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How stable are inorganic fullerene-like particles? Thermal analysis (STA) of inorganic fullerene-like NbS 2 , MoS 2 , and WS 2 in oxidizing and inert atmospheres in comparison with the bulk material

Christoph Schuffenhauer、Gerhard Wildermuth、Jürgen Felsche 等 4 位作者2004-01-01Physical Chemistry Chemical Physics

Two-dimensional compounds (like graphite or MoS2) are capable of bending their layers and forming a closed cage structure, which is denoted the inorganic-fullerene-like (IF) phase in the case of inorganic materials. Simultaneous thermal analysis (TG-DTA) of a number of nanomaterials (IF-MoS2, IF-NbS2, and IF-WS2) and…

Graphene research and applicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Characterization of chromate conversion coating on AA7075‐T6 aluminum alloy

Qingjiang Meng、G. S. Frankel2004-01-01Surface and Interface Analysis

Abstract Chromate conversion coatings (CCCs) on AA7075‐T6 were characterized using scanning electron microscopy, focused ion beam sectioning and scanning transmission electron microscopy with nano‐electron dispersive spectroscopy line profiling. The thickness and composition of the CCC was different at different locat…

Corrosion Behavior and InhibitionAluminum Alloy Microstructure PropertiesBauxite Residue and Utilization

POSS Based Electrolytes for Rechargeable Lithium Batteries

Prithwiraj Maitra、Stephanie L. Wunder2004-01-01Electrochemical and Solid-State Letters

A class of electrolytes based on polyethylene oxide (PEO)-functionalized polyhedral oligosilsesquioxanes or PEO(n)-POSS] and lithium salts was developed, where 4, 〈8〉, 〈12.5〉 ethylene oxide units. Conductivities (σ) of these highly branched, nonvolatile (375°C), viscous polymers were at 50°C and at room temperature (R…

Advanced Battery Materials and TechnologiesPolyoxometalates: Synthesis and ApplicationsSilicone and Siloxane Chemistry

Effects of Dislocations on the Oxygen Ionic Conduction in Yttria Stabilized Zirconia

Kazuya Otsuka、Katsuyuki Matsunaga、Atsutomo Nakamura 等 7 位作者2004-01-01MATERIALS TRANSACTIONS

Ionic conductivities of yttria-stabilized zirconia (YSZ) single crystals deformed at high-temperature were measured by the AC impedance method. A correlation between ionic conductivity and dislocation structures of deformed YSZ single crystals were investigated. Electrical conductivity measurements of the deformed YSZ…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Enhanced fluorescence quenching in receptor-containing conjugated polymers: a calix[4]arene-containing poly(phenylene ethynylene)

Jordan H. Wosnick、Timothy M. Swager2004-01-01Chemical Communications

A fluorescent poly(phenylene ethynylene) containing calix[4]arene-based receptor units has a sensitivity to quenching by the N-methylquinolinium ion that is over three times larger than that seen in a control polymer lacking calix[4]arenes.

Molecular Sensors and Ion DetectionSupramolecular Chemistry and ComplexesLuminescence and Fluorescent Materials

Characterization of Ferrite-Austenite Boundary Region of Duplex Stainless Steels by SAES

M. Femenia、Jinshan Pan、Christofer Leygraf2004-01-01Journal of The Electrochemical Society

Scanning Auger electron spectroscopy (SAES) has been used to investigate the phase boundary region between ferrite and austenite in three duplex stainless steels. Of the elements investigated Cr and Mo are partitioned to the ferrite phase, while Ni and N are partitioned to the austenite phase. The composition gradient…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsWelding Techniques and Residual Stresses

Low Temperature Grain Boundary Diffusion of Chromium in SUS316 and 316L Stainless Steels

Masaki Mizouchi、Yoshihiro Yamazaki、Yoshiaki Iijima 等 4 位作者2004-01-01MATERIALS TRANSACTIONS

Grain boundary diffusivity of chromium in SUS316 and 316L stainless steels has been determined in the temperature range between 518 and 1173 K. The magnitudes of the grain boundary diffusivities in four kinds of specimens are in the order of the cold-worked SUS316, the solution-treated SUS316L, the solution-treated SU…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsHigh Temperature Alloys and Creep

A simple preparation method of epoxy resin/silica nanocomposite for Tg loss materialElectronic supplementary information (ESI) available: infrared spectrum of silica directly obtained from TEOS and acetic anhydride in autoclave, SEM image of Sample 3-5, 1H NMR spectra of DGEBA-1, DGEBA-3, allyl-DGEBA-3, Si-DGEBA-3, hydridodimethylsilyloxy-POSS and POSS-DGEBA-3. See http://www.rsc.org/suppdata/jm/b3/b315474b/

Masahiro Fujiwara、Katsunori Kojima、Yūko Tanaka 等 4 位作者2004-01-01Journal of Materials Chemistry

Nanocomposite materials of epoxy resin and silica were prepared by a simple procedure wherein diglycidyl ethers of bisphenol-A (DGEBA) as the pre-polymer of epoxy resin, tetraethoxysilane (TEOS) as silica source, and hexahydrophthalic anhydride (HHPA) were mixed together and heated at 170 °C in a sealed autoclave. HHP…

Polymer Nanocomposites and PropertiesSynthesis and properties of polymersSilicone and Siloxane Chemistry

Expanded Wood Fiber Polystyrene Composites: Processing–Structure–Mechanical Properties Relationships

Saeed Doroudiani、Mark T. Kortschot2004-01-01Journal of Thermoplastic Composite Materials

In this study, processing–structure–mechanical properties relationships in expanded wood fiber polystyrene composites (EPSC) made with a physical blowing agent were investigated. A systematic investigation was performed based on a statistical experimental design. The samples were saturated with carbon dioxide at high…

Natural Fiber Reinforced CompositesCellular and Composite StructuresPolymer Foaming and Composites

Effect of Alloy Chemistry on the High Temperature Strengths and Room Temperature Fracture Toughness of Advanced Nb-Based Alloys

Masakuni Fujikura、Akio Kasama、Ryohei Tanaka 等 4 位作者2004-01-01MATERIALS TRANSACTIONS

High temperature strength and room temperature fracture toughness of Nb-based alloy system were investigated to explore a candidate material for gas turbine use at 1773 K as a function of chemical compositions. 0.2% proof stress at 1773 K and the fracture toughness were studied for the solid-solution hardening Nb-Mo-W…

Intermetallics and Advanced Alloy PropertiesAdvanced Materials Characterization TechniquesMetallurgical and Alloy Processes

Development of Materials Testing Equipment in High Pressure Hydrogen and Hydrogen Environment Embrittlement of Austenitic Stainless Steels

Seiji Fukuyama、Lin Zhang、Kiyoshi Yokogawa2004-01-01Journal of the Japan Institute of Metals and Materials

Testing equipment for materials under high-pressure hydrogen of 70 MPa at the temperature range of room temperature up to 373 K has been developed. The pressure vessel was designed to enable the measurement of actual tensile load on a specimen by an external load cell without the influence of axial load due to high pr…

Microstructure and Mechanical Properties of SteelsFatigue and fracture mechanicsHydrogen embrittlement and corrosion behaviors in metals

Molecular precursors to gallium oxide thin films

Siama Basharat、Claire J. Carmalt、Simon J. King 等 5 位作者2004-01-01Dalton Transactions

The donor-functionalised alkoxides [Et(2)Ga(OR)](2)(R = CH(2)CH(2)NMe(2)(1), CH(CH(2)NMe(2))(2)(2), CH(2)CH(2)OMe (3), CH(CH(3))CH(2)NMe(2)(4), C(CH(3))(2)CH(2)OMe (5)) were synthesised by the 1:1 reaction of Et(3)Ga with ROH in hexane or dichloromethane at room temperature. Reaction of Et(3)Ga with excess ROH in refl…

Luminescence Properties of Advanced MaterialsSemiconductor materials and devicesGa2O3 and related materials

A contribution to the understanding of the polyamorphism situation in triphenyl phosphite

Alain Hédoux、Yannick Guinet、Patrick Derollez 等 6 位作者2004-01-01Physical Chemistry Chemical Physics

Triphenyl phosphite (TPP) is now well known to exhibit an intriguing transformation of the supercooled liquid. The transformation was firstly interpreted as a first-order polyamorphic transition between the supercooled liquid and an apparently amorphous state different from the glass and the ordinary liquid, the so-ca…

Liquid Crystal Research AdvancementsPolymer crystallization and propertiesMaterial Dynamics and Properties

Dendron-stabilised gold nanoparticles: generation dependence of core size and thermal stabilityElectronic supplementary information (ESI) available: TEM images of G1-Au, G2-Au, G3-Au complete with size distribution curves, and characterization data for dendrimers G2SSG2 and G1SSG1 and nanoparticles G1-Au and G2-Au. See http://www.rsc.org/suppdata/jm/b3/b312727c/

Christine S. Love、Victor Chechik、David K. Smith 等 4 位作者2004-01-01Journal of Materials Chemistry

L-Lysine based dendrimers containing a disulfide moiety at the core were synthesized. These novel ligands were used to stabilize Au nanoparticles via a one-phase chemical reduction method. The size of the resultant nanoparticles was found to decrease with increasing dendritic generation. Furthermore, the thermal stabi…

Gold and Silver Nanoparticles Synthesis and ApplicationsDendrimers and Hyperbranched PolymersNanocluster Synthesis and Applications

Benthic algae as bioindicators of agricultural pollution in the streams and rivers of southern Québec (Canada)

Isabelle Lavoie、Warwick F. Vincent、Reinhard Pienitz 等 4 位作者2004-01-01Aquatic Ecosystem Health & Management

The objective of this study was to evaluate the effect of agricultural pollution on periphyton in streams and rivers of southern Québec. We sampled benthic algae incubated from mid-July to mid-August on artificial substrates at 29 sites and analysed the variations in community structure and total community biomass. Di…

Freshwater macroinvertebrate diversity and ecologySoil and Water Nutrient DynamicsDiatoms and Algae Research

Effects of Microstructure on the High Temperature Constitutive Behavior of IN100

W.W. Milligan、E.L. Orth、J.J. Schirra 等 4 位作者2004-01-01OpenAlex

An experimental program was conducted in order to determine the effects of microstructure on the high temperature constitutive behavior or powder-processed IN100. The relevant application is the high pressure turbine disk in a gas turbine engine. Eight different microstructures were prepared, with 260 o C yield streng…

High Temperature Alloys and CreepMetallurgy and Material FormingHigh-Velocity Impact and Material Behavior

Green luminescence band of zinc oxide films copper-doped by thermal diffusion

Ya. I. Alivov、М. В. Чукичев、В. А. Никитенко2004-01-01Semiconductors

High quality ZnO single-crystal films were doped with copper by thermal diffusion, and their luminescent properties were studied by cathodoluminescence spectroscopy. Doping with copper increases the intensity of the green-emission band of the cathodoluminescence spectrum, whose peak, width, and shape at 78 and 300 K r…

ZnO doping and propertiesCopper-based nanomaterials and applicationsGa2O3 and related materials

Effect of Cation Radius Ratio and Unit Cell Free Volume on Oxide-Ion Conductivity in Oxide Systems with Pyrochlore-Type Composition

Hanako Nishino、Hiroshi Yamamura、Takahiko Arai 等 5 位作者2004-01-01Journal of the Ceramic Society of Japan

The oxide-ion conductivity of two solid-solution systems of a pyrochlore-type composition, (Y1-xLax)2(Ce1-xZrx)2O7 (YLa) and (Nd1-xYbx)2(Ce1-xZrx)2O7 (NdYb), was investigated. The crystal phase of the YLa system with a variable cation radius ratio, r(A3+)/r(B4+), but a constant lattice parameter, changed from the rare…

Nuclear Materials and PropertiesAdvanced Condensed Matter PhysicsNuclear materials and radiation effects

EQCM Study of Anodic Film Growth on Valve Metals

C.-O.A. Olsson、M.-G. Vergé、D. Landolt2004-01-01Journal of The Electrochemical Society

A comparative study of anodic film growth on niobium, zirconium, and tungsten in 0.4 M Na 2 SO 4 + 0.1 M H 2 SO 4 was performed using the rotating electrochemical quartz crystal microbalance (EQCM). Potential sweep as well as potential step and hold experiments were performed in the range between open circuit and 8 V…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsAnodic Oxide Films and Nanostructures

Carbon and copper nanostructured materials syntheses by plasma discharge in a supercritical fluid environment

Tsuyohito Ito、Ken Katahira、Yoshiki Shimizu 等 6 位作者2004-01-01Journal of Materials Chemistry

This first report on applications of discharges (or discharge plasma) in a supercritical carbon dioxide environment describes simple generation of nanostructured materials such as carbon nanotubes, nanopolyhedra, and copper nanostructured materials. Carbon nanostructured materials are synthesized by supercritical carb…

Carbon Nanotubes in CompositesDiamond and Carbon-based Materials ResearchFullerene Chemistry and Applications