Materials Literature
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The performance of a battery-ultracapacitor hybrid power source under pulsed load conditions is analytically described using simplified models. We show that peak power can be greatly enhanced, internal losses can be considerably reduced, and that discharge life of the battery is extended. Greatest benefits are seen wh…
We have investigated the atomistic structure of the 180\ifmmode^\circ\else\textdegree\fi{} and 90\ifmmode^\circ\else\textdegree\fi{} domain boundaries in the ferroelectric perovskite compound ${\mathrm{PbTiO}}_{3}$ using a first-principles ultrasoft-pseudopotential approach. For each case we have computed the position…
Block copolymers form a large number of superlattices with characteristic dimensions in the range of a few nanometers up to several micrometers by self-organization. The interplay of supramolecular physics and chemistry opens up new approaches to the production of inorganic, organic, and biological structures and to t…
The influence of chemical cross-links between a single-walled fullerene nanotube and a polymer matrix on the matrix−nanotube shear strength has been studied using molecular dynamics simulations. A (10,10) nanotube embedded in either a crystalline or amorphous polyethylene matrix is used as a model for a nonbonded inte…
The development and current status of microwave ferrite technology is reviewed in this paper. An introduction to the physics and fundamentals of key ferrite devices is provided, followed by a historical account of the development of ferrimagnetic spinel and garnet (YIG) materials. Key ferrite components, i.e., circula…
Single-walled carbon nanotubes (SWNTs) have emerged as a very promising new class of electronic materials. The fabrication and electronic properties of devices based on individual SWNTs are reviewed. Both metallic and semiconducting SWNTs are found to possess electrical characteristics that compare favorably to the be…
We have developed a transparent organic polymeric material that can repeatedly mend or "re-mend" itself under mild conditions. The material is a tough solid at room temperature and below with mechanical properties equaling those of commercial epoxy resins. At temperatures above 120 degrees C, approximately 30% (as det…
The expression of several heat-shock proteins of nitrogen-fixing bacteria is controlled post-transcriptionally by the thermosensitive secondary structure of the 'ROSE' regulatory sequences in their mRNA
Thieno[2,3-d]-1,2,3-thiadiazoles (1) react with carbon disulfide in a "Matryoshkatype" double compartment autoclave [1] to yield thieno[2,3-d]-1,3-dithiol-2-thiones (2). With BH3/Me2S the cyclic trithiocarbonate (2d) is cleaved and the product characterized after methylation as 4b. Compounds 7a and 7b are prepared via…
Electrochemical and chemical reductions of Rh (I) complexes of L P4 (a macrocycle containing four phosphinine rings) and of L P2S2 (a macrocycle containing two phosphinine rings and two thiophene rings) lead, in liquid solution, to EPR spectra exhibiting large hyperfine couplings with 31 P nuclei. An additional coupli…
The structures of side chain liquid crystalline poly(silylenemethylene)s (−(SiCH 3 R−CH 2 )−: R = O(CH 2 ) N O−Ph−Ph, Ph = phenyl) (PSM- N; N = 3, 6, 8, 11) have been studied by X-ray diffraction, differential scanning calorimetry (DSC), polarized optical microscopy, and transmission electron microscopy (TEM). DSC stu…
ABSTRACT The strength of films extruded from powder blends of corn zein or corn gluten meal (CGM) with low‐density polyethylene was investigated. Tensile strength, percent elongation at break, and elastic modulus of the extruded films were measured. The tensile strength decreased from 13 MPa to ≈10.5 MPa with zein add…
A facile synthesis of new conjugated ferrocenyl-based dendrimers is reported and the compounds obtained have been fully characterized. The synthetic method consists of a two-step procedure, which combines olefination by the Wittig procedure and Pd-mediated C–C coupling, leading to high yields of first generation dendr…
Abstract The crystallization behavior of oligoester blends prepared from crystalline poly(hexanediol adipate) (PHA) and amorphous poly(ethylene diethylene glycol adipate) (PEDEA) was studied using POM, WAXD, and DSC. The crystal form of both PHA and the blends are spherulites. The crystallinity, melting enthalpies, an…
The copper(II) ion in [Cu(C5H5N3O)2(CF3SO3)2]·H2O lies on a center of symmetry and is coordinated by two pyrazinecarboxamide ligands in a square-planar geometry with Cu—O and Cu—N distances of 1.9445 (14) and 1.9680 (17) Å, respectively. The Cu(C5H5N3O)2 unit is approximately planar, with an average atomic deviation…
Manganese (III) meso-tetrakis(p-sulfonatophenyl)-β-octabromoporphyrin supported on Amberlite IRA-400 [Mn(Br8TPPS)-Ad-400] is a robust and efficient catalyst for epoxidation of alkenes and hydroxylation of alkanes with sodium periodate at room temperature.
The redox reaction of silver acetate with [Ni6(CO)12]2− (2) in acetonitrile has afforded in low yields (≤10%) a close-packed silver–nickel carbonyl cluster: namely, the pseudo-Td [Ag16Ni24(CO)40]4− tetraanion (1) as the [PPh3Me]+ salt. This well-defined, dark brown bimetallic cluster, which is air-unstable and light-s…
Abstract To develop high‐quality electromagnetic interference (EMI) shielding materials, the effect of plasma pretreatment with various gases prior to Cu plating was investigated. Plasma treatment increased the surface roughness in the decreasing order of Ar > O 2 > NH 3 , but adhesion of the Cu layer on poly(et…
This paper presents a 35 Cl NMR and XRD study of the structure and dynamical behavior of ClO 4 - intercalated into the interlayers of Mg,Al and Li,Al layered double hydroxides (LDHs). The variable temperature and variable relative humidity (R.H.) 35 Cl NMR data show that for these phases ClO 4 - is rigidly held at low…
Absorption and fluorescence spectroscopies were used to study the adsorption of Rhodamine 3B (R3B) dye on Saponite (Sap) particles in aqueous suspensions. Fluorescence data confirmed that the R3B monomer can be adsorbed in the interlayer space and at the water/clay interface of the Sap tactoids. From the evolution of…