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Thermally stable conducting composites based on a carbon black‐filled polyoxadiazole matrix

Fernando Gomes de Souza、Maria E. Sena、Bluma G. Soares2004-05-24Journal of Applied Polymer Science

Abstract New thermally stable conducting materials can be obtained by dispersing conducting carbon black into poly(4,4′‐diphenylether‐1,3,4‐oxadiazole) (POD–DPE) solution in NMP. The blend preparation process resulted in quite good dispersed composite and a relatively low percolation threshold (around 5 wt % of CB). T…

Conducting polymers and applicationsAdvanced Sensor and Energy Harvesting MaterialsOrganic Electronics and Photovoltaics

Synthesis and hydrolytic degradation of a random copolymer derived from 1,4‐dioxan‐2‐one and glycolide

Narayan Bhattarai、Wen Ying Jiang、Hak Yong Kim 等 5 位作者2004-05-24Journal of Polymer Science Part B Polymer Physics

Abstract Novel biodegradable copolymers, poly(1,4‐dioxan‐2‐one‐ co ‐glycolide) [P(DON‐ co ‐GA)] containing a high proportion of 1,4‐dioxan‐2‐one (DON), were synthesized by copolymerizations of DON and glycolide (GA) at 120 °C for 16 h using stannous octoate as catalyst. Chemical composition and microstructural variati…

biodegradable polymer synthesis and propertiesPolymer crystallization and propertiesAdvanced Polymer Synthesis and Characterization

Biaxially self‐reinforced high‐density polyethylene prepared by dynamic packing injection molding. I. Processing parameters and mechanical properties

Jun Lei、Chaodong Jiang、Kaizhi Shen2004-05-24Journal of Applied Polymer Science

Abstract Uniaxial oscillating stress field by dynamic packing injection molding (DPIM) is well established as a means of producing uniaxially self‐reinforced polyethylene and polypropylene. Here, the effects on the mechanical properties of high‐density polyethylene (HDPE) in both flow direction (MD) and transverse dir…

Polymer crystallization and propertiesPolymer Foaming and CompositesPolymer Nanocomposites and Properties

Highly grafted polystyrene‐modified natural rubber as toughener for polystyrene

S. B. Neoh、Azanam S. Hashim2004-05-24Journal of Applied Polymer Science

Abstract A polystyrene‐modified natural rubber (SNR) with 80% degree of grafting was evaluated against natural rubber (NR) in their blends with polystyrene (PS). The rubber loading of the PS‐SNR and PS‐NR blends was varied from 5 to 20% by volume. At 10–15% rubber loading, the PS‐SNR blends were found to be approximat…

Natural Fiber Reinforced CompositesPolymer Nanocomposites and PropertiesPolymer crystallization and properties

Structure of a poly(2,5‐benzimidazole)/phosphoric acid complex

Jaedong Cho、John Blackwell、С. Н. Чвалун 等 5 位作者2004-05-24Journal of Polymer Science Part B Polymer Physics

Abstract As‐cast films of poly(2,5‐benzimidazole) exhibit uniplanar orientation in which the planes of the aromatic rings lie parallel to the film surface. Upon doping with phosphoric acid, the original crystalline order is lost, but the doped film can be stretched to produce films with uniaxial orientation. After the…

Fiber-reinforced polymer compositesPolymer crystallization and propertiesSynthesis and properties of polymers

Combination of bifunctional aldehydes and poly(vinyl alcohol) as the crosslinking systems to improve paper wet strength

Gordon Guozhong Xu、Charles Q. Yang、Yulin Deng2004-05-24Journal of Applied Polymer Science

Abstract Two bifunctional aldehydes (i.e., glyoxal and glutaraldehyde) are used as the crosslinking agents to improve paper wet strength in the presence of fully hydrolyzed poly(vinyl alcohol) (PVA) as a co‐reactant. These bifunctional aldehydes alone improve paper wet strength but diminish its folding endurance. The…

Advanced Cellulose Research StudiesMaterial Properties and ProcessingRecycling and Waste Management Techniques

Synthesis and humidity sensitivity of conducting polyaniline in SBA‐15

Nan Li、Xiaotian Li、Wangchang Geng 等 6 位作者2004-05-24Journal of Applied Polymer Science

Abstract Conducting polyaniline (PANI) was synthesized in mesoporous silica SBA‐15. The investigations of XRD, N 2 adsorption–desorption, and IR spectra confirm the existence of polyaniline in the channels of SBA‐15 hosts. The impedance of PANI/SBA‐15 composites was studied at different relative humidity (RH) levels,…

Supercapacitor Materials and FabricationConducting polymers and applicationsElectrochemical sensors and biosensors

First-principles study of neutral oxygen vacancies in amorphous silica and germania

Tomoyuki Tamura、Guang‐Hong Lu、Ryōichi Yamamoto 等 4 位作者2004-05-24Physical Review B

Neutral oxygen vacancies in amorphous $(a\ensuremath{-})$ ${\mathrm{SiO}}_{2}$ and ${\mathrm{GeO}}_{2}$ as well as bulk $a\ensuremath{-}{\mathrm{SiO}}_{2}$ and $a\ensuremath{-}{\mathrm{GeO}}_{2}$ configurations have been investigated by using the first-principles pseudopotential method in order to elucidate the mechan…

Photorefractive and Nonlinear OpticsLuminescence Properties of Advanced MaterialsGlass properties and applications

Comparison of solutions to the scatterometry inverse problem

Christopher J. Raymond、Michael E. Littau、A.D. Chuprin 等 4 位作者2004-05-24Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

Scatterometry is a novel optical metrology that has received considerable attention in the silicon industry in the past few years. Based on the analysis of light scattered from a periodic sample, scatterometry technology can be thought of as consisting of two parts known as the forward problem and the inverse problem.…

Advanced Measurement and Metrology TechniquesSurface Roughness and Optical MeasurementsOptical Coatings and Gratings

USING EPILITHIC ALGAL COMMUNITIES TO ASSESS TROPHIC STATUS IN IRISH LAKES1

Dean M. DeNicola、Elvira de Eyto、Alice Wemaëre 等 4 位作者2004-05-24Journal of Phycology

Relationships between taxonomic composition of shallow epilithic algal communities and nine environmental variables in 32 lakes of different trophic states in Ireland were explored using gradient analysis. A canonical correspondence analysis using four representative environmental variables, alkalinity (correlated wit…

Aquatic Ecosystems and Phytoplankton DynamicsDiatoms and Algae ResearchMarine and coastal ecosystems

Crystal structure of the Deinococcus radiodurans single-stranded DNA-binding protein suggests a mechanism for coping with DNA damage

Douglas A. Bernstein、Julie M. Eggington、Michael P. Killoran 等 6 位作者2004-05-24Proceedings of the National Academy of Sciences

Single-stranded DNA (ssDNA)-binding (SSB) proteins are uniformly required to bind and protect single-stranded intermediates in DNA metabolic pathways. All bacterial and eukaryotic SSB proteins studied to date oligomerize to assemble four copies of a conserved domain, called an oligonucleotide/oligosaccharide-binding (…

Bacterial Genetics and BiotechnologyRNA and protein synthesis mechanismsEnzyme Structure and Function

Crystal structure of LeuA from Mycobacterium tuberculosis , a key enzyme in leucine biosynthesis

N. Koon、C.J. Squire、Edward N. Baker2004-05-24Proceedings of the National Academy of Sciences

The leucine biosynthetic pathway is essential for the growth of Mycobacterium tuberculosis and is a potential target for the design of new anti-tuberculosis drugs. The crystal structure of alpha-isopropylmalate synthase, which catalyzes the first committed step in this pathway, has been determined by multiwavelength a…

Microbial Natural Products and BiosynthesisEnzyme Structure and FunctionBiochemical and Molecular Research

Current-Driven Microwave Dynamics in Magnetic Point Contacts as a Function of Applied Field Angle

W. H. Rippard、M. R. Pufall、S. Kaka 等 5 位作者2004-05-24arXiv

We have measured microwave frequency, current-driven magnetization dynamics in point contacts made to Co90Fe10/Cu/ Ni80Fe20 spin valves as a function of applied field strength and angle relative to the film plane. As the field direction is varied from parallel to nearly perpendicular, the device power output increases…

Materials Sciencecond-mat.other

Conductivity of DNA probed by conducting-atomic force microscopy: effects of contact electrode, DNA structure, surface interactions

Thomas Heim、Dominique Deresmes、Dominique Vuillaume2004-05-24arXiv

We studied the electrical conductivity of DNA molecules with conducting atomic force microscopy as a function of the chemical nature of the substrate surfaces, the nature of the electrical contact, and the number of DNA molecules (from a few molecules, to ropes and large fibers containing up to ~ 106 molecules). Indep…

Soft Condensed MatterMaterials Science

In vivo monitoring of tissue pharmacokinetics of liposome/drug using MRI: Illustration of targeted delivery

Benjamin L. Viglianti、Sheela A. Abraham、Charles R. Michelich 等 7 位作者2004-05-24Magnetic Resonance in Medicine

The purpose of this study was to determine if MnSO(4)/doxorubicin (DOX) loaded liposomes could be used for in vivo monitoring of liposome concentration distribution and drug release using MRI. In vitro results show that T(1) shortening correlates with MnSO(4) concentration. Using a temperature-sensitive liposome formu…

Characterization and Applications of Magnetic NanoparticlesNanoparticle-Based Drug DeliveryNMR spectroscopy and applications

Vibration of the Dimer on Ge(001) Surface Excited Coherently by STM Current

Hiroshi Kawai、Osamu Narikiyo2004-05-24arXiv

The vibration of the dimer on Ge(001) surface with the higher vibrational number excited coherently by STM current is theoretically investigated. The coherent excitation rate of the dimer vibration is obtained by the Hamiltonian consisting of the terms of the electron system and the electron-vibration coupling terms.…

Materials Science

Role of molecular weight of atactic poly(vinyl alcohol) (PVA) in the structure and properties of PVA nanofabric prepared by electrospinning

Joon Seok Lee、Kyu Ha Choi、Han Do Ghim 等 7 位作者2004-05-24OpenAlex

Abstract Atactic poly(vinyl alcohols) (a‐PVAs) having number‐average degrees of polymerization [( P n )s] of 1700 and 4000 were prepared by the solution polymerization of vinyl acetate, which was followed by the saponification of poly(vinyl acetate) to investigate the effects of molecular weights of a‐PVA on the chara…

Conducting polymers and applicationsElectrospun Nanofibers in Biomedical ApplicationsAdvanced Sensor and Energy Harvesting Materials

Universal features of charge and spin order in a half-doped layered perovskite

I. A. Zaliznyak、J. M. Tranquada、G. Gu 等 5 位作者2004-05-23arXiv

We have investigated the peculiar structure of charge and spin ordering in the half-doped layered perovskite oxide La$_{1.5}$Sr$_{0.5}$CoO$_4$ by elastic neutron scattering. Two samples with different preparation histories were studied. We find that the generic features of the ordered states, such as their short-range…

Strongly Correlated ElectronsMaterials Science

Low-temperature nucleation in a kinetic Ising model under different stochastic dynamics with local energy barriers

Gloria M. Buendia、Per Arne Rikvold、Kyungwha Park 等 4 位作者2004-05-23arXiv

Using both analytical and simulational methods, we study low-temperature nucleation rates in kinetic Ising lattice-gas models that evolve under two different Arrhenius dynamics that interpose between the Ising states a transition state representing a local energy barrier. The two dynamics are the transition-state appr…

cond-mat.stat-mechMaterials Science

Nanofibre growth from cobalt carbide produced by mechanosynthesis

L. Díaz Barriga-Arceo、E. Orozco、Vicente Garibay-Feblés 等 7 位作者2004-05-22Journal of Physics Condensed Matter

Mechanical alloying was used to prepare cobalt carbide. Microstructural characterization of samples was performed by x-ray diffraction, differential scanning calorimetry and transmission electron microscopy methods. In order to produce carbon nanotubes, the cobalt carbide was precipitated after heating at 800 and 1000…

Boron and Carbon Nanomaterials ResearchDiamond and Carbon-based Materials ResearchCarbon Nanotubes in Composites