in a twin‐screw extruder. The rheological, mechanical, thermal and morphological properties of the blends were examined. Differential Scanning Calorimetry (DSC) and Scanning Electron Micros…
Abstract The formation of well‐aligned ZnO nanorods has been achieved via H 2 treatment of as‐grown ZnO films. Structural analyses reveal that the ZnO nanorods on the ZnO films are preferentially oriented along the c ‐axis direction and exhibit a single‐crystalline wurtzite structure. To investigate the mechanism of f…
Abstract A series of MCM‐41s with a high copper content were synthesized at room temperature from sodium metasilicate (Na 2 SiO 3 ) as the silicon source, tetraamminecopper( II ) nitrate [Cu(NH 3 ) 4 (NO 3 ) 2 ] as the copper source and cetyltrimethylammonium bromide (CTABr) as the template. The resulting material was…
Abstract We report a Grand Canonical Monte Carlo simulation study of Ar adsorption at 77 K in silica nanopores having various morphologies/topologies. Both the morphological and topological disorders are shown to significantly affect the capillary condensation phenomenon. In the case of an ellipsoidal pore, we observe…
A drop shape analysis technique called Axisymmetric Drop Shape Analysis (ADSA) has been developed in our laboratory over the last twenty years. ADSA is a powerful technique for the measurement of interfacial tensions and contact angles of pendant drops, sessile drops, and bubbles. In essence, it relies on the best fit…
Abstract The creep behavior of composites prepared from woodflour and polypropylene has been analyzed. The woodflour content was varied from 0% to 60%. The compatibility between filler and matrix was varied by adding a non‐commercial polypropylene‐maleic anhydride copolymer (PPMAN) to the mixture. Short‐term and long‐…
Abstract A system based on variation of the octahedrally coordinated cations is proposed for graphical presentation and subdivision of tri- and dioctahedral K micas, which makes use of elemental differences (in a.p.f.u.): (Mg – Li) [= mgli ] and (Fe tot + Mn + Ti – VI Al) [= feal ]. All common true tri- and dioctahedr…
Leakage current produced on contaminated ceramic and polymeric insulating surfaces was analyzed using a wavelet transform technique providing time-frequency domain information. Salt-fog tests with and without the deposition of non-soluble contamination were conducted in a laboratory, during which the leakage current w…
The ultrafine ZnFe 2 O 4, MnFe 2 O 4, and cation deficit Zn−Mn ferrites were obtained by thermal decomposition of appropriate mixed complex compounds with acetylacetone (2,4-pentadione) ligands ([M(AA) x ]) at 500 °C. In ZnFe 2 O 4 cation distribution is partially inverse with 14% of Zn 2+ ions at octahedral 16d sites…
Using the Lagrangian formalism, coupled equations are derived that describe radial and translational motions of an arbitrary bubble in a three-dimensional cluster subject to an ultrasound field. The obtained equations incorporate the nonlinear coupling of the volume and the translational modes of bubbles as well as in…
This paper reports on an experimental investigation of the effects of garment fit on clothing thermal insulation and moisture vapor resistance, both of which increase with the thickness of the air gap between the garment and the body when the air gap is small. The rate of increase gradually decreases as the air gap be…
Abstract Dioctahedral smectite samples of a wide range of compositions (beidellites, montmorillonites, nontronites, Fe-rich montmorillonites and Al-rich nontronites) were studied by infrared (IR) spectroscopy. A special sample-preparation technique was used to eliminate the contribution of molecular water. The OH-stre…
A new, versatile methodology for functionalization of single-walled carbon nanotubes (SWNTs), using 1,3-dipolar cycloaddition of nitrile imines to the sidewalls of SWNTs has been used to synthesize two soluble, photoactive single walled carbon nanotubes containing n -pentyl esters at the tips and 2,5-diarylpyrazoline…
Nanostructured β‐SiC, with crystallite size in the range of 5–20 nm in agglomerates of 50–150 nm, was formed by reactive high‐energy ball milling and consolidated to a relative density of 98% by sintering at 1700°C without the use of additives. X‐ray line broadening analysis gave a crystallite size of 25 nm, while tra…
Novel devices for converting a linear polarization state to radial or azimuthal polarization states are realized by use of space-variant inhomogeneous media on a subwavelength scale. The two designs presented use form birefringence to locally transform the polarization state. The devices are fabricated in a GaAs subst…