Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
We report an interesting reentrant metallic resistivity pattern beyond a characteristic temperature T* which is higher than other such characteristic transition temperatures like T(c)(Curie point), T(N) (Neel point), T(CO) (charge order onset point) or T(OO) (orbital order onset point) in a range of rare-erath perovsk…
A mixed oxide-electron conducting ceramic, La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3 - α (LSCF), hollow-fiber membrane was prepared by a combined phase-inversion/sintering technique. The hollow-fiber membrane precursor was first spun from a starting solution containing 66.33 wt % LSCF powder, 6.63 wt % PESf binder, 0.5 wt % PVP…
The flexural properties of a particle adsorption monolayer are investigated theoretically. If the particles are not densely packed, the interfacial bending moment and the spontaneous curvature (due to the particles) are equal to zero. The situation changes if the particles are closely packed. Then the particle adsorpt…
The self-assembly of nanoparticles at fluid interfaces, driven by the reduction in interfacial energy, was investigated. With spherical, tri-n-octyl-phosphine-oxide covered cadmium selenide (CdSe) nanoparticles (1-8 nm), thermal fluctuations compete with the interfacial segregation giving rise to a size-dependent self…
Through three case studies, plane wave pseudopotential density functional theory calculations are performed to investigate the mechanism of second harmonic generation (SHG) of the nonlinear optical materials. We want to know how SHG coefficients are affected by: (1) anion substitution in $\mathrm{AgGa}{({\mathrm{S}}_{…
Porphyrins and fullerenes are spontaneously attracted to each other. This new supramolecular recognition element can be used to construct discrete host-guest complexes, as well as ordered arrays of interleaved porphyrins and fullerenes. The fullerene-porphyrin interaction underlies successful chromatographic separatio…
A study of step edges in graphite with different atomic structures combining Raman spectroscopy and scanning probe microscopy is presented. The orientation of the carbon hexagons with respect to the edge axis, in the so-called armchair or zigzag arrangements, is distinguished spectroscopically by the intensity of a di…
In this article we describe the synthesis, characterization, and applications of dendrimer-encapsulated nanoparticles (DENs). These materials are synthesized by a template approach in which metal ions are extracted into the interior of dendrimers and then subsequently chemically reduced to yield nearly size-monodisper…
The electrical characteristics of single CoPt3 nanocrystal microwires formed by magnetic field-directed growth from colloidal solutions are presented. The wires comprise disordered assemblies of discrete nanocrystals, separated from each other by protective organic ligand shells. Electrical data indicate that the acti…
The dynamics of two molecular glass formers are monitored at microsecond scales via muon spin relaxation. Measurements in transverse magnetic fields display unambiguous signatures of critical behavior at temperatures somewhat above those signaling the thermodynamic glass transition, namely at the onset of stochastic m…
Abstract A new naphthalene‐ring‐containing bis(ester–amine), 1,5‐bis(3‐aminobenzoyloxy)naphthalene, was prepared from the condensation of 1,5‐dihydroxynaphthalene with 3‐nitrobenzoyl chloride followed by catalytic hydrogenation. A series of novel naphthalene‐containing poly(ester–amide)s was synthesized by direct phos…
Abstract From chloromethylated polyimide, a useful starting material for modification of aromatic polyimides, a thermocurable transparent polyimide having acrylate side groups was prepared. In the presence of 1,8‐diazabicyclo[5,4,0]undec‐7‐ene, chloromethylated polyimide was esterified with acrylic acid to synthesize…
Abstract Some hydrogen‐bonding‐interactions‐mediated poly(ε‐caprolactone) (PCL)/silica (SiO 2 ) polymeric‐inorganic hybrids were prepared by the sol–gel process. The non‐isothermal crystallization kinetics of PCL in the hybrids was investigated by means of differential scanning calorimetry. The results show that the J…
Abstract Density functional theory calculations are used to determine the kinetics and reactivity indices of the first propagation steps of the polyethylene and poly(vinyl chloride) polymerization. Transition state theory is applied to evaluate the rate coefficient from the microscopically determined energies and part…
Abstract The dynamic flammability of flame‐retardant composites that consist of high‐density polyethylene (HDPE) and ethylene–propylene–diene rubber (EPDM) and other additives, and can be used as wire‐ and cable‐insulation materials, was studied before and after irradiation. The data for the heat‐release rate (HRR), t…
Klein, aber oho: Der Metallosternkomplex [Fe{Gd2L(H2O)4}3]4− (siehe Bild; L ist ein Bipyridin-Poly(aminocarboxylat)-Ligand) weist eine für seine recht geringe Molekülmasse außergewöhnlich hohe Protonenrelaxivität auf. Erklärt wird dies mit einer starren supramolekularen Struktur, zwei Wassermolekülen in der inneren Sp…
$\mathrm{U}{\mathrm{H}}_{3}$ thin films have been prepared by dc sputtering of uranium in presence of hydrogen, and studied in situ by valence band and core level spectroscopy. X-ray diffraction measurements showed formation of $\ensuremath{\beta}\text{\ensuremath{-}}\mathrm{U}{\mathrm{H}}_{3}$, and magnetization expe…
Abstract A semi‐interpenetrating polymer network (semi‐IPN) of polyethylene glycol (PEG) and crosslinked poly[(2‐hydroxyethyl methacrylate)‐ co ‐acrylonitrile] was prepared and adsorption of bovine serum albumin (BSA) on the IPN surfaces was investigated. The dynamic nature of the adsorption process was studied, and t…
Abstract Polyurethane dispersions (PUDs) have been an active area of research since the early 1940s because of legislative restrictions on the use of organic solvents in conventional solvent‐based products and also because PUDs exhibit almost the same high performance levels as solvent‐borne polyurethanes. In the pres…
High-quality SrBi2Ta2O9 single crystals were obtained by a self-flux solution method. The crystals were naturally oriented with [001] direction perpendicular to the major face and edges parallel to [110] axes. The dielectric and ferroelectric properties of the crystals were investigated along the c axis and in the ab…